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Gold. This is what alchemists
dreams were made of.
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The medieval thinkers spent
their lives trying to find a way
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00:00:09,760 --> 00:00:13,760
to turn cheap metals,
such as this lead, into gold.
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Success would bring them fame
and infinite fortune,
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but is such magic even possible?
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Join us in the search
for the philosopher's stone.
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APPLAUSE
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The alchemists were obsessed with
the idea of producing
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a philosopher's stone.
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A magical rock or powder that could
turn metals into gold.
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There are even stories of espionage,
kidnap and even murder
12
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in a bid to steal
the secret of the stone.
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But what about the gold I just made?
14
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Well, I'm afraid we cheated.
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I'm not an alchemist.
My name is Dr Peter Wothers
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and I'm a chemist
from the University of Cambridge.
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I did start with lead.
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It was a specially prepared
form of lead that reacts
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with the oxygen from the air
to give this beautiful lead oxide.
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This yellowy orange compound here.
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So we did cheat here.
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And my philosopher's stone, well,
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it was just a hot coal which
started this reaction.
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Some alchemists used this reaction
to try to convince people
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that they could make gold.
But is such a feat even possible?
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In the last of this year's Royal
Institution Christmas lectures,
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I hope to find out.
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In the previous lectures,
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we've looked at the elements in the
air, and water, and now we are
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going to look at the elements in the
earth and how we can extract them.
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How we can use them and whether
we can turn one into another.
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To help me, I have a giant periodic
table made up
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of members from the audience
here at the Royal Institution.
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Let's just look at the elements
we have already talked about.
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We have lead, can you stand up,
please, lead? Thank you.
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We were looking at you
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and you were reacting with
the oxygen from the air.
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Can you stand up please, oxygen? OK.
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This is how we normally
find our metals in the earth.
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We don't find them lying around,
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they are normally combined with
the oxygen from the air.
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Or maybe sulphur, or occasionally
other metals. Thank you very much.
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If we put our periodic
tables down now, please.
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But occasionally, we can find
metals just lying around.
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The classic case is gold.
Where are you, gold?
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You are so special because sometimes
you can be found just lying around.
47
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In fact, here's a piece of you here.
This is a gold nugget.
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Thank you, periodic table, at ease.
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This is pure gold. And it can be
found like this in nature.
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In fact,
this is how it is normally found.
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Now the remarkable thing about gold
is that it doesn't change over time.
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So you could leave it for tens,
hundreds, even thousands
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of years and it'll still
have this beautiful appearance.
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I've got a very old
piece of gold to show you now.
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Would you please welcome, from the
Museum of London, Meriel Jeater.
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APPLAUSE
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I gather that this is a piece of
local gold, is that right?
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Exactly, yes. It was found in London,
in Cannon Street in 1976.
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00:03:59,960 --> 00:04:04,160
It's actually a Roman gold and
emerald necklace. That's beautiful.
60
00:04:04,160 --> 00:04:07,400
This is pure gold wire running
through these emeralds?
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00:04:07,400 --> 00:04:10,720
That's right, yes. And you say this
is from the early Roman times?
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This is how old? Nearly 2,000 years
old, yes. 2,000 years old.
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00:04:14,920 --> 00:04:17,160
Has this been heavily restored?
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00:04:17,160 --> 00:04:19,800
It's been given a bit of a clean
to get the mud off.
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00:04:19,800 --> 00:04:24,160
Just the mud off and the gold itself
was looking just like this? Exactly.
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That's why it's so wonderful
for archaeologists. Exactly.
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00:04:26,760 --> 00:04:29,960
For me as a chemist, I think it's
incredible that you can find
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gold in this state
and it doesn't tarnish over time.
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It doesn't combine with oxygen or
water or anything.
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This is how you find it.
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You can see that clearly it was
highly prized
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and I think maybe you should take
it back to the museum.
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Thank you very much. Pleasure.
Big round of applause, please.
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APPLAUSE
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This has lasted so well
because it was so highly prized,
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so valued there but also
because it didn't change over time.
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00:04:56,560 --> 00:04:59,600
But, of course, we have a saying
about the value of gold.
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00:04:59,600 --> 00:05:02,680
Sometimes people are told,
"You're worth your weight in gold."
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00:05:02,680 --> 00:05:05,680
Have you ever been told you're
worth your weight in gold? Yeah.
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00:05:05,680 --> 00:05:07,920
Oh, you have! Oh, good.
Who told you that?
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00:05:07,920 --> 00:05:10,360
I can't remember. Probably a parent.
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00:05:10,360 --> 00:05:14,560
Maybe we should ask gold. Where's
gold sitting? Are you gold, yes?
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00:05:14,560 --> 00:05:18,240
Have you been told that you're
worth your weight in gold before?
84
00:05:18,240 --> 00:05:21,000
I think my parents...
They've told you this, have they?
85
00:05:21,000 --> 00:05:25,000
I think we should see just how much
gold that would be.
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00:05:25,000 --> 00:05:27,400
Would you like to come down to
the front, please?
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00:05:27,400 --> 00:05:29,840
APPLAUSE
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00:05:31,080 --> 00:05:32,720
Would you like to face
the front here.
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00:05:32,720 --> 00:05:35,120
Would you like to tell
everyone your name? Emma.
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00:05:35,120 --> 00:05:36,160
Take a seat on here.
91
00:05:36,160 --> 00:05:39,400
If you just carefully sit down on
there. That's beautiful, lovely job.
92
00:05:39,400 --> 00:05:41,840
OK, right, are you sitting
comfortably?
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00:05:41,840 --> 00:05:45,520
Yep. Then we'll begin.
This is where I get very excited.
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This is all real gold. And it's
pretty good stuff, actually.
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00:05:52,200 --> 00:05:54,800
Have you ever held a big
block of gold before?
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No. No. Well, have a feel of this.
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That is pretty exciting, isn't it?
Would you like to feel this as well?
98
00:06:01,440 --> 00:06:03,240
I'm afraid I can't let
everybody have...
99
00:06:03,240 --> 00:06:05,160
I know, it's amazing, isn't it?
100
00:06:05,160 --> 00:06:10,480
This is actually about the same as
six large bottles of fizzy pop.
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00:06:10,480 --> 00:06:12,680
I'm just going to put this on here.
102
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OK, I think you need more than that.
Let's keep going.
103
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Let's put this one on. It really is
pretty good stuff, this.
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00:06:22,960 --> 00:06:25,880
This is 24ct pure gold.
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And this one here.
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More. More still.
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00:06:34,480 --> 00:06:38,520
Not quite. No.
OK, let's try this one.
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I think it's almost level
but not quite.
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00:06:46,520 --> 00:06:49,320
I think we need just
a little bit more.
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Has anyone else in the audience
got any gold?
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LAUGHTER
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I found some on the way in.
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Oh, you've got some?
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Isn't that Nobel prize-winning
chemist Prof Sir Harry Kroto?
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00:07:02,240 --> 00:07:03,760
I think it is.
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APPLAUSE
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So what exactly...I think
I might know what this is.
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Is this really your Nobel Prize?
Yes, they give them away.
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This is solid gold, isn't it?
It's solid gold. And I want it back.
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Well, of course, Harry.
I trust you. Oh, thank you.
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Right, anyway,
maybe this is just what we need.
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Let's just try that on there.
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Oh, I think that's pretty well
balanced now.
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00:07:42,040 --> 00:07:43,320
I think that's quite amazing.
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I think that is 43kg of gold and
one Nobel Prize.
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Thank you very much.
Big round of applause.
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Stay where you are for a moment.
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APPLAUSE
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Thank you, Prof Kroto, for saving
the day. This is quite amazing.
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43kg, but it doesn't actually
look too much there, does it, Emma?
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What do you think?
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00:08:03,840 --> 00:08:05,840
As you say, it's very dense
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and this is why it doesn't actually
take up much space.
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00:08:09,080 --> 00:08:12,800
If you were made of gold,
you would weigh 800kg,
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which is about as much
as a small car.
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Which is quite a lot really, isn't
it? So that's pretty impressive.
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How much do you think this is worth?
How much do you think? Have a guess.
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Um...quite a lot.
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I think you're right there.
Quite a lot, yes.
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Anyone have any other ideas?
Shout it out. Yes?
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One million? One million, actually,
you're not far off.
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It is even more than that.
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This is about £1.5 million
worth of gold just sitting here.
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Which is pretty impressive,
isn't it? All right, now.
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If you just stay where
you are sitting, please.
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I need to unload this first of all.
I'll just take that and...
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LAUGHTER
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Just going to put these over here.
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A few little bits left.
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There we are. That's fantastic.
OK, thank you very much, Emma.
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Big round of applause.
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APPLAUSE
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Gold really is an incredibly
dense substance.
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But actually,
it's not the densest element.
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Could we just have cards
up for a second, please?
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That honour goes to osmium. You are
the densest thing in the universe.
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Well, at least on Earth.
Did you know that?
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I don't mean that in a bad way.
This is just you as an element.
159
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Osmium is incredibly dense indeed.
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Can we just keep the cards
up for the people in the same row
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as osmium and gold.
Everyone else down.
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Caesium stay up, barium stay up.
All the way over to mercury.
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Why is it, then, that these
elements are so incredibly dense?
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The most dense element is osmium,
closely followed by iridium.
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Well, atoms after osmium,
iridium, gold,
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all these other
ones are getting heavier.
167
00:10:02,880 --> 00:10:04,880
So the atoms themselves are heavier
168
00:10:04,880 --> 00:10:07,880
and yet these ones are the most
tightly packed.
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So it's not just to do with how
heavy the atoms are.
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We also need to look at the bonding
that we have between them.
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And this is what
we can see in the graph here.
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This shows how much energy
we need to put in to separate
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a certain number of atoms
of these elements.
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And we see that we've got
a peak around tungsten.
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This is why we use tungsten
in light bulb filaments,
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because it's very difficult
to pull them apart.
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And we have very high temperatures.
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But as we go beyond tungsten,
the bonding isn't quite so strong
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but the atoms are getting heavier.
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And so it's bit of a balance
between the strength of the bonds,
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how tightly they are packed,
and how heavy the atoms are.
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This is why we reach a maximum for
osmium and iridium.
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Gold, platinum and so on are still
very dense afterwards,
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but the maximum is there for
osmium and iridium.
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So osmium is even more expensive
than gold, in fact.
186
00:11:01,560 --> 00:11:04,560
And if someone was really going to
pay you a compliment
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they would say, "You are worth
your weight in osmium."
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Actually, these metals are not
the only precious things
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we can extract from the earth.
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There are even non-metals that we
can sometimes find as well.
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00:11:18,560 --> 00:11:20,760
Hello. Hello, Prof Kroto.
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I'm assuming you would
like your Nobel Prize, would you?
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I'd swap it for those bigger ones.
Yes, so would I, I think.
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Well, there we go.
Thank you very much.
195
00:11:32,080 --> 00:11:36,400
Perhaps you could tell us
what you won the Nobel Prize for.
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It's for discovering
an alternative to these.
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This is graphite and this is diamond.
These structures.
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These are actually the only ones
that I knew about
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when I was at school.
200
00:11:47,160 --> 00:11:50,040
In the text books, there were just
two types of carbon.
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Two different forms called
allotropes.
202
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One has this arrangement.
This one is the graphite.
203
00:11:54,400 --> 00:11:56,640
This is the sort of thing you
find in your pencils.
204
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It's pretty soft and well, carbon,
it's just an arrangement of carbon.
205
00:12:00,480 --> 00:12:03,040
Diamond looks very different
though, doesn't it?
206
00:12:03,040 --> 00:12:06,360
I don't suppose...you've very
kindly lent us your gold,
207
00:12:06,360 --> 00:12:09,080
I don't suppose you have a spare
diamond on you, do you?
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00:12:09,080 --> 00:12:12,600
I don't myself
but my wife actually has one.
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00:12:12,600 --> 00:12:16,400
A-ha! You don't want to take that as
well, do you? Well, just borrow it.
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I hope I get it back. Thank you,
Mrs Kroto. Of course, yes.
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You can trust me.
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This is a beautiful ring here. Is it
an engagement ring or something?
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00:12:30,880 --> 00:12:32,880
It's really quite lovely.
214
00:12:32,880 --> 00:12:35,080
The diamond comes out quite easily,
doesn't it? Yes.
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00:12:35,080 --> 00:12:36,440
LAUGHTER
216
00:12:36,440 --> 00:12:39,560
We can see it more clearly now.
Look at that. It's beautiful.
217
00:12:39,560 --> 00:12:42,920
What a beautiful diamond. It is
a real diamond though, is it?
218
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It as real as you can get.
It's quite stunning.
219
00:12:46,720 --> 00:12:52,680
Of course, we want to show that this
graphite is made up of carbon.
220
00:12:52,680 --> 00:12:54,120
There is one way we can do this.
221
00:12:54,120 --> 00:12:58,360
We can burn our carbon in oxygen
and we'll get, what would we get?
222
00:12:58,360 --> 00:13:02,360
Carbon dioxide. See?
He's pretty good. Carbon dioxide.
223
00:13:02,360 --> 00:13:05,880
And then if we bubble that through
lime water? Calcium carbonate.
224
00:13:05,880 --> 00:13:08,800
Calcium carbonate. That's the test
for carbon dioxide, of course.
225
00:13:08,800 --> 00:13:11,160
And it would be white.
I didn't ask you that one.
226
00:13:11,160 --> 00:13:15,400
You are getting carried away now.
Let's just see this over here.
227
00:13:15,400 --> 00:13:16,840
We have some apparatus.
228
00:13:16,840 --> 00:13:20,680
This is where we are going to
burn some graphite
229
00:13:20,680 --> 00:13:23,320
and show that it is made of carbon.
230
00:13:23,320 --> 00:13:25,640
What's bubbling through
here is just oxygen.
231
00:13:25,640 --> 00:13:29,320
This won't react
with our lime water at all.
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00:13:29,320 --> 00:13:33,280
We are going to see
if we can light the graphite
233
00:13:33,280 --> 00:13:38,160
and get it burning inside the
oxygen. There we are. Thank you.
234
00:13:38,160 --> 00:13:41,520
That's great.
So now we have a hydrogen flame.
235
00:13:41,520 --> 00:13:44,840
This won't produce anything.
It's only going to produce water.
236
00:13:44,840 --> 00:13:48,440
You can see the water just
beginning to condense.
237
00:13:48,440 --> 00:13:51,160
Beautiful.
I'm going to turn the flame off.
238
00:13:52,960 --> 00:13:55,600
Look at that. What do you think?
It's brilliant.
239
00:13:55,600 --> 00:13:57,320
It is literally brilliant, yes.
240
00:13:57,320 --> 00:14:02,960
This is the carbon combining with
oxygen that's flowing through here.
241
00:14:02,960 --> 00:14:06,600
Hopefully, we are going to see this
changing colour, giving us
242
00:14:06,600 --> 00:14:10,040
a milky colour. Showing that there
is carbon dioxide present.
243
00:14:10,040 --> 00:14:13,720
I think we should test diamond as
well, don't you? What do you think?
244
00:14:13,720 --> 00:14:15,520
ALL: Yes!
245
00:14:15,520 --> 00:14:18,000
Yes? Does Mrs Kroto mind?
246
00:14:18,000 --> 00:14:21,120
OK. In the name of science.
That's very kind of you.
247
00:14:21,120 --> 00:14:24,280
Harry seems a little nervous.
Are you sure this is a real diamond?
248
00:14:24,280 --> 00:14:27,720
I think it's a real diamond, yes.
Let's give it a go then.
249
00:14:27,720 --> 00:14:31,680
We will just put it on there.
And again, we'll put this on here.
250
00:14:34,080 --> 00:14:39,720
Right, so we have our flame.
Here we go. The moment of truth.
251
00:14:39,720 --> 00:14:44,960
Now can we get our diamond to
burn in the oxygen?
252
00:14:46,200 --> 00:14:47,960
WATER BUBBLES
253
00:14:54,720 --> 00:14:57,680
Ah, look at that!
254
00:14:57,680 --> 00:15:00,520
I hope you can afford to
pay for this.
255
00:15:00,520 --> 00:15:03,200
The good news is, Harry, it is
a real diamond.
256
00:15:03,200 --> 00:15:04,680
LAUGHTER
257
00:15:04,680 --> 00:15:05,880
OK.
258
00:15:07,520 --> 00:15:09,600
I think this is absolutely stunning.
259
00:15:09,600 --> 00:15:13,920
That diamond there, it is
burning in oxygen.
260
00:15:13,920 --> 00:15:16,280
It's combining with
the oxygen of the air.
261
00:15:16,280 --> 00:15:19,280
Have you ever seen a diamond burning
like that before? No, I haven't.
262
00:15:19,280 --> 00:15:21,560
It is quite stunning to see.
That's right.
263
00:15:21,560 --> 00:15:23,960
There are no flames
coming from this.
264
00:15:23,960 --> 00:15:28,680
So this is just the heat of the
reaction as the carbon combines
265
00:15:28,680 --> 00:15:32,320
with the oxygen that's present,
flowing through here,
266
00:15:32,320 --> 00:15:35,840
forming carbon dioxide. That is
absolutely stunning.
267
00:15:35,840 --> 00:15:38,040
Just look at that.
It's glowing all by itself.
268
00:15:38,040 --> 00:15:41,480
It's absolutely brilliant.
I think that's amazing.
269
00:15:41,480 --> 00:15:45,520
And look,
our lime water is going milky.
270
00:15:45,520 --> 00:15:49,000
It's the most expensive
lime water I've ever seen.
271
00:15:49,000 --> 00:15:50,800
I think you are probably
right there.
272
00:15:50,800 --> 00:15:53,720
It really is the most expensive
lime water you've ever seen.
273
00:15:53,720 --> 00:15:57,680
Well, we are waiting for your
diamond just to... Disappear.
274
00:15:57,680 --> 00:15:59,760
To disappear, yes.
275
00:15:59,760 --> 00:16:02,840
Maybe you could tell us
about your Nobel Prize again.
276
00:16:02,840 --> 00:16:07,240
I think it has something to do with
this. I think it does, yes.
277
00:16:07,240 --> 00:16:09,680
Would you like to come round to
the front, actually.
278
00:16:09,680 --> 00:16:11,360
We'll compare it to these ones.
279
00:16:11,360 --> 00:16:15,200
This one was the graphite.
This is the diamond.
280
00:16:15,200 --> 00:16:19,040
And this is the third form,
the well-characterised form.
281
00:16:19,040 --> 00:16:23,600
It consists of 60 carbon
atoms in the shape of a soccer ball.
282
00:16:23,600 --> 00:16:26,920
And it was such a fantastic surprise
when we discovered it.
283
00:16:26,920 --> 00:16:32,040
One of the clues to its structure was
Mr Fuller's geodesic domes.
284
00:16:32,040 --> 00:16:36,440
In Montreal, we had visited that.
And I remembered it.
285
00:16:36,440 --> 00:16:38,120
It was in a book of mine
286
00:16:38,120 --> 00:16:43,000
and when we were trying to work out
how a sheet of graphite like this,
287
00:16:43,000 --> 00:16:46,600
or a graphing sheet, might close up,
288
00:16:46,600 --> 00:16:50,920
what we discovered was, it could
close up if it had 12 pentagons.
289
00:16:50,920 --> 00:16:54,800
You cannot close a sheet of
hexagons up. It won't close up.
290
00:16:54,800 --> 00:16:57,040
But if you have 12 pentagons,
it will.
291
00:16:57,040 --> 00:17:00,480
And you are all familiar with
that in the case of the normal
292
00:17:00,480 --> 00:17:05,280
soccer ball with 12 black pentagons
and 20 hexagons.
293
00:17:05,280 --> 00:17:09,360
And that's the magic that Mr Fuller
knew, and other people as well.
294
00:17:09,360 --> 00:17:12,920
And I called it Buckminsterfullerene
295
00:17:12,920 --> 00:17:16,080
because there are double
bonds as there are in benzene.
296
00:17:16,080 --> 00:17:20,040
So the "ene" ending was just
a beautiful sort of ending
297
00:17:20,040 --> 00:17:21,840
to a great name.
298
00:17:21,840 --> 00:17:26,200
So since my time at school,
the textbooks have to be rewritten
299
00:17:26,200 --> 00:17:30,000
with a new form of carbon
discovered by this chap here.
300
00:17:30,000 --> 00:17:34,320
And colleagues in the States. And
your co-workers in the States.
301
00:17:34,320 --> 00:17:37,480
We should have another
look at your diamond here.
302
00:17:37,480 --> 00:17:40,440
It seems to have decreased in size.
303
00:17:40,440 --> 00:17:42,040
I think we should come clean.
304
00:17:42,040 --> 00:17:46,120
Don't worry, we didn't destroy
Mrs Kroto's engagement ring.
305
00:17:46,120 --> 00:17:51,480
That really would be quite harsh.
This is a pretty low-grade diamond.
306
00:17:51,480 --> 00:17:53,960
It still looks pretty good
to the naked eye
307
00:17:53,960 --> 00:17:56,520
but the experts say it's not
very valuable at all.
308
00:17:56,520 --> 00:17:58,160
But it is a real diamond.
309
00:17:58,160 --> 00:18:00,000
And it is combining with oxygen
310
00:18:00,000 --> 00:18:03,640
and I think that's a pretty stunning
reaction. Thank you, Prof Kroto.
311
00:18:03,640 --> 00:18:06,080
It's a real privilege to have a
Nobel Prize winner here,
312
00:18:06,080 --> 00:18:08,600
helping out with an experiment.
Thank you very much.
313
00:18:08,600 --> 00:18:10,120
APPLAUSE
314
00:18:13,400 --> 00:18:18,240
So is it possible that we could take
this worthless carbon dioxide
315
00:18:18,240 --> 00:18:21,000
and get our diamond back from that?
316
00:18:21,000 --> 00:18:24,080
I mean, that really would be
the alchemist's dream.
317
00:18:24,080 --> 00:18:26,880
Recovering something
precious from something worthless.
318
00:18:26,880 --> 00:18:31,080
We've got a demonstration here that
shows that this may be possible.
319
00:18:31,080 --> 00:18:32,880
I'll just turn this round.
320
00:18:34,760 --> 00:18:39,200
Now this tank is filled with
carbon dioxide gas.
321
00:18:39,200 --> 00:18:42,040
We've put some solid carbon
dioxide in the bottom,
322
00:18:42,040 --> 00:18:45,280
which is slowly evaporating,
turning into the gas.
323
00:18:45,280 --> 00:18:48,040
We can't see the gas because,
of course, it's colourless.
324
00:18:48,040 --> 00:18:51,000
But it is there.
How can we test for this?
325
00:18:51,000 --> 00:18:54,000
Does anyone know another
use for carbon dioxide? Yes?
326
00:18:54,000 --> 00:18:56,520
To put out flames.
To put out flames, yes, exactly.
327
00:18:56,520 --> 00:19:00,320
I wonder if we have a flame, please.
Is there a flame anywhere?
328
00:19:00,320 --> 00:19:05,800
Ah, yes. Here is a flame
that certainly needs putting out.
329
00:19:05,800 --> 00:19:08,560
If I just lower
this into the tank...
330
00:19:11,280 --> 00:19:13,560
There we are.
You can see that it goes out.
331
00:19:13,560 --> 00:19:17,400
This is because, of course, the tank
is filled with carbon dioxide.
332
00:19:17,400 --> 00:19:20,200
And carbon dioxide doesn't
support combustion.
333
00:19:21,560 --> 00:19:27,640
Right, now then. We have also placed
in this tank some magnesium metal.
334
00:19:27,640 --> 00:19:30,200
I'm just going to fish this out.
335
00:19:33,240 --> 00:19:36,880
This is a little
nest of magnesium metal.
336
00:19:36,880 --> 00:19:39,440
I'm going to
light the magnesium here
337
00:19:39,440 --> 00:19:43,040
and it burns with a brilliant white
flame. There we are.
338
00:19:43,040 --> 00:19:46,840
Now I'm going to lower
this into the carbon dioxide.
339
00:19:46,840 --> 00:19:49,840
It seems to be burning even
more vigorously now.
340
00:19:49,840 --> 00:19:52,080
The flame is still burning.
341
00:19:54,440 --> 00:19:58,800
But what about this? This
one...well, this one still goes out.
342
00:20:00,320 --> 00:20:05,120
Our petrol is extinguished
in the carbon dioxide,
343
00:20:05,120 --> 00:20:08,000
but the magnesium
is reacting with it.
344
00:20:08,000 --> 00:20:13,040
The magnesium is stealing the oxygen
away from the carbon dioxide
345
00:20:13,040 --> 00:20:16,320
and, well, we'll have a look at what
we've got at the bottom
346
00:20:16,320 --> 00:20:19,480
but let me take this out.
You can see magnesium oxide
347
00:20:19,480 --> 00:20:22,200
covered over what was
the magnesium here,
348
00:20:22,200 --> 00:20:26,880
but look in the centre.
What we've now got is black carbon.
349
00:20:28,880 --> 00:20:33,320
The magnesium removes the oxygen
leaving behind the carbon
350
00:20:33,320 --> 00:20:35,200
from the carbon dioxide.
351
00:20:35,200 --> 00:20:38,680
We can get our carbon
back from carbon dioxide
352
00:20:38,680 --> 00:20:43,320
but, well, it's not a diamond yet.
353
00:20:43,320 --> 00:20:47,960
Is it possible to turn
that carbon into a diamond?
354
00:20:47,960 --> 00:20:52,840
Well, actually, this is what happens
deep within the earth,
355
00:20:52,840 --> 00:20:56,120
and this is a diamond in a rock
356
00:20:56,120 --> 00:21:00,760
just as it would have
come out of the earth.
357
00:21:00,760 --> 00:21:03,000
This is really quite
beautiful indeed.
358
00:21:03,000 --> 00:21:06,960
Deep within the earth,
the carbon is heated up
359
00:21:06,960 --> 00:21:09,920
and compressed with huge
temperatures, huge pressures,
360
00:21:09,920 --> 00:21:12,920
and the carbon we saw there,
the black carbon,
361
00:21:12,920 --> 00:21:16,760
is converted into diamond.
362
00:21:16,760 --> 00:21:20,080
Recently, chemists have learnt
how to copy this process,
363
00:21:20,080 --> 00:21:24,880
how to turn graphite or other
forms of carbon into diamond.
364
00:21:24,880 --> 00:21:29,080
I'd like a volunteer to help me
out with this one, please.
365
00:21:29,080 --> 00:21:32,840
Would you like to come down
to the front, please?
366
00:21:32,840 --> 00:21:35,320
APPLAUSE
367
00:21:35,320 --> 00:21:38,360
If you'd like to come down to
the front. Your name is...?
368
00:21:38,360 --> 00:21:43,040
Lewis. Lewis, OK.
Now, this is a diamond.
369
00:21:43,040 --> 00:21:46,080
Would you like to just hold this?
370
00:21:46,080 --> 00:21:48,520
What do you think,
are you impressed? Yeah.
371
00:21:48,520 --> 00:21:52,120
Looks like a piece of glass, doesn't
it? It actually really is a diamond.
372
00:21:52,120 --> 00:21:55,200
This is a synthetically grown
diamond and this has been prepared
373
00:21:55,200 --> 00:21:59,040
not from the high temperature, high
pressure system that we also use,
374
00:21:59,040 --> 00:22:02,000
this is a technique
called chemical vapour deposition
375
00:22:02,000 --> 00:22:05,080
where the diamond is gradually
built up a layer at a time.
376
00:22:05,080 --> 00:22:09,440
I'd like you to take this,
not keep it, but bring it over here
377
00:22:09,440 --> 00:22:11,400
and just place it on top.
378
00:22:11,400 --> 00:22:14,720
This is some ice here.
Hold it like this.
379
00:22:14,720 --> 00:22:19,680
Just put that on top of there
and push through this ice.
380
00:22:19,680 --> 00:22:23,400
How does that feel? Cold. It feels
very cold and what's happening?
381
00:22:23,400 --> 00:22:25,480
Water's coming off.
382
00:22:25,480 --> 00:22:28,920
This is ice, solid ice,
and it seems to be going...
383
00:22:28,920 --> 00:22:32,040
You've chopped all the way through
this quite cleanly there.
384
00:22:32,040 --> 00:22:33,800
As you say, it's got very cold.
385
00:22:33,800 --> 00:22:36,240
Do you know why it's got colder?
No idea.
386
00:22:36,240 --> 00:22:39,160
It's used your energy
to heat up this block of ice,
387
00:22:39,160 --> 00:22:42,400
so yes, you're getting cold
because it's taking the energy
388
00:22:42,400 --> 00:22:44,960
from your fingers here.
Let's try this again.
389
00:22:44,960 --> 00:22:48,400
If I just put this on here,
it slices through like butter.
390
00:22:48,400 --> 00:22:51,080
It's really quite amazing.
It feels very strange.
391
00:22:51,080 --> 00:22:55,000
I'm not sawing. It's not cutting
because it's hard,
392
00:22:55,000 --> 00:22:58,440
it's cutting because it's
a very good conductor of heat.
393
00:22:58,440 --> 00:23:01,640
Quite remarkable, so cleanly
through this block of ice.
394
00:23:01,640 --> 00:23:04,720
Feels very strange. Thank you very
much, thank you for that.
395
00:23:04,720 --> 00:23:07,720
APPLAUSE
396
00:23:09,120 --> 00:23:11,120
That remarkable
property of diamond
397
00:23:11,120 --> 00:23:14,320
was because it's an incredible
conductor of heat.
398
00:23:14,320 --> 00:23:17,280
To demonstrate this
and explain why this is so,
399
00:23:17,280 --> 00:23:20,120
I'd like some other volunteers,
please.
400
00:23:20,120 --> 00:23:23,480
I'd like six people so if we could
have all of you, six of you,
401
00:23:23,480 --> 00:23:26,000
if you could come down
to the front, please?
402
00:23:26,000 --> 00:23:30,800
In a row, facing the audience.
Sit next to each other.
403
00:23:30,800 --> 00:23:33,920
I'd like all of you to face that
direction, please,
404
00:23:33,920 --> 00:23:35,920
turn around and face that way.
405
00:23:35,920 --> 00:23:38,720
Just close up a little bit,
a little bit friendlier.
406
00:23:38,720 --> 00:23:42,040
Come this way, please. Lovely job.
Close up there
407
00:23:42,040 --> 00:23:45,680
and put your hands on the shoulders
of the person in front.
408
00:23:45,680 --> 00:23:47,600
Face that way. That's good.
409
00:23:47,600 --> 00:23:51,400
Now, at the moment, these are
all pretty weak bonds here.
410
00:23:51,400 --> 00:23:54,240
Watch what happens when I give
a bit of energy this way.
411
00:23:54,240 --> 00:23:56,640
Don't do anything,
just behave normally.
412
00:23:56,640 --> 00:23:59,520
Lucy, can you feel anything?
413
00:23:59,520 --> 00:24:02,400
It was very difficult to get
this energy through there
414
00:24:02,400 --> 00:24:04,960
and this is because
of all these weak bonds.
415
00:24:04,960 --> 00:24:08,560
What I'd like you to do is just
spread yourselves out a little more
416
00:24:08,560 --> 00:24:11,280
and hold arms
with very rigid arms.
417
00:24:11,280 --> 00:24:14,560
Rigid, straight arms. That's it.
418
00:24:14,560 --> 00:24:17,560
Now I'm just going to do
the same thing again.
419
00:24:17,560 --> 00:24:22,280
Give you a jolt that end and now you
can see you're certainly moving.
420
00:24:22,280 --> 00:24:25,720
Thank you very much indeed,
thank you for all your help.
421
00:24:25,720 --> 00:24:27,960
APPLAUSE
422
00:24:27,960 --> 00:24:34,040
This is why our diamond is such
a good conductor of thermal energy.
423
00:24:34,040 --> 00:24:38,840
It's because the bonds are so strong
holding these carbon atoms together,
424
00:24:38,840 --> 00:24:43,600
they're so rigid, that this energy
is very easily transmitted through.
425
00:24:43,600 --> 00:24:47,080
Diamond is the best conductor of
heat of any substance known,
426
00:24:47,080 --> 00:24:51,120
until very recently when scientists
discovered a new form of carbon,
427
00:24:51,120 --> 00:24:54,880
another form, called graphene,
which is a single sheet of graphite.
428
00:24:54,880 --> 00:24:59,600
That is an even better conductor of
heat. They're the best ones known.
429
00:25:01,840 --> 00:25:05,160
We've seen then that we can
convert charcoal,
430
00:25:05,160 --> 00:25:09,280
we convert graphite into diamond
under very high pressures
431
00:25:09,280 --> 00:25:12,240
or using the other technique
of chemical vapour deposition.
432
00:25:12,240 --> 00:25:16,720
Surely if the alchemists had focused
on that, they would have changed
433
00:25:16,720 --> 00:25:20,920
their attention away from trying
to turn base metals into gold.
434
00:25:20,920 --> 00:25:24,000
But of course, they were focused
on metals because metals
435
00:25:24,000 --> 00:25:26,960
were incredibly important
and still are very important.
436
00:25:26,960 --> 00:25:29,280
It's only gold that has
this unique property
437
00:25:29,280 --> 00:25:33,800
that we can find it lying around.
Most metals we find in their ores.
438
00:25:33,800 --> 00:25:36,440
Ores like this here.
439
00:25:36,440 --> 00:25:41,480
This is the natural mineral -
does anybody know what it is?
440
00:25:41,480 --> 00:25:43,280
It is an iron ore.
441
00:25:43,280 --> 00:25:47,160
Does anyone know what
the name of the iron ore would be?
442
00:25:47,160 --> 00:25:49,560
Very good, you're doing well.
Hematite it is.
443
00:25:49,560 --> 00:25:52,160
This is the mineral hematite.
444
00:25:52,160 --> 00:25:54,920
This is now our source for iron
445
00:25:54,920 --> 00:25:59,760
but it's locked up with the iron
combined with oxygen.
446
00:25:59,760 --> 00:26:03,960
Somehow we have to learn how
to extract the metal out of this.
447
00:26:03,960 --> 00:26:07,080
After all,
it doesn't just fall from the skies.
448
00:26:07,080 --> 00:26:12,160
But remarkably, sometimes it does
just fall from the skies
449
00:26:12,160 --> 00:26:14,960
and this is what we have here.
450
00:26:14,960 --> 00:26:17,640
This is actually very heavy as well.
451
00:26:17,640 --> 00:26:23,360
This is a lump of iron that did fall
from the skies about 5,000 years ago
452
00:26:23,360 --> 00:26:27,000
and it landed in Australia.
Look at this.
453
00:26:27,000 --> 00:26:30,360
What I wanted to show you here
was the comparison
454
00:26:30,360 --> 00:26:32,080
between these two pieces.
455
00:26:32,080 --> 00:26:37,520
We can see that this is developing
this reddish-brown colour,
456
00:26:37,520 --> 00:26:39,920
the same as the hematite.
457
00:26:39,920 --> 00:26:42,440
This contains iron.
It is a slice of iron
458
00:26:42,440 --> 00:26:45,280
but it is gradually combining
with oxygen
459
00:26:45,280 --> 00:26:47,520
to form this mineral hematite.
460
00:26:47,520 --> 00:26:49,960
We can show that it is a meteorite
461
00:26:49,960 --> 00:26:52,840
if we were to take a slice
through this.
462
00:26:52,840 --> 00:26:55,640
If we took a slice through this,
463
00:26:55,640 --> 00:26:59,480
what we would see
is something like this.
464
00:26:59,480 --> 00:27:06,000
This is a slice through a meteorite
and it's really quite beautiful.
465
00:27:06,000 --> 00:27:08,440
This has been cut
and we can see the side here.
466
00:27:08,440 --> 00:27:10,680
This is the outer surface
of the meteorite
467
00:27:10,680 --> 00:27:14,120
and here it's been cut with this
incredible pattern here.
468
00:27:14,120 --> 00:27:18,400
This pattern
has been etched with acid.
469
00:27:18,400 --> 00:27:22,560
It etches away certain types
of the minerals that are in here.
470
00:27:22,560 --> 00:27:25,720
The forms of the iron, it etches
away certain of them
471
00:27:25,720 --> 00:27:28,760
and it reveals this beautiful
crystal structure
472
00:27:28,760 --> 00:27:31,160
and this proves
that it's a meteorite,
473
00:27:31,160 --> 00:27:34,880
because it's impossible to get
this pattern here on Earth.
474
00:27:34,880 --> 00:27:37,040
That's because we need to cool
down molten iron
475
00:27:37,040 --> 00:27:39,080
with a little bit of nickel in.
476
00:27:39,080 --> 00:27:41,960
We'd need to cool it down
over such a slow rate,
477
00:27:41,960 --> 00:27:44,600
just one degree
over thousands of years,
478
00:27:44,600 --> 00:27:47,440
if we wanted to see
these crystals develop.
479
00:27:47,440 --> 00:27:51,520
This really is
quite stunning indeed.
480
00:27:51,520 --> 00:27:55,840
Over time, the metal of this
beautiful meteorite
481
00:27:55,840 --> 00:27:58,720
will turn into this ore here.
482
00:27:58,720 --> 00:28:01,480
We can't wait thousands of years
to see that
483
00:28:01,480 --> 00:28:03,520
but we can speed this process up
484
00:28:03,520 --> 00:28:08,000
and we can show how iron combines
with the oxygen to form iron oxide.
485
00:28:08,000 --> 00:28:10,880
I'd like a volunteer
for this one, please.
486
00:28:10,880 --> 00:28:13,440
I'd like someone from this side,
who shall we have?
487
00:28:13,440 --> 00:28:15,840
Would you like to come down
to the front, please?
488
00:28:15,840 --> 00:28:19,080
APPLAUSE
489
00:28:19,080 --> 00:28:22,040
Would you like to tell us
your name, please? Rose.
490
00:28:22,040 --> 00:28:25,600
Rose, OK, we have some iron
over here. This is just iron wool.
491
00:28:25,600 --> 00:28:27,040
Would you like to feel this?
492
00:28:27,040 --> 00:28:29,880
It's just the sort of thing
you would use to clean your pots
493
00:28:29,880 --> 00:28:31,920
and pans if you're
helping out at home.
494
00:28:31,920 --> 00:28:33,760
Now, I'll put on my goggles
495
00:28:33,760 --> 00:28:37,400
and we're going to combine this
with some oxygen.
496
00:28:37,400 --> 00:28:43,080
We want to see how much this weighs
by itself. This weighs 15.9 grams.
497
00:28:43,080 --> 00:28:45,520
Now, the question is,
what will happen
498
00:28:45,520 --> 00:28:48,160
when this combines
with the oxygen from the air?
499
00:28:48,160 --> 00:28:50,400
How do you think
its mass will change?
500
00:28:50,400 --> 00:28:52,600
Will it go up, go down,
stay the same?
501
00:28:52,600 --> 00:28:54,680
What do you think, when it burns?
502
00:28:54,680 --> 00:28:57,320
It will go up? It will go up,
and why's that?
503
00:28:57,320 --> 00:29:01,680
Because it will become more dense.
It will become more dense.
504
00:29:01,680 --> 00:29:03,880
Let's have a look and see,
shall we?
505
00:29:03,880 --> 00:29:06,280
I'm just going to apply
a light here.
506
00:29:06,280 --> 00:29:10,080
This beautiful reaction is the
iron combining with the oxygen
507
00:29:10,080 --> 00:29:12,520
and look what's happened
to the mass.
508
00:29:12,520 --> 00:29:15,800
It's gone down. It's getting lower.
509
00:29:15,800 --> 00:29:19,680
-0.16, so whoever said it
goes down, you're quite right.
510
00:29:19,680 --> 00:29:22,880
But look now what's happening.
It's going up again.
511
00:29:22,880 --> 00:29:26,280
It's is getting heavier so whoever
said it goes up, you're quite right.
512
00:29:26,280 --> 00:29:29,000
Everyone's right, that's good.
Why did it go down?
513
00:29:29,000 --> 00:29:33,520
It went down initially because
this iron wool was treated with oil,
514
00:29:33,520 --> 00:29:37,920
just to try and stop it combining
with the oxygen from the air.
515
00:29:37,920 --> 00:29:41,160
Once this reaction has
started, it is combining with oxygen
516
00:29:41,160 --> 00:29:44,360
and that's why it's getting heavier.
You were quite right.
517
00:29:44,360 --> 00:29:48,200
It is getting heavier because
the iron is forming iron oxide.
518
00:29:48,200 --> 00:29:50,440
Thank you very much indeed.
519
00:29:50,440 --> 00:29:53,360
APPLAUSE
520
00:29:55,360 --> 00:29:57,240
Iron is pretty reactive stuff.
521
00:29:57,240 --> 00:29:59,520
It reacts with oxygen
and this is how
522
00:29:59,520 --> 00:30:03,280
we would normally find our metal,
combined with oxygen.
523
00:30:03,280 --> 00:30:07,160
What about if you couldn't extract
the iron from this?
524
00:30:07,160 --> 00:30:09,560
What about before we knew
how to do this?
525
00:30:09,560 --> 00:30:12,480
The only iron that we would have had
would have been iron
526
00:30:12,480 --> 00:30:14,960
from a natural source
such as this meteorite.
527
00:30:14,960 --> 00:30:19,160
This sort of iron was used
to make tools and so on.
528
00:30:19,160 --> 00:30:23,520
I think we have an example of a tool
using some natural iron here.
529
00:30:23,520 --> 00:30:25,600
Would you please welcome
Dr Caroline Smith
530
00:30:25,600 --> 00:30:27,880
from the Natural History Museum.
531
00:30:27,880 --> 00:30:30,280
APPLAUSE
532
00:30:32,160 --> 00:30:34,800
This is really beautiful.
What exactly is this?
533
00:30:34,800 --> 00:30:39,080
This is an Inuit knife
and it's made of walrus tusk,
534
00:30:39,080 --> 00:30:43,440
so walrus ivory, but in the end
you can hopefully see
535
00:30:43,440 --> 00:30:46,080
it actually has an iron blade.
536
00:30:46,080 --> 00:30:49,040
When this was discovered, the Inuits
hadn't yet learnt
537
00:30:49,040 --> 00:30:51,880
how to make iron,
how to extract it from the ore.
538
00:30:51,880 --> 00:30:55,320
That's right. They had to have
a source of metallic iron.
539
00:30:55,320 --> 00:30:58,560
At the time, it was thought
that the iron in this knife
540
00:30:58,560 --> 00:31:02,120
was actually from a meteorite called
the Cape York meteorite,
541
00:31:02,120 --> 00:31:05,080
a very large meteorite
which was found in Greenland.
542
00:31:05,080 --> 00:31:07,400
This knife actually
came from Greenland,
543
00:31:07,400 --> 00:31:09,760
but we're not actually sure
that's right, now,
544
00:31:09,760 --> 00:31:12,000
we think it might be
from somewhere else.
545
00:31:12,000 --> 00:31:14,840
I gather that you've performed
an analysis on this
546
00:31:14,840 --> 00:31:18,480
and more research suggests
that you are beginning to question
547
00:31:18,480 --> 00:31:21,720
whether this is a meteorite,
but it has to be naturally occurring
548
00:31:21,720 --> 00:31:23,960
because they didn't have the
technology.
549
00:31:23,960 --> 00:31:27,000
Exactly. They didn't have
the technology to extract iron
550
00:31:27,000 --> 00:31:29,800
from things like hematite
so they had to have a source
551
00:31:29,800 --> 00:31:31,680
of native iron, metallic iron.
552
00:31:31,680 --> 00:31:34,480
We think now that maybe
this is actually from a place
553
00:31:34,480 --> 00:31:35,800
called Disko Island,
554
00:31:35,800 --> 00:31:38,560
which is an island off the west coast
of Greenland,
555
00:31:38,560 --> 00:31:41,720
and it's one of the very
few locations on earth
556
00:31:41,720 --> 00:31:45,760
where you get metallic iron
existing in metallic form.
557
00:31:45,760 --> 00:31:49,320
You very kindly brought
a couple of samples for us.
558
00:31:49,320 --> 00:31:52,600
These are from Disko Island.
559
00:31:52,600 --> 00:31:56,680
They look quite different but this
one clearly looks very metallic.
560
00:31:56,680 --> 00:31:59,320
You can see this here,
it's got quite a shine to it.
561
00:31:59,320 --> 00:32:02,080
It's quite a heavy specimen.
It is very heavy.
562
00:32:02,080 --> 00:32:05,920
This looks like a piece of iron but
this is naturally occurring iron?
563
00:32:05,920 --> 00:32:09,440
This is naturally occurring iron
found at the surface of the Earth.
564
00:32:09,440 --> 00:32:12,000
In fact, tons of this iron
has been found.
565
00:32:12,000 --> 00:32:15,720
But why hasn't this one
corroded into the hematite?
566
00:32:15,720 --> 00:32:19,600
What we think happened is that
about 55 million years ago,
567
00:32:19,600 --> 00:32:22,240
lava was erupted in this place,
in Disko Island,
568
00:32:22,240 --> 00:32:24,280
and as the lava was coming up,
569
00:32:24,280 --> 00:32:28,640
it went through sedimentary rocks
that have got a lot of carbon in,
570
00:32:28,640 --> 00:32:30,480
and the lava picked the carbon up
571
00:32:30,480 --> 00:32:33,960
and you've got a chemical reaction
happening where the iron,
572
00:32:33,960 --> 00:32:37,160
which was bonded with oxygen
just like here in the hematite,
573
00:32:37,160 --> 00:32:41,160
actually became metallic iron.
It reduced the iron from the lava.
574
00:32:41,160 --> 00:32:44,600
We can see this is also
a sample of iron, so this is iron.
575
00:32:44,600 --> 00:32:47,440
This is a sample of lava
from Disko Island
576
00:32:47,440 --> 00:32:51,160
so there is some metal in there
but not as big as that.
577
00:32:51,160 --> 00:32:54,360
This one is a very grey colour
and that's due to the graphite
578
00:32:54,360 --> 00:32:55,800
and carbon in here?
579
00:32:55,800 --> 00:32:59,160
You can see a bit
of a smudge on the paper.
580
00:32:59,160 --> 00:33:00,960
There's a black smear there.
581
00:33:00,960 --> 00:33:04,520
That's just from the carbon that's
present in here, the graphite?
582
00:33:04,520 --> 00:33:08,520
That's right. Actually, we've got
a clip of a blast furnace to show.
583
00:33:08,520 --> 00:33:11,000
This is how iron is now manufactured
584
00:33:11,000 --> 00:33:15,680
and this is using carbon to steal
away the oxygen from the iron ore,
585
00:33:15,680 --> 00:33:16,920
from the hematite.
586
00:33:16,920 --> 00:33:19,760
This is how we're producing iron but
what you're saying now is that...
587
00:33:19,760 --> 00:33:23,120
Nature beat us to it
about 55 million years ago.
588
00:33:23,120 --> 00:33:25,440
Exactly. That is quite amazing.
589
00:33:25,440 --> 00:33:29,640
Thank you very much for bringing
these samples on.
590
00:33:33,360 --> 00:33:37,000
Now, I really wanted to produce
some molten iron for you
591
00:33:37,000 --> 00:33:40,480
here in the lecture theatre,
but clearly we couldn't bring in
592
00:33:40,480 --> 00:33:43,520
a blast furnace, so we had to think
of another way to do this.
593
00:33:43,520 --> 00:33:46,160
We can learn
from what we did earlier,
594
00:33:46,160 --> 00:33:49,880
when we used the magnesium metal
to steal the oxygen away
595
00:33:49,880 --> 00:33:51,680
from the carbon dioxide.
596
00:33:51,680 --> 00:33:54,440
We can do the same thing now
with our iron oxide.
597
00:33:54,440 --> 00:33:56,640
We can use a more reactive metal
598
00:33:56,640 --> 00:33:59,760
and we are going to use
the metal, aluminium.
599
00:33:59,760 --> 00:34:04,800
You may be wondering why there's
a safe under here.
600
00:34:04,800 --> 00:34:08,200
This is because we have a bit
of an embarrassing story here.
601
00:34:08,200 --> 00:34:14,760
We accidentally locked Andy's
Christmas bonus in the safe.
602
00:34:14,760 --> 00:34:18,360
We tried getting into the safe
and it's pretty hard.
603
00:34:18,360 --> 00:34:24,280
It's made of pretty solid stuff.
We can't really get into this
604
00:34:24,280 --> 00:34:28,280
but the energy generated
as the oxygen is taken away
605
00:34:28,280 --> 00:34:32,840
by the aluminium to form iron
should be enough to get in here.
606
00:34:32,840 --> 00:34:34,880
Can we have a little look in here?
607
00:34:34,880 --> 00:34:38,360
Get the camera right in to show
what's inside this vessel.
608
00:34:38,360 --> 00:34:42,400
This is made of a very tough form
of carbon. This is made of graphite,
609
00:34:42,400 --> 00:34:45,080
and you may be able to see
the orangey colour.
610
00:34:45,080 --> 00:34:49,720
That's our iron oxide.
It's mixed with aluminium powder.
611
00:34:49,720 --> 00:34:53,400
The thing you see sticking out there
is a little bit of magnesium
612
00:34:53,400 --> 00:34:55,640
I'm going to use to start
this reaction.
613
00:34:55,640 --> 00:34:58,040
Hopefully, we should generate
some iron
614
00:34:58,040 --> 00:35:00,480
and see if we can get through
into the safe.
615
00:35:00,480 --> 00:35:04,160
Sounds like a good idea, doesn't it?
If it's the only way to do it.
616
00:35:04,160 --> 00:35:08,880
I think we will need
a safety screen around this, though.
617
00:35:08,880 --> 00:35:14,720
I'm going to need a glove as well.
Thank you very much.
618
00:35:14,720 --> 00:35:18,360
Feeling confident? Yeah, I can't see
what could go wrong.
619
00:35:18,360 --> 00:35:20,800
What could possibly go wrong?
Exactly.
620
00:35:20,800 --> 00:35:24,440
Let's give it a go. You'll see
a bright white light first of all.
621
00:35:24,440 --> 00:35:26,640
That's just the magnesium
we saw earlier.
622
00:35:26,640 --> 00:35:29,520
The magnesium combining
with the oxygen from the air.
623
00:35:32,120 --> 00:35:37,040
OK. We should know when it starts.
I think it's started now!
624
00:35:37,040 --> 00:35:41,120
This is our little blast furnace
here. Look at that, fantastic.
625
00:35:41,120 --> 00:35:44,360
We've got some molten metal there.
Can we lose the safety screen?
626
00:35:44,360 --> 00:35:47,760
That would be good if we can
possibly take this off. Lovely job.
627
00:35:47,760 --> 00:35:53,200
Right off the top very carefully.
I'm just going to see...
628
00:35:53,200 --> 00:35:56,720
I'll give you that,
see if we can pick up this.
629
00:35:56,720 --> 00:35:59,800
What have we got here?
Yes, that's wonderful.
630
00:35:59,800 --> 00:36:02,800
It releases such an enormous amount
of energy
631
00:36:02,800 --> 00:36:06,920
as the aluminium combines with
the oxygen from the iron oxide.
632
00:36:06,920 --> 00:36:09,360
Good news, Andy.
Good news and bad news.
633
00:36:09,360 --> 00:36:12,800
The good news is there's a hole
in the top of the safe.
634
00:36:12,800 --> 00:36:16,480
The bad news is there's a lot
of smoke coming from outside.
635
00:36:16,480 --> 00:36:19,760
I think I've just found
the key as well!
636
00:36:19,760 --> 00:36:22,920
Now he finds the key! At least
we got into the safe, well done.
637
00:36:22,920 --> 00:36:25,800
Thank you very much for that.
638
00:36:25,800 --> 00:36:27,840
APPLAUSE
639
00:36:27,840 --> 00:36:31,120
We formed there during
that reaction aluminium oxide
640
00:36:31,120 --> 00:36:33,600
as the aluminium
took the oxygen away.
641
00:36:33,600 --> 00:36:36,400
This is how we find
aluminium in nature.
642
00:36:36,400 --> 00:36:40,320
We find it as aluminium oxide
and here's a sample here.
643
00:36:40,320 --> 00:36:43,480
What do you think of that?
644
00:36:43,480 --> 00:36:47,920
It is light and this is because
it's a very light metal, aluminium.
645
00:36:47,920 --> 00:36:52,640
How can we get
our aluminium out of this rock?
646
00:36:52,640 --> 00:36:56,080
This, for a long time,
was a great problem.
647
00:36:56,080 --> 00:37:00,160
It was only solved when chemists
realised they could use
648
00:37:00,160 --> 00:37:04,280
an even more reactive metal
and this was the metal over here,
649
00:37:04,280 --> 00:37:05,800
the metal potassium.
650
00:37:05,800 --> 00:37:09,080
When this was first discovered,
it was a bit of a curiosity.
651
00:37:09,080 --> 00:37:11,520
There was this amazing
substance, aluminium,
652
00:37:11,520 --> 00:37:13,960
and it did have very
remarkable properties.
653
00:37:13,960 --> 00:37:16,600
I'll need another volunteer
from the audience.
654
00:37:16,600 --> 00:37:18,000
We'll have someone this side.
655
00:37:18,000 --> 00:37:21,200
In the green, would you like
to come down, please?
656
00:37:21,200 --> 00:37:23,000
APPLAUSE
657
00:37:26,160 --> 00:37:30,240
Your name is? Ailish.
Ailish, OK, great.
658
00:37:30,240 --> 00:37:33,440
Obviously you've seen a lot
of aluminium before, haven't you?
659
00:37:33,440 --> 00:37:35,920
It's very cheap now because now
we have worked out
660
00:37:35,920 --> 00:37:38,520
how to extract it from the ores,
but initially,
661
00:37:38,520 --> 00:37:42,360
it was incredibly difficult and that
made it incredibly expensive.
662
00:37:42,360 --> 00:37:46,200
In fact, so valuable
and so strange that this chap,
663
00:37:46,200 --> 00:37:48,040
this is Napoleon III,
664
00:37:48,040 --> 00:37:51,120
he had a whole cutlery set
made from aluminium.
665
00:37:51,120 --> 00:37:54,160
I think we have some
aluminium utensils here
666
00:37:54,160 --> 00:37:56,600
so you have a look at these.
What do you think?
667
00:37:56,600 --> 00:37:58,960
Very light. They are very light,
aren't they?
668
00:37:58,960 --> 00:38:00,640
This was the remarkable thing.
669
00:38:00,640 --> 00:38:03,640
With Napoleon's cutlery set,
he had his cutlery,
670
00:38:03,640 --> 00:38:06,480
and it was so valuable
that if he had a huge feast,
671
00:38:06,480 --> 00:38:10,640
he would give his most honoured
guests the aluminium cutlery
672
00:38:10,640 --> 00:38:13,080
and all the rest
had to make do with gold.
673
00:38:13,080 --> 00:38:14,920
OK, it seems strange to us now
674
00:38:14,920 --> 00:38:17,320
because we do know
how to extract aluminium
675
00:38:17,320 --> 00:38:20,720
and it is incredibly abundant
and we can find loads of it around
676
00:38:20,720 --> 00:38:22,840
but it was very difficult
to get it out.
677
00:38:22,840 --> 00:38:25,440
Can I just say,
it does feel very light indeed.
678
00:38:25,440 --> 00:38:27,880
That is one
of the remarkable properties.
679
00:38:27,880 --> 00:38:30,880
It isn't actually
the lightest metal that's known.
680
00:38:30,880 --> 00:38:34,720
Do you know what the lightest metal
is? Lithium.
681
00:38:34,720 --> 00:38:38,480
Oh, yes, you're quite right. It is
lithium. Give us a wave, lithium!
682
00:38:38,480 --> 00:38:41,880
Lithium is in fact a metal
and it is incredibly light.
683
00:38:41,880 --> 00:38:46,200
We have made the world's first
lithium spoon,
684
00:38:46,200 --> 00:38:49,640
which is very exciting. Here it is.
685
00:38:49,640 --> 00:38:52,960
This is our special RI spoon.
686
00:38:54,920 --> 00:38:58,160
Isn't that beautiful?
Would you like to feel this?
687
00:38:58,160 --> 00:39:01,800
It's really light.
It really is. It's amazingly light.
688
00:39:01,800 --> 00:39:05,440
It feels almost like plastic
but it is solid metal.
689
00:39:05,440 --> 00:39:07,800
It is quite remarkable,
don't you think?
690
00:39:07,800 --> 00:39:12,480
This is my dinner, I think.
691
00:39:12,480 --> 00:39:17,560
Some soup. Of course,
cutlery sinks in it,
692
00:39:17,560 --> 00:39:22,160
but would you just drop it in
and step back?
693
00:39:22,160 --> 00:39:23,920
Look at that? First of all,
694
00:39:23,920 --> 00:39:26,960
it is incredibly light
and it's floating on the surface,
695
00:39:26,960 --> 00:39:28,440
but it's also reacting.
696
00:39:28,440 --> 00:39:31,880
I'm going to fish that out.
It's very reactive indeed.
697
00:39:31,880 --> 00:39:35,440
I don't think lithium spoons are
going to catch on at all, do you?
698
00:39:35,440 --> 00:39:38,480
This is because it's just
too reactive. Too explosive.
699
00:39:38,480 --> 00:39:41,120
Exactly, thank you very much indeed.
700
00:39:41,120 --> 00:39:43,680
APPLAUSE
701
00:39:46,280 --> 00:39:49,320
A bit of coughing there
just from the reaction
702
00:39:49,320 --> 00:39:51,960
as the lithium combines
with the oxygen.
703
00:39:51,960 --> 00:39:54,640
It's reacting with the water vapour.
704
00:39:54,640 --> 00:39:57,760
COUGHING
705
00:39:57,760 --> 00:40:03,720
Yes, yes. Thank you. The lithium
there, it floats on the surface.
706
00:40:03,720 --> 00:40:08,640
It is incredibly light but
it's incredibly reactive as well.
707
00:40:08,640 --> 00:40:11,880
That may be the world's
first lithium spoon
708
00:40:11,880 --> 00:40:16,360
but I think it's safe to say it's
also going to be the world's last.
709
00:40:16,360 --> 00:40:20,920
It does show how reactive lithium is
and maybe be can use this element
710
00:40:20,920 --> 00:40:23,800
to prepare new elements,
and we can indeed.
711
00:40:23,800 --> 00:40:30,000
We have a reaction here to generate
a new element from silicon dioxide.
712
00:40:30,000 --> 00:40:34,520
Does anyone know
where we find silicon dioxide?
713
00:40:34,520 --> 00:40:36,920
Any ideas, right at the back?
714
00:40:36,920 --> 00:40:39,400
In sand, you're quite right.
715
00:40:39,400 --> 00:40:43,120
We find silicon dioxide, it is sand.
716
00:40:45,000 --> 00:40:48,240
We've got some lithium in here
and some sand.
717
00:40:48,240 --> 00:40:51,880
We've mixed the two together, little
lithium pelts and some sand,
718
00:40:51,880 --> 00:40:56,720
and I'm going to heat this up
at the moment and see what happens.
719
00:40:56,720 --> 00:40:59,160
This is lithium with silicon dioxide
720
00:40:59,160 --> 00:41:02,440
and the silicon dioxide
is a mineral, it's just sand.
721
00:41:02,440 --> 00:41:04,880
Quartz is the same stuff,
silicon dioxide,
722
00:41:04,880 --> 00:41:08,960
so sand is smashed up
pieces of quartz.
723
00:41:08,960 --> 00:41:12,000
I'm hoping that we should see
a reaction take place
724
00:41:12,000 --> 00:41:14,640
and there we are.
725
00:41:14,640 --> 00:41:18,000
This is a very violent
reaction again
726
00:41:18,000 --> 00:41:21,960
and this is as the lithium
is stealing the oxygen away
727
00:41:21,960 --> 00:41:25,160
from the silicon dioxide
that makes up the sand.
728
00:41:27,040 --> 00:41:31,320
Anyone have a guess at what we're
going to make? Silicon, very good.
729
00:41:31,320 --> 00:41:35,560
We take the oxygen away
from the silicon dioxide
730
00:41:35,560 --> 00:41:38,760
and we end up with silicon.
731
00:41:38,760 --> 00:41:43,440
Remarkably, this is a single crystal
732
00:41:43,440 --> 00:41:47,160
of a very purified silicon.
733
00:41:47,160 --> 00:41:50,000
It's very valuable and very precious
734
00:41:50,000 --> 00:41:53,040
and I need to put on some
special gloves for this.
735
00:41:56,200 --> 00:42:00,440
It's hard, it's very solid.
736
00:42:00,440 --> 00:42:04,760
It's sort of like a metal
and it's incredibly heavy.
737
00:42:04,760 --> 00:42:08,880
Actually, I can hardly
lift this thing up,
738
00:42:08,880 --> 00:42:11,960
but it's grown in this
very special way here.
739
00:42:11,960 --> 00:42:13,840
This is one crystal of silicon
740
00:42:13,840 --> 00:42:17,200
but it has a seam running
all the way along the top here.
741
00:42:17,200 --> 00:42:21,160
This just proves that it is
in fact one crystal.
742
00:42:21,160 --> 00:42:23,400
Why do people grow these?
743
00:42:23,400 --> 00:42:26,960
They grow them
from the molten silicon.
744
00:42:26,960 --> 00:42:29,400
They would keep purifying it,
heating it
745
00:42:29,400 --> 00:42:33,240
and allowing it to cool into
this rather strange-looking shape.
746
00:42:33,240 --> 00:42:36,160
They do this because they're
trying to make these,
747
00:42:36,160 --> 00:42:40,480
and this is a silicon wafer.
748
00:42:40,480 --> 00:42:44,400
It's just a sheet of silicon,
just a slice from this,
749
00:42:44,400 --> 00:42:49,280
and these are used to make
silicon chips.
750
00:42:49,280 --> 00:42:53,040
This is the same slice of silicon
751
00:42:53,040 --> 00:42:59,240
and then they're etching in
and adding other reagents to this,
752
00:42:59,240 --> 00:43:02,240
gradually building up
the silicon chips that we have
753
00:43:02,240 --> 00:43:07,400
in our mobile phones
and in our computers.
754
00:43:10,080 --> 00:43:13,400
A fantastic use for this element,
silicon.
755
00:43:13,400 --> 00:43:17,000
The element we extract from sand.
756
00:43:17,000 --> 00:43:20,360
Chemists are always finding new uses
for the elements.
757
00:43:20,360 --> 00:43:23,640
Even though this has been known
for well over 100 years,
758
00:43:23,640 --> 00:43:27,680
it is only relatively recently
that we have found out
759
00:43:27,680 --> 00:43:30,760
how to use this element
to make silicon chips.
760
00:43:30,760 --> 00:43:31,960
So far in the lecture,
761
00:43:31,960 --> 00:43:35,400
we swapped elements around
to make different useful materials.
762
00:43:35,400 --> 00:43:38,480
We've stolen oxygen
from iron oxide to make iron,
763
00:43:38,480 --> 00:43:40,080
and we've stolen it from sand.
764
00:43:40,080 --> 00:43:43,400
We've even rearranged
the structures of carbon
765
00:43:43,400 --> 00:43:45,600
to turn graphite into diamond.
766
00:43:45,600 --> 00:43:51,040
What we still haven't done
is turn one element into another.
767
00:43:51,040 --> 00:43:53,680
That's what the alchemists were
trying to do,
768
00:43:53,680 --> 00:43:56,320
to turn lead into gold.
Is this possible?
769
00:43:56,320 --> 00:43:58,760
Can we turn one element
into another?
770
00:43:58,760 --> 00:44:03,240
Yes, this is
the process of radioactivity,
771
00:44:03,240 --> 00:44:08,040
and this occurs deep in the Earth
and indeed all around us.
772
00:44:08,040 --> 00:44:11,280
Can we have our periodic table up,
please?
773
00:44:11,280 --> 00:44:14,560
Those of you,
you elements who are radioactive,
774
00:44:14,560 --> 00:44:16,640
I'd like you to stand up, please.
775
00:44:16,640 --> 00:44:20,680
All the radioactive elements.
That's all of this front row here.
776
00:44:20,680 --> 00:44:22,320
Yes, you're all radioactive.
777
00:44:22,320 --> 00:44:25,080
Bismuth, we're not sure about you,
you're unknown,
778
00:44:25,080 --> 00:44:27,000
but actually you're so radioactive,
779
00:44:27,000 --> 00:44:29,040
you're no longer
who you thought you were.
780
00:44:29,040 --> 00:44:31,640
You'd better sit down again.
What does that mean?
781
00:44:31,640 --> 00:44:33,320
Why do you have to sit down again?
782
00:44:33,320 --> 00:44:36,080
It's because
during radioactive decay,
783
00:44:36,080 --> 00:44:40,160
an element changes
into another element.
784
00:44:40,160 --> 00:44:42,920
If we have cards down for a moment,
please?
785
00:44:42,920 --> 00:44:46,600
Remember,
what makes an element unique
786
00:44:46,600 --> 00:44:49,720
is the heart of the atom itself.
787
00:44:49,720 --> 00:44:54,040
That's the number of protons
that it has within it.
788
00:44:54,040 --> 00:44:57,520
This represents
what's inside an atom.
789
00:44:57,520 --> 00:45:01,600
This is its nucleus, and we have to
count the number of the red spheres,
790
00:45:01,600 --> 00:45:03,360
these represent the protons,
791
00:45:03,360 --> 00:45:05,600
to work out what element this is.
792
00:45:05,600 --> 00:45:08,040
In fact, this is the element
uranium.
793
00:45:08,040 --> 00:45:13,480
The thing about uranium is - oops -
it's unstable,
794
00:45:13,480 --> 00:45:15,520
and bits drop off.
795
00:45:15,520 --> 00:45:17,600
The nucleus here just gets so large
796
00:45:17,600 --> 00:45:21,840
that it's very difficult for all
these things to stay together
797
00:45:21,840 --> 00:45:25,120
and, yes, bits do drop off
and when they drop off,
798
00:45:25,120 --> 00:45:27,440
it's changed into different element.
799
00:45:27,440 --> 00:45:31,760
It's the number of the red protons
that define an element,
800
00:45:31,760 --> 00:45:33,040
so if we lose two,
801
00:45:33,040 --> 00:45:37,080
it's no longer what we thought
it was to start off with.
802
00:45:37,080 --> 00:45:40,320
Can we find uranium in our periodic
table. Where's uranium?
803
00:45:40,320 --> 00:45:44,800
Would you like to stand up?
804
00:45:44,800 --> 00:45:49,040
Uranium, you are radioactive,
and bits do drop off.
805
00:45:49,040 --> 00:45:51,720
Quite slowly, don't worry,
we won't notice.
806
00:45:51,720 --> 00:45:55,040
But actually when it does happen,
when it does fall off,
807
00:45:55,040 --> 00:45:57,080
you change into a different element
808
00:45:57,080 --> 00:45:59,200
and you move a couple
of spaces along.
809
00:45:59,200 --> 00:46:02,480
You become thorium, so maybe you
should move over to thorium.
810
00:46:02,480 --> 00:46:07,480
Better put your card down because
you're not "U" any more. Get it?
811
00:46:07,480 --> 00:46:10,400
You're no longer you,
you're actually thorium.
812
00:46:10,400 --> 00:46:13,880
You'd better go over there,
you are on thorium's space now.
813
00:46:13,880 --> 00:46:18,520
Actually, both thorium
and uranium have also decayed,
814
00:46:18,520 --> 00:46:22,600
and if you decay now, you're going
to become the element radon.
815
00:46:22,600 --> 00:46:25,960
You're also radioactive, I'm afraid,
so if you decay,
816
00:46:25,960 --> 00:46:29,520
you lose a couple of protons
in an alpha particle.
817
00:46:29,520 --> 00:46:33,120
You're not radon any more,
you've become polonium.
818
00:46:33,120 --> 00:46:34,920
Can we see this in action?
819
00:46:34,920 --> 00:46:38,640
We can, using this apparatus here.
820
00:46:38,640 --> 00:46:42,160
This is known as a cloud chamber.
821
00:46:42,160 --> 00:46:49,920
The tank that we see here contains
an atmosphere of alcohol vapour
822
00:46:49,920 --> 00:46:52,480
and it's got a lot of vapour
in there
823
00:46:52,480 --> 00:46:55,680
and it's actually trying
to form little droplets.
824
00:46:55,680 --> 00:46:57,520
There's a temperature gradient.
825
00:46:57,520 --> 00:47:00,720
There's a little heating wire
at the top and it's cooled down
826
00:47:00,720 --> 00:47:03,160
from underneath,
so it's gradually freezing.
827
00:47:03,160 --> 00:47:07,520
It wants to form droplets
but actually it's much easier
828
00:47:07,520 --> 00:47:09,720
if there's something there
to help it.
829
00:47:09,720 --> 00:47:12,720
Any charged particles
can cause this.
830
00:47:12,720 --> 00:47:16,000
All the tracks that you can see now,
831
00:47:16,000 --> 00:47:18,840
all these little wispy white trails,
832
00:47:18,840 --> 00:47:24,040
are actually particles of radiation.
833
00:47:24,040 --> 00:47:28,400
This is natural radiation
just in the air around us.
834
00:47:28,400 --> 00:47:32,120
We don't tend to think of
radioactivity as being very natural,
835
00:47:32,120 --> 00:47:34,880
but of course,
we're all weakly radioactive
836
00:47:34,880 --> 00:47:37,520
because of some of
the radioactive elements in us.
837
00:47:37,520 --> 00:47:42,880
Here, we can see radiation in action
here just in the air around us.
838
00:47:42,880 --> 00:47:48,640
I'm going to introduce into this
a sample of a radioactive element
839
00:47:48,640 --> 00:47:52,120
called americium.
840
00:47:52,120 --> 00:47:57,440
Look at that.
You can see the tracks forming here.
841
00:48:00,680 --> 00:48:06,640
Each little track that we see is the
result of a charged particle
842
00:48:06,640 --> 00:48:12,280
being emitted
from the element americium
843
00:48:12,280 --> 00:48:16,960
and the particles emitted
are alpha particles.
844
00:48:16,960 --> 00:48:21,800
The alpha particle is two protons,
two neutrons,
845
00:48:21,800 --> 00:48:26,040
and actually that is the heart
of an atom of helium.
846
00:48:26,040 --> 00:48:31,600
What we're actually seeing here
is the birth of helium atoms,
847
00:48:31,600 --> 00:48:37,440
which I think is quite remarkable.
I'll just put this away.
848
00:48:37,440 --> 00:48:42,120
It is possible then
to change one atom into another.
849
00:48:42,120 --> 00:48:45,720
Nature seems to do this, but can we?
850
00:48:45,720 --> 00:48:47,720
Actually, it is possible,
851
00:48:47,720 --> 00:48:51,480
and one of the first people to
generate lots of different atoms
852
00:48:51,480 --> 00:48:54,520
was this chap here, Glenn Seaborg.
853
00:48:54,520 --> 00:48:58,560
In fact, he even has an element
named after him.
854
00:48:58,560 --> 00:49:00,800
Where's seaborgium? There we are,
855
00:49:00,800 --> 00:49:03,440
right in the middle
of the periodic table.
856
00:49:03,440 --> 00:49:08,400
In 1980, Seaborg did
an amazing experiment.
857
00:49:08,400 --> 00:49:13,200
He took bismuth
and he turned it into gold.
858
00:49:13,200 --> 00:49:16,520
This is what the alchemists
had been dreaming of.
859
00:49:16,520 --> 00:49:18,520
He changed one element into gold.
860
00:49:18,520 --> 00:49:20,240
What he did was take bismuth -
861
00:49:20,240 --> 00:49:23,400
can we have our periodic table
up for a second, please?
862
00:49:23,400 --> 00:49:28,240
He took the element bismuth and
he fired atoms of carbon and neon
863
00:49:28,240 --> 00:49:32,440
at this and it knocked out
a number of protons
864
00:49:32,440 --> 00:49:35,280
until we ended up with gold.
865
00:49:35,280 --> 00:49:39,040
Unfortunately, he only ended up
with the few thousand atoms
866
00:49:39,040 --> 00:49:41,440
and this is not enough
to get him rich.
867
00:49:41,440 --> 00:49:45,000
It was a very expensive experiment,
took a lot of money to get this
868
00:49:45,000 --> 00:49:49,560
and all he made was a few atoms,
but it is possible to do it.
869
00:49:49,560 --> 00:49:53,400
Radioactivity is a natural process
but it can also be brought about
870
00:49:53,400 --> 00:49:55,920
by firing one atom at another,
871
00:49:55,920 --> 00:49:59,880
and changing it and creating new,
heavier elements
872
00:49:59,880 --> 00:50:01,720
or even to make gold.
873
00:50:01,720 --> 00:50:03,520
Do we even want to make gold?
874
00:50:03,520 --> 00:50:06,160
Are there other things
that fascinated the alchemists
875
00:50:06,160 --> 00:50:09,480
which modern scientists
have taken one step further?
876
00:50:09,480 --> 00:50:12,120
This is another
naturally occurring rock
877
00:50:12,120 --> 00:50:15,160
that has really quite
remarkable properties.
878
00:50:15,160 --> 00:50:18,640
This one amazed
the early alchemists.
879
00:50:18,640 --> 00:50:20,440
I'll show you why.
880
00:50:20,440 --> 00:50:23,920
Over here, our audience members
have some paper clips.
881
00:50:23,920 --> 00:50:26,720
Have you got some paper clips?
882
00:50:26,720 --> 00:50:31,200
I'd like you to put your paper clips
onto here, just onto the rock.
883
00:50:32,800 --> 00:50:35,800
They should stick by themselves.
884
00:50:35,800 --> 00:50:39,960
It's not a surprise to us because
we've all seen magnets before,
885
00:50:39,960 --> 00:50:44,120
but just imagine if you were the
first person to ever see a magnet.
886
00:50:44,120 --> 00:50:46,840
I have a book here from the 1530s
887
00:50:46,840 --> 00:50:51,480
that describes this magnetic rock,
this lodestone.
888
00:50:51,480 --> 00:50:54,320
They really did find it
quite remarkable.
889
00:50:54,320 --> 00:50:56,960
This here shows this magnetic rock.
890
00:50:56,960 --> 00:51:02,720
There's a ship sailing past
a mountain that's supposedly made
891
00:51:02,720 --> 00:51:06,440
of this lodestone,
this magnetic ore.
892
00:51:06,440 --> 00:51:10,080
You can see here, these are
the nails from the ship.
893
00:51:10,080 --> 00:51:14,280
They've supposedly been sucked
out of the ship, so this is
894
00:51:14,280 --> 00:51:18,520
a sort of warning that there's this
incredibly strange magical material
895
00:51:18,520 --> 00:51:22,040
with these amazing properties
which would suck the nails
896
00:51:22,040 --> 00:51:24,680
out of your ship
and you'd be shipwrecked.
897
00:51:24,680 --> 00:51:28,880
There's a warning for you.
OK, thank you.
898
00:51:28,880 --> 00:51:35,000
Nowadays, scientists have learned
how to make even stronger magnets
899
00:51:35,000 --> 00:51:38,240
from the elements, and if we just
have our periodic table up again,
900
00:51:38,240 --> 00:51:45,720
some of the strongest magnets
now made use the element neodymium.
901
00:51:45,720 --> 00:51:49,600
Give us a wave, up there, very good.
902
00:51:49,600 --> 00:51:54,040
The strongest magnets in the world
are made with neodymium.
903
00:51:54,040 --> 00:51:56,320
This element was discovered
in the 1880s,
904
00:51:56,320 --> 00:52:00,960
but it was over 100 years later
that scientists learnt how to use
905
00:52:00,960 --> 00:52:03,800
this element
to create these magnets.
906
00:52:03,800 --> 00:52:06,080
Thank you very much, periodic table.
907
00:52:06,080 --> 00:52:08,120
I have a couple
of these magnets here
908
00:52:08,120 --> 00:52:10,840
and they really
are very strong indeed.
909
00:52:10,840 --> 00:52:13,600
These are little neodymium magnets.
910
00:52:13,600 --> 00:52:16,640
Here we are, just try to pull
these apart?
911
00:52:16,640 --> 00:52:19,240
I can't. Are they stuck together?
912
00:52:19,240 --> 00:52:22,480
No, they're not stuck together.
Try again.
913
00:52:22,480 --> 00:52:26,120
Give them to your neighbour,
see if he can get them?
914
00:52:26,120 --> 00:52:28,400
Can you pull those apart? No.
915
00:52:28,400 --> 00:52:31,240
I promise you
they're not stuck together.
916
00:52:31,240 --> 00:52:36,120
I could probably slide them or
something if I push. Look at that.
917
00:52:36,120 --> 00:52:39,360
They're very strong magnets indeed.
918
00:52:39,360 --> 00:52:43,640
Even though the element neodymium
has been known for over 100 years,
919
00:52:43,640 --> 00:52:47,720
these magnets have only
recently been developed.
920
00:52:47,720 --> 00:52:49,760
Now, these really are quite strong
921
00:52:49,760 --> 00:52:54,920
and I think to show just how strong
these are, I need another volunteer.
922
00:52:54,920 --> 00:52:58,480
I think we should have
one from this side.
923
00:52:58,480 --> 00:53:02,480
Would you like to come down
to the front, please?
924
00:53:02,480 --> 00:53:05,760
APPLAUSE
925
00:53:05,760 --> 00:53:09,600
OK, very good. Are you feeling
strong? You are, that's good.
926
00:53:09,600 --> 00:53:12,240
Tell us your name, please.
Marie. Marie.
927
00:53:12,240 --> 00:53:15,960
We're just going
to bring down this rig here.
928
00:53:15,960 --> 00:53:19,440
We're going to suspend you
from the ceiling
929
00:53:19,440 --> 00:53:23,240
using this little magnet here.
That's the only magnet.
930
00:53:23,240 --> 00:53:26,080
This is a block of iron.
It's not magnetic.
931
00:53:26,080 --> 00:53:27,920
I can show that with a paper clip,
932
00:53:27,920 --> 00:53:30,920
just holding the paper clip,
it stays on it
933
00:53:30,920 --> 00:53:32,760
but it's not attracted to it.
934
00:53:32,760 --> 00:53:34,120
This is our magnet.
935
00:53:34,120 --> 00:53:37,680
I'm not going to put the paper clip
on this, I'd never get it off again.
936
00:53:37,680 --> 00:53:39,920
If you'd like
to come over here, please.
937
00:53:39,920 --> 00:53:43,360
I just need to very carefully
put this in the middle. Perfect.
938
00:53:43,360 --> 00:53:47,000
Just clip this on as well.
939
00:53:47,000 --> 00:53:51,480
OK, so you're feeling strong?
940
00:53:51,480 --> 00:53:55,440
If you just hold on to here.
That's it.
941
00:53:55,440 --> 00:53:58,040
Can you just raise up the
winch then, please?
942
00:53:58,040 --> 00:54:01,840
Hold on strong, hold on tightly and
we'll just see if we can lift you
943
00:54:01,840 --> 00:54:04,640
off the ground so you need
to hold on very tightly.
944
00:54:04,640 --> 00:54:06,720
Might need to move forward
a little bit.
945
00:54:06,720 --> 00:54:09,160
Keep holding on
and just watch the feet.
946
00:54:09,160 --> 00:54:10,960
There we are, look at that!
947
00:54:10,960 --> 00:54:14,920
You are now suspended
from the ceiling. That's fantastic!
948
00:54:14,920 --> 00:54:17,280
APPLAUSE
949
00:54:19,800 --> 00:54:22,160
It really is pretty strong
magnets there.
950
00:54:22,160 --> 00:54:24,160
We can actually hang from them.
951
00:54:24,160 --> 00:54:27,640
It's just using the power
of these new magnets
952
00:54:27,640 --> 00:54:30,880
but these are incredibly useful
and they find uses for instance
953
00:54:30,880 --> 00:54:36,040
in turbines, but are also used
in electric cars and so on as well.
954
00:54:36,040 --> 00:54:39,200
These new materials -
very, very useful.
955
00:54:39,200 --> 00:54:43,320
We can create even more amazing
materials using the elements.
956
00:54:43,320 --> 00:54:46,160
Can we just have our periodic table
up for a moment?
957
00:54:46,160 --> 00:54:48,520
We were using magnets
there to suspend
958
00:54:48,520 --> 00:54:50,920
and these were
the neodymium magnets,
959
00:54:50,920 --> 00:54:54,040
but this, we're going to use
some superconductors
960
00:54:54,040 --> 00:54:58,280
and the superconductors
are made from the elements yttrium,
961
00:54:58,280 --> 00:55:01,360
just here. Give us a wave, yttrium.
962
00:55:01,360 --> 00:55:05,840
And from barium, so give us
a wave, barium. Very good.
963
00:55:05,840 --> 00:55:09,400
And copper.
OK, there's copper,
964
00:55:09,400 --> 00:55:12,520
and oxygen at the top there.
965
00:55:12,520 --> 00:55:17,280
Put you four elements together
and we get these amazing materials -
966
00:55:17,280 --> 00:55:19,440
high-temperature superconductors.
967
00:55:19,440 --> 00:55:23,640
This is called a Mobius strip.
It's a rather strange looking thing.
968
00:55:23,640 --> 00:55:27,680
How many sides has this got? Two.
Well, you'd think so.
969
00:55:27,680 --> 00:55:31,600
Actually, if you start here
and you keep on going round,
970
00:55:31,600 --> 00:55:34,280
you actually come back underneath.
971
00:55:34,280 --> 00:55:37,920
If you keep going round, you come
back where you started from.
972
00:55:37,920 --> 00:55:40,800
It actually has one side,
this mathematical shape,
973
00:55:40,800 --> 00:55:42,600
which is very unusual.
974
00:55:42,600 --> 00:55:46,440
I can show you this using
our little superconductor.
975
00:55:46,440 --> 00:55:50,680
This Mobius strip is covered
with these neodymium magnets,
976
00:55:50,680 --> 00:55:54,160
these very strong magnets.
We've got a superconductor here
977
00:55:54,160 --> 00:55:56,760
and this is the superconductor
978
00:55:56,760 --> 00:56:01,680
that's made from the barium, the
yttrium, the copper and the oxygen.
979
00:56:01,680 --> 00:56:05,280
This is the ceramic there.
This is this disc in the centre.
980
00:56:05,280 --> 00:56:07,760
We are cooling it
with liquid nitrogen
981
00:56:07,760 --> 00:56:11,440
in this little holding tray
on the top.
982
00:56:11,440 --> 00:56:13,000
It levitates quite nicely.
983
00:56:18,280 --> 00:56:22,760
There we are, it's come back
to where it was.
984
00:56:22,760 --> 00:56:26,760
Now it's actually hanging
underneath this strip,
985
00:56:26,760 --> 00:56:28,280
but it needs to be cooled down
986
00:56:28,280 --> 00:56:30,560
so we are cooling it
with liquid nitrogen.
987
00:56:30,560 --> 00:56:34,440
That's in order to enable
these superconductors to work.
988
00:56:34,440 --> 00:56:36,840
They only work at these
very low temperatures,
989
00:56:36,840 --> 00:56:40,480
so eventually it's going to warm up
and it will fall off the track
990
00:56:40,480 --> 00:56:43,600
so you need to catch it
when it does fall.
991
00:56:43,600 --> 00:56:45,920
You're meant to catch it!
992
00:56:45,920 --> 00:56:49,200
Just pass it to me straight away,
thank you. That's lovely.
993
00:56:51,040 --> 00:56:54,480
Thank you very much.
Thank you for all your help there.
994
00:56:54,480 --> 00:56:56,760
APPLAUSE
995
00:57:04,000 --> 00:57:07,680
Really quite remarkable properties
then of this ceramic
996
00:57:07,680 --> 00:57:11,840
made out of the elements barium,
yttrium, copper and oxygen.
997
00:57:11,840 --> 00:57:15,000
We've come a long way
since the days of the alchemists
998
00:57:15,000 --> 00:57:20,000
when the whole world could be made
from air, water, earth and fire.
999
00:57:20,000 --> 00:57:22,520
I hope you've enjoyed our quest
to discover
1000
00:57:22,520 --> 00:57:25,160
what's really making up
the world around us.
1001
00:57:25,160 --> 00:57:28,280
If you remember one thing
from these lectures,
1002
00:57:28,280 --> 00:57:30,720
it's that the work of the chemist
is not complete.
1003
00:57:30,720 --> 00:57:34,200
New combinations are being
discovered all the time
1004
00:57:34,200 --> 00:57:37,960
and nobody knows what exciting
properties they may have.
1005
00:57:37,960 --> 00:57:40,760
I'd like everyone to pick up
your cards one last time
1006
00:57:40,760 --> 00:57:42,960
and have a look at your card.
1007
00:57:42,960 --> 00:57:47,040
Just remember what element you've
got, and I want you to go home
1008
00:57:47,040 --> 00:57:49,120
and research about your element
1009
00:57:49,120 --> 00:57:52,200
and think what uses
can we put this element to,
1010
00:57:52,200 --> 00:57:55,640
and what new possibilities
could there be? Who knows?
1011
00:57:55,640 --> 00:57:59,120
You may be able to solve some
of the challenges of the future
1012
00:57:59,120 --> 00:58:03,120
and maybe even make something
more valuable than gold.
1013
00:58:03,120 --> 00:58:05,680
Thank you and goodnight.
1014
00:58:05,680 --> 00:58:06,560
APPLAUSE
1015
00:58:09,840 --> 00:58:12,760
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