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Early alchemists
wrote of a Fountain of Youth,
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00:00:05,320 --> 00:00:07,960
and for centuries kings
and explorers searched
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00:00:07,960 --> 00:00:10,720
for this legendary spring
that would restore the youth
4
00:00:10,720 --> 00:00:12,160
to anyone who drank from it.
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Does such a place even exist?
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And, if it does,
what incredible elements
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might we find in its waters?
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Join us in the search
for the Fountain of Youth.
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APPLAUSE
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Many people searched
for the Fountain of Youth,
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but one of the most famous was
the 16th Century Spanish explorer
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Juan Ponce de Leon,
who spent his life
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trying to hang onto his good looks.
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And legend has it that he found
the Fountain in Florida.
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Local people claimed this miraculous
spring could even restore
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frail old men to perfect health
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and, incredibly,
the spring is still there.
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On the screen now we
can see the workers
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filling bottles from
this Fountain of Youth
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And they've sent us a sample
by airmail.
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Here we have our Fountain of Youth.
I can't wait.
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Right, let's have a look.
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"It's on the shelf." OK.
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Right, so here it is.
They've put it over here.
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So here is the Fountain of Youth.
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It really has come all
the way from Florida
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which is quite exciting,
but we need somebody to try it.
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Do I have a volunteer?
Some hands went up...
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I'm afraid I can't give it
to anyone down the front.
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You're far too young already.
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If I gave you this,
who knows what might happen.
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We need somebody
slightly more mature,
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slightly more advanced in years.
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I'm looking at the top, actually,
and...
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Oh, yes, there's a chap
right on the end.
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What's your name, please? Tim.
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Tim. And you'd like to try
some of the Fountain of Youth?
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I'll give it a go.
You'll give it a go.
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That's very good of you.
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I think we've arranged for some to
be brought up to you.
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LAUGHTER
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Goodness me. Is it safe?
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DR WOTHERS LAUGHS
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Well...
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Don't drink it all!
Save some for later!
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So, are you feeling any younger?
Not yet.
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Not yet? No wrinkles lost yet?
Don't know. Don't know. OK.
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We'll come back to you
later and see how it is going,
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but you were very good.
You must be a chemistry teacher.
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You did ask, "Is it safe to drink?"
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You shouldn't be drinking in the
chemistry lab, so well done there.
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Thank you very much.
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A round of applause for Tim
for trying our water.
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APPLAUSE
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This year's Royal Institution
Christmas Lectures
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are all about the elements.
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My name is Dr Peter Wothers,
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and I'm a Fellow of The Royal
Society of Chemistry.
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The ancient Greeks thought
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there were just four elements
that made up everything around them.
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These are the elements earth,
air, fire and water.
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Last time we looked at
the elements in the air,
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and tonight we're going to be
looking at the elements in a glass
of water,
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in fact, the water that Tim
has just drunk, to be precise.
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To help me, we're going to
be using our periodic table.
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Periodic table. Look at that.
Excellent.
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Very good, everyone's here.
Marvellous.
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We now know, of course, that we've
got over 100 different elements.
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Together, we're going to see what
elements we can find in our water
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and maybe we're going to find
something quite miraculous
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in our glass of water,
the water that Tim's just drunk.
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OK. Right, I need to put on
my coat, ready for action now.
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So, thank you, periodic table.
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Excellent. Oh, you're so
well-trained, really! Excellent.
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That's perfect, look at that.
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So, our periodic table, we saw that
there's over 100 elements.
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And yet, water, of course, isn't one
of these elements. We know this now.
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But this was only first realised
about 200 years ago, just over.
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So, why was that? Well, partly
because nobody had ever done this.
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BOOMING EXPLOSION
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ALL GASP AND GIGGLE
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Well!
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That seemed to bring the house down!
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APPLAUSE
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That was certainly rather dramatic!
86
00:05:05,520 --> 00:05:08,800
But what we actually did there
is just make some water.
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The balloon
was filled with hydrogen...
88
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which, of course,
when we light it...
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combines with the oxygen
from the air...
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to form water.
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OK. Now, that was rather violent,
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and we couldn't see
any of the water that we made
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because as soon as it was made, all
that energy that was released there
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vaporised it and disbursed all the
droplets into the lecture theatre.
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But we can do this
in a more controlled way,
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so we can actually see
some of the water being formed.
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And, well, this is the apparatus
that we're just bringing on now.
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OK, so...
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We're going to combine
our hydrogen and oxygen
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in this carefully designed
apparatus.
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And we're passing pure oxygen
through this,
102
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and Mark is just going to pass me
a tube with some hydrogen.
103
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And let's just light that.
Ah, beautiful.
104
00:06:06,260 --> 00:06:08,540
It's very difficult to see
this flame sometimes
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because hydrogen burns with
more or less a colourless flame.
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I think there's a few impurities
in the glass there,
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but you can see it's definitely
lit, it's definitely going.
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I'm just going to insert this
into the apparatus.
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I hope I don't catch fire
to our little things there!
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There we are, look at that,
beautiful, right.
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So, just insert this.
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In fact, as it's going in,
the flame gets much hotter,
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because this is an oxygen-rich
environment in this apparatus.
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And it's just beginning to vaporise
some of the glass.
115
00:06:38,100 --> 00:06:40,620
And this yellow colour
that you see now
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is excited sodium atoms
from the glass.
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00:06:43,380 --> 00:06:46,500
But I'd like everyone to keep an eye
on this during the reaction.
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This is like our little
Olympic flame.
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If this goes out, please let me know
during the course of the reaction,
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I'm trying to generate enough water
to maybe taste it later.
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We'll have to see,
we're using very pure gases here.
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The important thing that we can see
is that we've got our flame,
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it's clearly very hot,
but we are generating water.
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You can see that this is misting up
now at the top here,
125
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and we're beginning to get some
water and it's dribbling down here.
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So this is actually showing us that
water is not an element after all.
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It's made up of these two gases,
hydrogen and oxygen.
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This, as we are forming these bonds
here, is releasing a lot of energy.
129
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This is, as we're making new bonds
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between hydrogen atoms
and oxygen atoms,
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forming our droplets of water,
that are beginning to collect now.
132
00:07:33,220 --> 00:07:37,740
But I'd like to show you another
reaction that clearly generates
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a lot of energy, a lot of heat
as molecules are coming together,
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00:07:41,580 --> 00:07:45,100
as bonds are being formed,
and this one is quite miraculous.
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00:07:45,100 --> 00:07:47,220
This is one of my
favourite reactions,
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because it really does
look like magic.
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What we've got here is
a tube just of cold water.
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Everyone knows what temperature
water freezes at, don't we?
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00:07:56,140 --> 00:07:58,020
What temperature does it freeze at?
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00:07:58,020 --> 00:08:00,020
ALL: Zero.
Zero, exactly.
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So here it's coming, this is
a test tube full of cold water.
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Thank you very much.
143
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What temperature is this water at?
Minus three.
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Minus three, this one.
So this is actually at minus three.
145
00:08:12,220 --> 00:08:17,460
And yet, of course, we know that
water SHOULD be ice at minus three,
146
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and yet it isn't. OK?
147
00:08:19,700 --> 00:08:23,540
Now, watch what happens when I add
just a tiny little crystal of ice.
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This is now freezing. OK?
149
00:08:27,620 --> 00:08:32,580
So you can see that this water
is turning into ice.
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00:08:32,580 --> 00:08:35,260
In fact, the ice is
all the way down to here now.
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00:08:36,300 --> 00:08:40,460
So we know that water should be
ice at minus three degrees,
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and it is now becoming ice
at minus three degrees. OK?
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00:08:44,900 --> 00:08:47,940
In fact, let me see if I can
actually turn this upside down.
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Can I do that?
There's a little bit dribbling out,
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but there we are,
it is in fact solid ice there.
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That's pretty impressive, I think.
Let's hand that out, thank you.
157
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Now... How can we...?
158
00:09:04,780 --> 00:09:06,420
So, how can we do this?
159
00:09:06,420 --> 00:09:09,460
We need to be very careful, it's
like trying to balance this pen.
160
00:09:09,460 --> 00:09:12,260
I was trying it with a pencil
earlier and it didn't work.
161
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I can balance a pen
on its end there.
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If we're careful, we can do this,
163
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but just give it a small jolt
and it falls over.
164
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Now, we can really cool down
our water very slowly,
165
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very carefully, we can get it
to those temperatures
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if it's very, very slowly cooled,
really pure water.
167
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But just give it a small jolt,
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it starts off this process
of being how it should be.
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00:09:31,980 --> 00:09:35,220
The question now is, what do you
think happens to the temperature?
170
00:09:35,220 --> 00:09:36,940
Do you think it stays the same?
171
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Do you think it gets hotter,
or do you think it gets colder?
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We're going to have a vote.
So who thinks it stays the same?
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OK, quite a few. Who thinks
it gets colder when freezes?
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Quite a few of you.
And who thinks it gets hotter?
175
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It's a bit of a mix, I think.
Let's see what happens.
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I need to take this
very, very carefully.
177
00:09:56,540 --> 00:10:02,380
And here we can see that the
temperature is indeed at -3.7.
178
00:10:02,380 --> 00:10:04,900
This is really pretty good,
179
00:10:04,900 --> 00:10:07,180
in this huge tube here.
180
00:10:07,180 --> 00:10:09,620
I might need some ice,
but I'm just going to give this...
181
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Look at that,
just moving it has set this off.
182
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Look what's happening to the
temperature. It has shot up.
183
00:10:16,380 --> 00:10:21,060
It was at -3.7, it's now just...
Well, it's actually,
184
00:10:21,060 --> 00:10:25,660
this top part is now above zero.
And again, it's freezing.
185
00:10:25,660 --> 00:10:27,860
This is because
as the water molecules...
186
00:10:27,860 --> 00:10:30,060
They were moving around
in the liquid,
187
00:10:30,060 --> 00:10:32,780
but as they're locked into place
in the ice
188
00:10:32,780 --> 00:10:35,980
we're forming bonds
between the water molecules
189
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and the temperature goes up.
190
00:10:37,620 --> 00:10:41,100
That's really beautifully done,
it's incredibly difficult to do,
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00:10:41,100 --> 00:10:44,340
and I think we should thank Fiona
for preparing this all day.
192
00:10:44,340 --> 00:10:47,140
Thank you, Fiona.
OK, thank you.
193
00:10:55,340 --> 00:10:58,300
So the formation of bonds
releases energy.
194
00:10:58,300 --> 00:11:00,180
This is a very important thing.
195
00:11:00,180 --> 00:11:02,620
Now, actually,
we can show this in another way.
196
00:11:02,620 --> 00:11:05,980
If you look under your seats,
you'll find a little hand warmer.
197
00:11:08,100 --> 00:11:11,580
Now, for those of you, of course,
watching at home, I'm afraid,
198
00:11:11,580 --> 00:11:14,820
if you look under your seats, you
probably won't find a hand warmer
199
00:11:14,820 --> 00:11:17,420
unless you remembered
to put it there earlier,
200
00:11:17,420 --> 00:11:18,740
in which case, well done!
201
00:11:20,100 --> 00:11:23,740
OK, looks like people are finding
their hand warmers.
202
00:11:23,740 --> 00:11:26,500
Your hand warmer contains a solution
203
00:11:26,500 --> 00:11:29,020
and it has salts dissolved in this.
204
00:11:29,020 --> 00:11:31,380
But actually, again,
it's an unstable situation.
205
00:11:31,380 --> 00:11:34,100
There are more salts dissolved
than there should be.
206
00:11:34,100 --> 00:11:36,940
So if we just give this a click,
if you haven't done this already,
207
00:11:36,940 --> 00:11:39,380
you just click the little bit
of metal in the corner.
208
00:11:39,380 --> 00:11:41,420
That's it, I can hear
lots of clicking going on.
209
00:11:41,420 --> 00:11:43,740
That's just starting this
reaction now.
210
00:11:43,740 --> 00:11:46,140
EXCITED CHATTER
211
00:11:52,140 --> 00:11:56,180
And it's resorted to
exactly how it should be.
212
00:11:56,180 --> 00:12:00,100
We are forming bonds,
the salts are precipitating out,
213
00:12:00,100 --> 00:12:03,260
and as they're forming bonds,
forming the solid here,
214
00:12:03,260 --> 00:12:06,740
formation of bonds gives out
energy and that's what you can feel.
215
00:12:06,740 --> 00:12:11,820
That's what's warming up your hands
now, which is rather nice. OK.
216
00:12:11,820 --> 00:12:15,260
So the formation of bonds
gives out energy.
217
00:12:15,260 --> 00:12:17,940
And that's what's taking place
with our little flame here,
218
00:12:17,940 --> 00:12:19,820
our Olympic flame.
219
00:12:19,820 --> 00:12:22,980
I think we might just turn up
the hydrogen a bit, lovely.
220
00:12:22,980 --> 00:12:26,700
So, here we are forming bonds
between hydrogen and oxygen
221
00:12:26,700 --> 00:12:28,380
and that's releasing energy.
222
00:12:28,380 --> 00:12:31,140
And this is a really beautiful
reaction here,
223
00:12:31,140 --> 00:12:34,420
because the only by-product
of this is water.
224
00:12:34,420 --> 00:12:37,460
You may know, of course, when
you burn petrol and other fuels,
225
00:12:37,460 --> 00:12:39,900
you get carbon dioxide,
this is a greenhouse gas.
226
00:12:39,900 --> 00:12:41,740
The only by-product here is water
227
00:12:41,740 --> 00:12:44,020
and there's a lot of energy
being released.
228
00:12:44,020 --> 00:12:48,820
So maybe this could be an answer to
the energy problems of the future.
229
00:12:48,820 --> 00:12:50,020
Well, have a look at this.
230
00:12:58,820 --> 00:13:01,020
APPLAUSE
231
00:13:03,060 --> 00:13:06,740
This is Nathan Chang from
Valeswood Fuel Cells Ltd.
232
00:13:06,740 --> 00:13:08,980
Nathan, can you tell us,
what is this thing?
233
00:13:08,980 --> 00:13:13,220
It looks like a normal road bike.
You can put it on the road, can you?
234
00:13:13,220 --> 00:13:15,060
It's a road legal scooter,
235
00:13:15,060 --> 00:13:18,700
but we put the fuel cell
and hydrogen on there.
236
00:13:18,700 --> 00:13:21,740
This is lanthanum nickel hydride?
237
00:13:21,740 --> 00:13:24,380
That's a nickel metal-based hydride.
238
00:13:24,380 --> 00:13:26,780
And it's absorbing the hydrogen...
Like a sponge.
239
00:13:26,780 --> 00:13:28,860
Like a sponge,
and gradually releasing it.
240
00:13:28,860 --> 00:13:31,100
It's combining with the oxygen
from the air.
241
00:13:31,100 --> 00:13:33,740
That's giving you the energy
to power this bike.
242
00:13:33,740 --> 00:13:36,380
Yeah, that fuel cell generates
electricity to power
243
00:13:36,380 --> 00:13:39,020
the motor and power the vehicle.
OK, this is great.
244
00:13:39,020 --> 00:13:41,820
So you've just driven
all the way through the RI.
245
00:13:41,820 --> 00:13:43,620
Haven't you polluted everywhere,
246
00:13:43,620 --> 00:13:45,940
is there oil dripping
out of everything now?
247
00:13:45,940 --> 00:13:49,100
The only emission is water vapour.
It's just water vapour.
248
00:13:49,100 --> 00:13:51,100
And the hydrogen comes from water.
249
00:13:51,100 --> 00:13:53,420
The hydrogen itself
comes from the water?
250
00:13:53,420 --> 00:13:55,460
So you convert water to hydrogen,
251
00:13:55,460 --> 00:13:57,900
the fuel cell converts
hydrogen to water again.
252
00:13:57,900 --> 00:14:00,740
So why don't we see more vehicles
like this now?
253
00:14:00,740 --> 00:14:03,820
Why don't we see more
hydrogen vehicles? Yeah.
254
00:14:03,820 --> 00:14:06,220
The hydrogen is still very expensive.
255
00:14:06,220 --> 00:14:11,460
And, also, you have problems to store
enough hydrogen for a bigger vehicle.
256
00:14:11,460 --> 00:14:13,540
So you'd have to change your tank,
would you,
257
00:14:13,540 --> 00:14:15,580
if you wanted to get back
to Birmingham?
258
00:14:15,580 --> 00:14:17,980
You'd need a bigger tank.
A slightly bigger tank.
259
00:14:17,980 --> 00:14:20,460
That tank can power this vehicle
for 70 miles.
260
00:14:20,460 --> 00:14:22,500
70 miles, oh, pretty good then.
261
00:14:22,500 --> 00:14:24,740
So, if we could get
a better source of hydrogen,
262
00:14:24,740 --> 00:14:27,620
it would be cheaper,
then we'd see more vehicles. Yeah.
263
00:14:27,620 --> 00:14:31,020
Because it's non-polluting,
it only produces water, yes? Yeah.
264
00:14:31,020 --> 00:14:34,260
Give Nathan a big round of applause,
thank you very much coming in.
265
00:14:34,260 --> 00:14:36,580
APPLAUSE
266
00:14:41,380 --> 00:14:43,340
So we've got
a bit of a challenge here.
267
00:14:43,340 --> 00:14:46,620
I mean, hydrogen could be
the ideal fuel of the future,
268
00:14:46,620 --> 00:14:50,300
but the problem is,
how do we get it in the first place?
269
00:14:50,300 --> 00:14:54,060
And one way that we can get it
would be to break up the water.
270
00:14:54,060 --> 00:14:57,260
In fact, Nathan said that
the hydrogen that they're using
271
00:14:57,260 --> 00:14:59,860
does come from splitting up water.
272
00:14:59,860 --> 00:15:04,260
But we can see that when hydrogen
and oxygen combine to form water,
273
00:15:04,260 --> 00:15:08,220
this gives out a lot of energy.
If we want to split up our water
274
00:15:08,220 --> 00:15:11,860
to generate hydrogen and oxygen,
we need to put a lot of energy in.
275
00:15:11,860 --> 00:15:15,060
We can show this, this is another
general thing of chemistry,
276
00:15:15,060 --> 00:15:16,740
that if we want to break bonds,
277
00:15:16,740 --> 00:15:18,780
we need to put energy
into the system,
278
00:15:18,780 --> 00:15:20,780
and we're going to show this
first of all
279
00:15:20,780 --> 00:15:23,620
by looking at interactions
between water molecules.
280
00:15:23,620 --> 00:15:25,860
I'd like some volunteers
from the audience.
281
00:15:25,860 --> 00:15:27,700
The back row, actually. That's it.
282
00:15:27,700 --> 00:15:31,100
Give them all a round of applause.
APPLAUSE
283
00:15:37,020 --> 00:15:39,460
In this space, lovely.
284
00:15:39,460 --> 00:15:42,100
Hold up your balloons
so everyone can see. That's it.
285
00:15:42,100 --> 00:15:43,940
Now, you're water molecules, OK?
286
00:15:43,940 --> 00:15:46,300
And at the moment
you're bonded together
287
00:15:46,300 --> 00:15:48,380
to form the rigid structure of ice.
288
00:15:48,380 --> 00:15:51,820
So, of course, you're going to be
wiggling around, gently vibrating.
289
00:15:51,820 --> 00:15:53,300
This is what ice looks like.
290
00:15:53,300 --> 00:15:56,740
But if we give them more energy,
we can break some of these bonds
291
00:15:56,740 --> 00:15:59,700
that hold the water molecules
together, and we get liquid.
292
00:15:59,700 --> 00:16:03,020
Now you can start moving around.
Just have a little walk.
293
00:16:03,020 --> 00:16:05,340
This is our liquid.
In fact, on the screen now,
294
00:16:05,340 --> 00:16:08,060
we can see this is
a very complicated calculation
295
00:16:08,060 --> 00:16:11,220
carried out at the University
of Cambridge from scratch.
296
00:16:11,220 --> 00:16:14,780
This shows what happens when
liquid water molecules get together.
297
00:16:14,780 --> 00:16:16,460
They're jiggling around,
298
00:16:16,460 --> 00:16:18,900
but they are sort of held
more or less in place
299
00:16:18,900 --> 00:16:21,060
with these dotted lines
that you see there.
300
00:16:21,060 --> 00:16:23,460
These are bonds
called hydrogen bonds.
301
00:16:23,460 --> 00:16:25,740
This is where the oxygen
of one water molecule
302
00:16:25,740 --> 00:16:28,020
is slightly negatively charged,
and it sticks
303
00:16:28,020 --> 00:16:31,260
to the slightly positively charged
hydrogen of the other.
304
00:16:31,260 --> 00:16:32,460
Keep walking around.
305
00:16:32,460 --> 00:16:35,940
But what happens
if we give you even MORE energy?
306
00:16:35,940 --> 00:16:37,580
They start separating,
307
00:16:37,580 --> 00:16:40,540
and we can get them
to fly out into the audience here.
308
00:16:40,540 --> 00:16:43,060
This is where we're making steam,
all right?
309
00:16:43,060 --> 00:16:45,100
LAUGHTER
So lots more energy,
310
00:16:45,100 --> 00:16:49,540
the water molecules are separated,
and we've got steam.
311
00:16:49,540 --> 00:16:51,500
So thank you very much,
water molecules.
312
00:16:51,500 --> 00:16:53,300
Please return to your seats.
313
00:16:53,300 --> 00:16:55,420
APPLAUSE
314
00:16:59,460 --> 00:17:02,340
So, all we've managed
to achieve so far, then,
315
00:17:02,340 --> 00:17:06,660
is pulling the water molecules apart
from each other to generate steam.
316
00:17:06,660 --> 00:17:09,300
But this raises
a very interesting question -
317
00:17:09,300 --> 00:17:12,780
how much more space
does the steam now take up,
318
00:17:12,780 --> 00:17:14,260
compared to the water?
319
00:17:14,260 --> 00:17:17,580
So, in other words,
if I took one millilitre of water,
320
00:17:17,580 --> 00:17:20,820
how many millilitres of steam
would I be able to get?
321
00:17:20,820 --> 00:17:24,300
This piece of apparatus here
is designed to try and show us
322
00:17:24,300 --> 00:17:27,540
how much steam we can get
from one millilitre of water.
323
00:17:27,540 --> 00:17:30,980
And I need a volunteer for this one,
please. Er...
324
00:17:30,980 --> 00:17:32,460
yes, actually, in the white.
325
00:17:32,460 --> 00:17:35,500
Would you like to come down
to the front, please?
326
00:17:35,500 --> 00:17:37,780
APPLAUSE
327
00:17:40,540 --> 00:17:43,180
OK. And your name is? Connor.
Connor, OK, great.
328
00:17:43,180 --> 00:17:44,940
Do you know how many
millilitres of steam
329
00:17:44,940 --> 00:17:46,540
we're going to
get from 1ml of water?
330
00:17:46,540 --> 00:17:48,660
Have a guess.
You've got a scale here.
331
00:17:48,660 --> 00:17:50,500
You're going to be
looking at this scale.
332
00:17:50,500 --> 00:17:53,540
It goes from zero up to 100ml.
How many do you think?
333
00:17:53,540 --> 00:17:54,980
50. 50 ml.
334
00:17:54,980 --> 00:17:59,020
In the middle, OK.
Who thinks more than 50?
335
00:17:59,020 --> 00:18:01,100
Who thinks less than 50?
336
00:18:01,100 --> 00:18:02,780
More than 50?
337
00:18:02,780 --> 00:18:04,100
Yes? 100.
338
00:18:04,100 --> 00:18:05,740
100. Any advances on 100?
339
00:18:05,740 --> 00:18:08,380
Yes? 150.
Well, if it goes past 100...
340
00:18:08,380 --> 00:18:11,620
150 is going to be past the dial.
I want you to watch the dial.
341
00:18:11,620 --> 00:18:14,300
I'm going to squirt
the water in this end.
342
00:18:14,300 --> 00:18:17,620
Here's my syringe. So this is
going to be 1ml of water.
343
00:18:17,620 --> 00:18:20,300
I'm hoping that this
is all nice and hot.
344
00:18:20,300 --> 00:18:22,340
So 1ml is not a lot.
345
00:18:22,340 --> 00:18:25,860
If you see, that's just 1ml there.
and you think 50, don't you?
346
00:18:25,860 --> 00:18:28,700
And we've got all sorts
of different guesses here.
347
00:18:28,700 --> 00:18:32,540
So, right, I'm just going to turn
this tap and put this in,
348
00:18:32,540 --> 00:18:35,540
and I hope, fingers crossed,
I squirt that in,
349
00:18:35,540 --> 00:18:38,020
close the tap, and there we are.
350
00:18:38,020 --> 00:18:40,660
Watch the thing. Let's see
how far it's going to go...
351
00:18:40,660 --> 00:18:42,860
Keep going. 50...
oh, it's gone past your 50.
352
00:18:42,860 --> 00:18:44,540
Still going. It's gone past 75.
353
00:18:44,540 --> 00:18:46,940
Can we turn this on
actually? Is that possible?
354
00:18:46,940 --> 00:18:50,500
To get this back up to temperature?
MACHINE WHIRS
355
00:18:50,500 --> 00:18:53,540
Ah, brilliant!
Yeah, I can see it boiling now.
356
00:18:53,540 --> 00:18:56,620
So we're trying to get some heat
back into this thing.
357
00:18:56,620 --> 00:18:59,220
How far have we gone so far? 225.
358
00:18:59,220 --> 00:19:00,540
Sorry? How many? 225.
359
00:19:00,540 --> 00:19:01,980
225. Who said 225?
360
00:19:01,980 --> 00:19:03,140
Oh, well done!
361
00:19:03,140 --> 00:19:06,260
Well, we've gone past that now!
LAUGHTER
362
00:19:06,260 --> 00:19:08,700
Right, OK, it's still going.
Got quite a lot of...
363
00:19:08,700 --> 00:19:10,780
look down this end, actually.
364
00:19:10,780 --> 00:19:12,900
Yeah, you can see
the water in there.
365
00:19:12,900 --> 00:19:15,860
Yeah, still quite a lot.
Oh, you've missed the dial!
366
00:19:15,860 --> 00:19:17,420
How's he doing? What's that?
367
00:19:17,420 --> 00:19:19,020
300. 300, OK. Good, keep going.
368
00:19:19,020 --> 00:19:21,860
Still water there. It's still
going, then. We're up to...
369
00:19:21,860 --> 00:19:23,900
What are we up to? 450.
370
00:19:23,900 --> 00:19:25,900
450, OK. Not quite hot enough.
371
00:19:25,900 --> 00:19:28,820
It's so difficult to do this.
It needs to be SO hot.
372
00:19:28,820 --> 00:19:30,420
Where are we up to now? 650.
373
00:19:30,420 --> 00:19:31,940
650? We're still going.
374
00:19:31,940 --> 00:19:34,180
There's still quite a bit
of water there.
375
00:19:34,180 --> 00:19:36,940
This is just our 1ml.
376
00:19:36,940 --> 00:19:39,980
OK. And this is now...
Where are we up to?
377
00:19:39,980 --> 00:19:41,820
900. 900.
378
00:19:41,820 --> 00:19:44,580
So quite a few people said...oh,
is that 1,000?
379
00:19:44,580 --> 00:19:46,060
Yeah. That's 1,000, OK.
380
00:19:46,060 --> 00:19:48,220
Now, it's still expanding.
381
00:19:48,220 --> 00:19:49,740
We'll keep counting here.
382
00:19:49,740 --> 00:19:54,220
But this is actually really quite
important, this expansion here.
383
00:19:54,220 --> 00:19:57,620
It's THIS expansion that drove,
quite literally,
384
00:19:57,620 --> 00:19:59,500
the Industrial Revolution.
385
00:19:59,500 --> 00:20:03,540
It was the power here,
as water is turned into steam,
386
00:20:03,540 --> 00:20:06,140
driving pistons,
driving our machinery.
387
00:20:06,140 --> 00:20:07,780
How are we up to so far?
388
00:20:07,780 --> 00:20:11,020
1,375. 1,375. Very precise!
389
00:20:11,020 --> 00:20:13,140
You're a keen scientist, I can tell!
390
00:20:13,140 --> 00:20:14,900
Physicist. Physicist! Ah!
391
00:20:14,900 --> 00:20:17,900
Almost as good as a chemist!
LAUGHTER
392
00:20:17,900 --> 00:20:20,660
Anyway, how are we doing now?
This is coming up to... 1,650.
393
00:20:20,660 --> 00:20:23,140
1,650. OK, we're going to
have to stop this now.
394
00:20:23,140 --> 00:20:27,300
There's a tiny bit there, but
this is going to go to over 2,000ml.
395
00:20:27,300 --> 00:20:31,980
So, you're a physicist,
and you said, what was it? 50ml?!
396
00:20:31,980 --> 00:20:34,020
Well, anyway, thank you very much.
397
00:20:34,020 --> 00:20:37,180
Give him a big round of applause
for keeping track. Thank you.
398
00:20:37,180 --> 00:20:39,260
APPLAUSE
399
00:20:41,740 --> 00:20:43,780
So, we've converted
our water into steam,
400
00:20:43,780 --> 00:20:46,340
and we need to put quite
a lot of energy in to do that,
401
00:20:46,340 --> 00:20:48,980
but we still haven't
actually made our hydrogen.
402
00:20:48,980 --> 00:20:50,460
This is what we were trying to do.
403
00:20:50,460 --> 00:20:53,820
To do that, to actually
split apart the water molecules,
404
00:20:53,820 --> 00:20:56,340
we need to put
even more energy into them.
405
00:20:56,340 --> 00:20:59,700
And, we're going to show this now
with this apparatus.
406
00:20:59,700 --> 00:21:01,940
So we've got some water
in the tubes here,
407
00:21:01,940 --> 00:21:03,700
and I'm just going to plug this in.
408
00:21:03,700 --> 00:21:05,860
So this is connected to here,
409
00:21:05,860 --> 00:21:08,700
and this is a generator.
410
00:21:08,700 --> 00:21:10,740
So if I hop on the bike,
411
00:21:10,740 --> 00:21:16,820
I should be able to drive the little
generator at the back like this.
412
00:21:16,820 --> 00:21:18,660
We can begin to see some bubbles.
413
00:21:18,660 --> 00:21:21,540
It's quite hard work here,
trying to split up the water,
414
00:21:21,540 --> 00:21:24,780
so I'm going to get somebody else
to do all the hard work, I think.
415
00:21:24,780 --> 00:21:27,420
Actually, we need
quite a lot of hydrogen,
416
00:21:27,420 --> 00:21:29,540
so I'd like you to welcome, please,
417
00:21:29,540 --> 00:21:32,100
Paralympic gold medallist,
Mark Colbourne.
418
00:21:32,100 --> 00:21:33,900
Thank you very much, Mark.
419
00:21:33,900 --> 00:21:36,820
APPLAUSE AND CHEERING
420
00:21:38,820 --> 00:21:41,020
Thank you for joining us.
Thank you very much.
421
00:21:44,580 --> 00:21:48,140
LOUD APPLAUSE AND CHEERING
422
00:21:51,860 --> 00:21:54,300
Some great warmth
from the audience here.
423
00:21:54,300 --> 00:21:56,260
You've obviously
done a fantastic job.
424
00:21:56,260 --> 00:21:59,740
Before you get onto this thing,
tell us a little bit about yourself.
425
00:21:59,740 --> 00:22:02,180
You had an accident paragliding,
is that right?
426
00:22:02,180 --> 00:22:04,860
I did, yes. May 2009.
427
00:22:04,860 --> 00:22:07,220
So just over three
and half years ago.
428
00:22:07,220 --> 00:22:10,700
I broke my back in a near fatal
paragliding crash in South Wales.
429
00:22:10,700 --> 00:22:12,940
So I was very lucky to survive, yeah.
430
00:22:12,940 --> 00:22:16,180
And clearly it's not affected
your legs too much,
431
00:22:16,180 --> 00:22:18,020
since you can cycle so well!
432
00:22:18,020 --> 00:22:21,660
Yes, I've been left with
lower leg paralysis.
433
00:22:21,660 --> 00:22:25,340
So both my feet don't work, so I have
to wear special ankle supports.
434
00:22:25,340 --> 00:22:28,980
No hamstrings firing, no bum muscles
firing, so it's all quads.
435
00:22:28,980 --> 00:22:31,940
There's pretty big quads there,
so that's pretty good!
436
00:22:31,940 --> 00:22:33,820
Now, this is what
I'd like to see. Yes!
437
00:22:33,820 --> 00:22:37,420
Being a modern alchemist, this is
some gold, is it? Some real gold?
438
00:22:37,420 --> 00:22:41,860
Yes, what you have here is my
very own Paralympic gold medal.
439
00:22:41,860 --> 00:22:43,860
That's fantastic.
440
00:22:43,860 --> 00:22:47,420
APPLAUSE AND CHEERING
441
00:22:51,220 --> 00:22:53,140
This certainly feels pretty heavy.
442
00:22:53,140 --> 00:22:54,780
Is this solid gold?
443
00:22:54,780 --> 00:22:58,620
No, it's actually
390g of solid silver,
444
00:22:58,620 --> 00:23:00,620
and then you have 22g of gold
445
00:23:00,620 --> 00:23:03,300
obviously coated
around the outside,
446
00:23:03,300 --> 00:23:06,540
and, proudly, actually made
in Llantrisant, in South Wales.
447
00:23:06,540 --> 00:23:08,540
Oh, that's fantastic. Really good.
448
00:23:08,540 --> 00:23:11,020
Nice to see a bit of gold
in the studio, as well.
449
00:23:11,020 --> 00:23:14,060
I think we've got a picture of you
here, just crossing the line.
450
00:23:14,060 --> 00:23:16,620
How did it feel crossing the line?
Just euphoric.
451
00:23:16,620 --> 00:23:19,580
It was almost like Christmas
and birthdays rolled into one.
452
00:23:19,580 --> 00:23:22,620
And you got one of these, as well.
Fantastic. Very much so.
453
00:23:22,620 --> 00:23:25,460
But have you ever split up
any water molecules before?
454
00:23:25,460 --> 00:23:28,100
That's the real question.
No, not in this sense!
455
00:23:28,100 --> 00:23:30,700
Obviously, lots of sweat
when I'm training.
456
00:23:30,700 --> 00:23:32,340
I think you need to give it a go.
457
00:23:32,340 --> 00:23:35,220
If you'd like to hop on.
I'll look after this for you.
458
00:23:35,220 --> 00:23:37,300
OK, wonderful.
Make sure he doesn't run away, OK?
459
00:23:37,300 --> 00:23:38,620
LAUGHTER
460
00:23:38,620 --> 00:23:40,700
Because I won't be able to catch him!
461
00:23:40,700 --> 00:23:45,020
Yes, so, now then,
Mark's on this bike here.
462
00:23:45,020 --> 00:23:49,180
All his power is going to go into
driving this little generator here,
463
00:23:49,180 --> 00:23:51,460
and this really is just connected
464
00:23:51,460 --> 00:23:54,020
to the water
we've got in these tubes.
465
00:23:54,020 --> 00:23:56,340
OK, take it away then. That's great.
466
00:23:56,340 --> 00:23:58,220
So we've got two electrodes here.
467
00:23:58,220 --> 00:24:00,060
On the negative electrode,
468
00:24:00,060 --> 00:24:03,500
this is where the
hydrogen atoms are collecting.
469
00:24:03,500 --> 00:24:06,660
So, remember, the hydrogen
in the water is slightly positive,
470
00:24:06,660 --> 00:24:09,420
the negative electrode
is giving them electrons,
471
00:24:09,420 --> 00:24:12,660
forming hydrogen atoms,
and forming hydrogen molecules.
472
00:24:12,660 --> 00:24:14,820
On the positive electrode,
the oxygen atoms,
473
00:24:14,820 --> 00:24:17,020
which are slightly
negative in the water,
474
00:24:17,020 --> 00:24:19,260
are having those
extra electrons ripped away
475
00:24:19,260 --> 00:24:22,540
to form oxygen atoms and,
eventually, oxygen molecules.
476
00:24:22,540 --> 00:24:25,340
But the interesting thing here,
as Mark's pedalling away...
477
00:24:25,340 --> 00:24:27,180
Go on, faster!
478
00:24:27,180 --> 00:24:29,540
The interesting thing is
that we can clearly see
479
00:24:29,540 --> 00:24:32,420
that we're getting twice as much
hydrogen gas
480
00:24:32,420 --> 00:24:34,380
as we are getting oxygen gas.
481
00:24:34,380 --> 00:24:36,100
So this clearly shows, then,
482
00:24:36,100 --> 00:24:39,380
that water is made up of
twice as much hydrogen as oxygen.
483
00:24:39,380 --> 00:24:41,340
Oh, I think you've broken it!
Go slower!
484
00:24:41,340 --> 00:24:42,980
Has it gone again? Sorry!
485
00:24:42,980 --> 00:24:45,780
Pretty tiring, isn't it?
Don't you think?
486
00:24:45,780 --> 00:24:48,100
Pretty tough.
Yeah, thank you very much.
487
00:24:48,100 --> 00:24:50,500
I think a big round of applause
there for Mark.
488
00:24:50,500 --> 00:24:53,540
APPLAUSE AND CHEERING
489
00:24:55,020 --> 00:24:57,980
Perhaps...can I offer you
a drink afterwards?
490
00:24:57,980 --> 00:25:00,700
Do you need a drop of water
after that? Yes, definitely.
491
00:25:00,700 --> 00:25:02,500
Lots of water. Would you want this?
492
00:25:02,500 --> 00:25:04,220
This is our Fountain of Youth.
493
00:25:04,220 --> 00:25:06,660
In fact, we've got
a guinea pig trying this.
494
00:25:06,660 --> 00:25:08,020
Tim, how's it going?
495
00:25:08,020 --> 00:25:10,260
How's your Fountain of Youth?
Just the same.
496
00:25:10,260 --> 00:25:13,300
Don't feel any different at all.
No wrinkles gone yet?
497
00:25:13,300 --> 00:25:16,060
No, still there!
OK, we'll come back.
498
00:25:16,060 --> 00:25:19,180
We'll give it a chance later.
But, anyway, thank you very much.
499
00:25:19,180 --> 00:25:21,580
I'll give that one to you.
Thank you for coming.
500
00:25:21,580 --> 00:25:22,740
Thank you. Cheers.
501
00:25:22,740 --> 00:25:25,460
APPLAUSE AND CHEERING
502
00:25:29,140 --> 00:25:31,980
So, we've seen, then,
that we need to put energy in
503
00:25:31,980 --> 00:25:33,260
to split up our water.
504
00:25:33,260 --> 00:25:35,780
And a lot of energy is needed there,
505
00:25:35,780 --> 00:25:38,620
and I don't think that
using Olympic cyclists...
506
00:25:38,620 --> 00:25:42,100
Even Britain doesn't have enough
Olympic gold medal cyclists
507
00:25:42,100 --> 00:25:45,580
to power all the vehicles
in the future using hydrogen.
508
00:25:45,580 --> 00:25:47,460
But there is another
way of doing this.
509
00:25:47,460 --> 00:25:52,100
Our plants here use the energy
from sunlight to split up water.
510
00:25:52,100 --> 00:25:54,500
They spit out oxygen
during the daytime, of course,
511
00:25:54,500 --> 00:25:56,220
but they're using the hydrogen
512
00:25:56,220 --> 00:25:58,580
to build up the molecules
they're made from.
513
00:25:58,580 --> 00:26:00,820
So maybe we can learn from nature.
514
00:26:00,820 --> 00:26:05,860
Now, Professor Akihiko Kudo
from the Tokyo University of Science
515
00:26:05,860 --> 00:26:09,180
has worked on a catalyst here.
516
00:26:09,180 --> 00:26:12,380
This is really quite remarkable
stuff. This is quite cutting edge.
517
00:26:12,380 --> 00:26:14,820
This is a catalyst that can use
518
00:26:14,820 --> 00:26:18,060
the energy of light
to split up water.
519
00:26:18,060 --> 00:26:20,260
And the catalyst is made of...
520
00:26:20,260 --> 00:26:23,620
Well, actually, if we can just have
our periodic tables up for a moment.
521
00:26:23,620 --> 00:26:25,220
Very good, periodic tables!
522
00:26:25,220 --> 00:26:28,660
OK, this catalyst is made up
of the element sodium.
523
00:26:28,660 --> 00:26:30,260
Sodium, give us a little wave!
524
00:26:30,260 --> 00:26:32,100
There we are. Very good, sodium.
525
00:26:32,100 --> 00:26:33,940
OK, can you see sodium there?
526
00:26:33,940 --> 00:26:37,580
And we've got tantalum, right
in the centre. Very good, tantalum.
527
00:26:37,580 --> 00:26:40,420
And oxygen up there.
So this is sodium tantalate,
528
00:26:40,420 --> 00:26:43,460
and it's doped with lanthanum.
Where's lanthanum?
529
00:26:43,460 --> 00:26:44,860
There's lanthanum. Very good.
530
00:26:44,860 --> 00:26:46,740
Give us a little wave
at the top there.
531
00:26:46,740 --> 00:26:49,700
So this is the catalyst
that he's developed,
532
00:26:49,700 --> 00:26:52,340
and this will convert
the energy from light
533
00:26:52,340 --> 00:26:54,700
and use this energy
to split up water.
534
00:26:54,700 --> 00:26:56,260
So, at ease, periodic tables!
535
00:26:56,260 --> 00:26:57,900
Back down, thank you very much.
536
00:26:57,900 --> 00:27:00,180
OK, so are we ready? Yep.
537
00:27:00,180 --> 00:27:03,980
OK, now, we're just going to
put this on, then.
538
00:27:05,380 --> 00:27:08,420
OK, now, so this is the catalyst,
539
00:27:08,420 --> 00:27:11,780
sodium tantalate
doped with lanthanum,
540
00:27:11,780 --> 00:27:15,140
and we're shining UV light on this,
541
00:27:15,140 --> 00:27:18,220
and, yes, I can see some bubbles.
542
00:27:18,220 --> 00:27:22,340
There are some bubbles in
the upper part of the chamber there.
543
00:27:22,340 --> 00:27:24,820
If we just move up,
we can see some. There we are.
544
00:27:24,820 --> 00:27:28,260
This is bubbles forming. So,
as I say, this is quite remarkable.
545
00:27:28,260 --> 00:27:33,220
This is using light energy
to catalytically split up,
546
00:27:33,220 --> 00:27:35,180
so this is not changing
the catalyst,
547
00:27:35,180 --> 00:27:39,940
but it's splitting up water
into hydrogen gas and oxygen gas.
548
00:27:39,940 --> 00:27:42,380
So we can see these bubbles here.
549
00:27:42,380 --> 00:27:44,860
Now, unfortunately,
the slight snag with this one
550
00:27:44,860 --> 00:27:49,340
is that it's using ultraviolet light
and not just visible light.
551
00:27:49,340 --> 00:27:51,740
The plants, of course,
use visible light.
552
00:27:51,740 --> 00:27:53,780
But scientists all round the world
553
00:27:53,780 --> 00:27:55,860
are trying to work on
developing a catalyst
554
00:27:55,860 --> 00:27:59,300
that will work very efficiently
with visible light instead.
555
00:27:59,300 --> 00:28:01,300
And if you can do that...
556
00:28:01,300 --> 00:28:03,340
Well, maybe somebody
from the audience
557
00:28:03,340 --> 00:28:05,940
will be the scientist
that actually finds a catalyst
558
00:28:05,940 --> 00:28:07,820
that will work with visible light.
559
00:28:07,820 --> 00:28:10,420
And if you can do that,
you're going to be very rich,
560
00:28:10,420 --> 00:28:14,300
and you will help to solve
the world's energy problems.
561
00:28:14,300 --> 00:28:18,820
Right, so, I think it's time
that we actually checked the water,
562
00:28:18,820 --> 00:28:20,980
after all this time making it.
563
00:28:20,980 --> 00:28:23,380
So we had to take
a lot of precautions here,
564
00:28:23,380 --> 00:28:25,540
to ensure that
this really is extra pure.
565
00:28:25,540 --> 00:28:27,900
This is something
you should NEVER normally do
566
00:28:27,900 --> 00:28:29,580
during any science experiment.
567
00:28:29,580 --> 00:28:31,940
You shouldn't drink
the products of the reaction.
568
00:28:31,940 --> 00:28:34,820
But this apparatus has been
specially designed for this.
569
00:28:34,820 --> 00:28:37,180
We've used extra pure oxygen,
medical oxygen,
570
00:28:37,180 --> 00:28:39,420
we've used extra pure hydrogen here.
571
00:28:39,420 --> 00:28:42,860
So I am actually going to just
try a few drops of this.
572
00:28:48,020 --> 00:28:50,620
Actually, it doesn't taste too nice,
to be honest!
573
00:28:50,620 --> 00:28:51,860
LAUGHTER
574
00:28:51,860 --> 00:28:54,740
But it's basically just pure water.
575
00:28:54,740 --> 00:28:57,380
And Tim was using
the Fountain of Youth water.
576
00:28:57,380 --> 00:28:59,900
If we look on the bottle
of the Fountain of Youth water,
577
00:28:59,900 --> 00:29:02,460
we see there are
other minerals dissolved in it.
578
00:29:02,460 --> 00:29:05,220
This is, of course, because
water is a very good solvent -
579
00:29:05,220 --> 00:29:06,500
things dissolve in it -
580
00:29:06,500 --> 00:29:09,860
and, well, look at all the other
components in our water.
581
00:29:09,860 --> 00:29:12,380
We've got, for instance,
there's a lot of calcium,
582
00:29:12,380 --> 00:29:14,340
there's quite a lot
of calcium there.
583
00:29:14,340 --> 00:29:16,940
There's quite a bit
of sodium in this, as well.
584
00:29:16,940 --> 00:29:18,580
So, sodium, what's your symbol?
585
00:29:18,580 --> 00:29:20,260
SODIUM: Na!
586
00:29:20,260 --> 00:29:24,260
OK, and do you have Na idea
where this comes from?
587
00:29:24,260 --> 00:29:25,780
Where does this symbol come from?
588
00:29:25,780 --> 00:29:27,380
Any ideas? No? No? OK.
589
00:29:27,380 --> 00:29:29,020
Well, I'm going to show you.
590
00:29:29,020 --> 00:29:31,860
Hold the sign up, please,
so we can all see. That's it.
591
00:29:31,860 --> 00:29:33,580
So, Na, where does this come from?
592
00:29:33,580 --> 00:29:35,540
Well, actually, I have a book here.
593
00:29:35,540 --> 00:29:37,740
Thank you. Now, in the book,
594
00:29:37,740 --> 00:29:41,020
we can see that this is a chap...
595
00:29:41,020 --> 00:29:44,300
This book is from 1557,
596
00:29:44,300 --> 00:29:47,740
and this man here,
he's making piles of compound here,
597
00:29:47,740 --> 00:29:50,180
and this is actually
sodium carbonate.
598
00:29:50,180 --> 00:29:52,820
They called it natron or niter.
And this is...
599
00:29:52,820 --> 00:29:56,260
He's taking Nile water here,
so this is water from the Nile,
600
00:29:56,260 --> 00:29:59,660
and this is why it's called niter,
from the Nile water.
601
00:29:59,660 --> 00:30:01,620
This corrupted into natron,
602
00:30:01,620 --> 00:30:04,780
and this is the word that gives us
the symbol for sodium.
603
00:30:04,780 --> 00:30:07,620
Na comes from the Latin
version of this, natrium.
604
00:30:07,620 --> 00:30:09,860
But it was first discovered
in water.
605
00:30:09,860 --> 00:30:12,740
OK, thank you.
So, periodic table, at ease.
606
00:30:12,740 --> 00:30:15,340
Thank you.
Now, how was this detected?
607
00:30:15,340 --> 00:30:18,980
Because we can't see
any of these substances in water,
608
00:30:18,980 --> 00:30:21,860
because they're present
in such small quantities,
609
00:30:21,860 --> 00:30:25,220
we have to use a chemist's technique
called spectroscopy.
610
00:30:25,220 --> 00:30:29,180
And this looks at how energy
interacts with electrons in atoms.
611
00:30:29,180 --> 00:30:32,140
Give them some energy, they move up,
and as they drop back down again,
612
00:30:32,140 --> 00:30:34,940
they can give out this energy
as light.
613
00:30:34,940 --> 00:30:39,740
And each element has its own unique,
characteristic, unique colours.
614
00:30:39,740 --> 00:30:43,980
It has its own spectrum, like a
rainbow barcode for each element.
615
00:30:43,980 --> 00:30:47,020
And we're going to show this now
with all these symbols here.
616
00:30:47,020 --> 00:30:49,220
These are the symbols
from group 1 elements.
617
00:30:49,220 --> 00:30:51,980
Can we have group 1 only, please?
That's it. Put them up.
618
00:30:51,980 --> 00:30:55,340
Hydrogen, well, you are, of course,
a component of water.
619
00:30:55,340 --> 00:30:57,940
You're not really IN water,
dissolved in it,
620
00:30:57,940 --> 00:30:59,820
so you can put your card down.
621
00:30:59,820 --> 00:31:02,060
Francium, I'm afraid
you're too radioactive,
622
00:31:02,060 --> 00:31:04,500
so there's going to be
no francium in our water,
623
00:31:04,500 --> 00:31:06,340
so you can put your card
down, as well.
624
00:31:06,340 --> 00:31:09,700
But these other group 1 elements,
well, here they are here.
625
00:31:09,700 --> 00:31:12,020
We've actually taken
some symbols here
626
00:31:12,020 --> 00:31:14,660
and soaked each of these
symbols with salts.
627
00:31:14,660 --> 00:31:17,220
With compounds
of the appropriate elements.
628
00:31:17,220 --> 00:31:19,500
And watch what happens
when we light them.
629
00:31:37,580 --> 00:31:40,860
APPLAUSE
630
00:31:47,980 --> 00:31:51,380
We can certainly see that the sodium
and lithium are very different,
631
00:31:51,380 --> 00:31:53,220
but these ones look rather similar.
632
00:31:53,220 --> 00:31:54,660
But, actually, they're not.
633
00:31:54,660 --> 00:31:56,460
If we were to look very closely
634
00:31:56,460 --> 00:31:58,740
at the colours of light
coming down here,
635
00:31:58,740 --> 00:32:00,940
if we split them up
using a spectroscope,
636
00:32:00,940 --> 00:32:03,620
we would see they have
slightly different colours.
637
00:32:03,620 --> 00:32:06,420
The exact frequencies
of light coming out
638
00:32:06,420 --> 00:32:08,220
are unique to these elements.
639
00:32:08,220 --> 00:32:10,700
Now these two elements,
caesium and rubidium,
640
00:32:10,700 --> 00:32:14,380
were also first discovered in water.
641
00:32:14,380 --> 00:32:17,500
And they were discovered
by Robert Bunsen.
642
00:32:17,500 --> 00:32:21,060
This is Bunsen of
Bunsen burner fame, of course -
643
00:32:21,060 --> 00:32:22,580
not to be confused with
644
00:32:22,580 --> 00:32:25,740
Bunsen Honeydew from the Muppets,
shown here!
645
00:32:25,740 --> 00:32:27,580
LAUGHTER
646
00:32:27,580 --> 00:32:31,860
But Robert Bunsen took litres
of mineral water, evaporated this,
647
00:32:31,860 --> 00:32:36,860
and he found these new elements
in the water using spectroscopy.
648
00:32:36,860 --> 00:32:38,740
And, in fact, he named these
elements
649
00:32:38,740 --> 00:32:40,980
from the appearance
of their spectra -
650
00:32:40,980 --> 00:32:43,820
caesium from the sky blue
lines in its spectra,
651
00:32:43,820 --> 00:32:48,300
and rubidium from two very distinct
red lines in its spectrum.
652
00:32:48,300 --> 00:32:51,100
OK, so, how do we find
these elements, though?
653
00:32:51,100 --> 00:32:54,580
They appear in compounds in water,
not as their elements.
654
00:32:54,580 --> 00:32:56,980
All of you,
all you group 1 elements,
655
00:32:56,980 --> 00:32:58,860
you're actually metals.
656
00:32:58,860 --> 00:33:01,300
We certainly
don't find metals in water.
657
00:33:01,300 --> 00:33:04,940
And that's because all of these
metals actually react with water.
658
00:33:04,940 --> 00:33:07,180
And this is what
we're going to show you now.
659
00:33:07,180 --> 00:33:09,140
So we have here a tank,
660
00:33:09,140 --> 00:33:13,260
and I'm going to add a tiny little
piece of sodium to the tank.
661
00:33:13,260 --> 00:33:15,500
Let's have this one.
A little piece of sodium.
662
00:33:15,500 --> 00:33:18,380
A little tiny piece.
I'm going to drop it into the water.
663
00:33:18,380 --> 00:33:20,420
There it is,
dancing around the surface.
664
00:33:20,420 --> 00:33:23,220
So it's lighter than water,
floating on the top,
665
00:33:23,220 --> 00:33:25,540
but it's actually
reacting with the water.
666
00:33:25,540 --> 00:33:27,380
We can see it's reacted there.
667
00:33:27,380 --> 00:33:28,980
It's giving out hydrogen gas.
668
00:33:28,980 --> 00:33:32,180
The sodium is giving up
its electron to the water,
669
00:33:32,180 --> 00:33:35,700
to the hydrogen in the water,
forming hydrogen gas, OK?
670
00:33:35,700 --> 00:33:38,380
It's rather disappointing
to see that one, though.
671
00:33:38,380 --> 00:33:39,900
There's not a lot there.
672
00:33:39,900 --> 00:33:45,100
I think we need, actually, a bigger
tank, and a bigger piece of sodium.
673
00:33:45,100 --> 00:33:46,540
So let's try this.
674
00:33:48,420 --> 00:33:51,420
OK, this is certainly
a bigger piece of sodium.
675
00:33:51,420 --> 00:33:54,500
Now, of course, when this reaction
is done at school,
676
00:33:54,500 --> 00:33:56,620
the teacher is always instructed
677
00:33:56,620 --> 00:33:59,300
to not use a piece
larger than the size of a pea.
678
00:33:59,300 --> 00:34:01,620
And, well, I thought
I'd show you why.
679
00:34:01,620 --> 00:34:05,060
So we've got a piece that IS a bit
larger than the size of a pea.
680
00:34:05,060 --> 00:34:09,020
Now then, we're going to add this
piece of sodium, then, to the water.
681
00:34:09,020 --> 00:34:11,140
Are you ready? And, step back.
682
00:34:13,220 --> 00:34:15,620
So it's floating
on the surface there...
683
00:34:15,620 --> 00:34:18,260
EXPLOSION
AUDIENCE GASPS
684
00:34:18,260 --> 00:34:21,820
HE LAUGHS
There's certainly
quite a lot of smoke!
685
00:34:21,820 --> 00:34:24,940
APPLAUSE AND CHEERING
686
00:34:33,660 --> 00:34:35,740
Well, you can certainly see why
687
00:34:35,740 --> 00:34:38,500
you shouldn't add a piece
larger than the size of a pea!
688
00:34:38,500 --> 00:34:41,140
LAUGHTER
COUGHING
689
00:34:41,140 --> 00:34:43,980
Oh, dear!
I've poisoned the audience!
690
00:34:43,980 --> 00:34:47,340
It's chemistry!
COUGHING
691
00:34:47,340 --> 00:34:48,540
Right, now...
692
00:34:48,540 --> 00:34:53,180
But it's not just water that sodium
can give its electron to.
693
00:34:53,180 --> 00:34:59,900
We can also...
It can give its electron to oxygen.
694
00:34:59,900 --> 00:35:01,700
So here is a piece of sodium
695
00:35:01,700 --> 00:35:03,940
and I'm just going to cut this now
696
00:35:03,940 --> 00:35:07,420
and chop it right down the middle.
697
00:35:07,420 --> 00:35:08,820
There we are.
698
00:35:10,300 --> 00:35:12,740
So this is beautiful, silvery metal.
699
00:35:12,740 --> 00:35:15,540
So this is what sodium
normally looks like.
700
00:35:15,540 --> 00:35:18,500
But just as it's left here,
exposed to the air,
701
00:35:18,500 --> 00:35:21,260
it's reacting with
the oxygen in the air.
702
00:35:21,260 --> 00:35:24,460
It's actually giving up
its electron to oxygen.
703
00:35:24,460 --> 00:35:26,540
OK, we can see it's changing.
704
00:35:26,540 --> 00:35:28,820
It's actually got
a sort of white crust
705
00:35:28,820 --> 00:35:30,780
developing over the surface.
706
00:35:30,780 --> 00:35:32,500
But, actually, if we just have
707
00:35:32,500 --> 00:35:34,660
our periodic table up
for the moment,
708
00:35:34,660 --> 00:35:37,020
and I want to focus on
group 1 again.
709
00:35:37,020 --> 00:35:39,340
So others, down. Just group 1 up.
710
00:35:39,340 --> 00:35:41,180
So we have sodium here,
711
00:35:41,180 --> 00:35:44,260
and the key thing here is this
outermost electron sodium has.
712
00:35:44,260 --> 00:35:46,260
I think we have
a graphic to show this.
713
00:35:46,260 --> 00:35:48,260
This is the atomic structure
of sodium.
714
00:35:48,260 --> 00:35:50,500
We have one outermost
electron there.
715
00:35:50,500 --> 00:35:53,900
This is the thing that's very
easily given in chemical reactions.
716
00:35:53,900 --> 00:35:55,580
But as we come down the group,
717
00:35:55,580 --> 00:35:58,020
you've all got this
one outermost electron,
718
00:35:58,020 --> 00:36:00,660
but if we look at, say, caesium,
right at the bottom,
719
00:36:00,660 --> 00:36:03,300
so here's caesium,
and has lots more electrons,
720
00:36:03,300 --> 00:36:05,940
but, again, there's one
outermost electron,
721
00:36:05,940 --> 00:36:09,580
and this is even more easily lost
than it is for sodium.
722
00:36:09,580 --> 00:36:12,020
And, well, we have some here.
723
00:36:12,020 --> 00:36:15,300
This is caesium in this vessel.
724
00:36:15,300 --> 00:36:18,580
The problem was,
we need to store it under argon,
725
00:36:18,580 --> 00:36:20,580
and we had a slight problem.
726
00:36:20,580 --> 00:36:23,580
We sealed it up so well,
we can't get it out!
727
00:36:23,580 --> 00:36:25,420
LAUGHTER
728
00:36:25,420 --> 00:36:27,780
So, I think the simplest thing to do
729
00:36:27,780 --> 00:36:29,980
is actually to hit it
with a hammer,
730
00:36:29,980 --> 00:36:31,940
which is what I'm going to do.
731
00:36:31,940 --> 00:36:34,180
HAMMERING
Oh, well, that did it!
732
00:36:34,180 --> 00:36:36,140
This is such a reactive element
733
00:36:36,140 --> 00:36:39,340
that is soon as it comes into
contact with the air...
734
00:36:39,340 --> 00:36:41,540
in fact, if you have
the lights down,
735
00:36:41,540 --> 00:36:44,940
you might be able to see
some of the sparks that are...
736
00:36:44,940 --> 00:36:46,180
ooh, yes, look at this.
737
00:36:46,180 --> 00:36:48,100
This is SO reactive
that as soon as...
738
00:36:48,100 --> 00:36:49,500
Ooh, dear! Lots of sparks!
739
00:36:49,500 --> 00:36:52,860
..as soon as it as it comes into
contact with the air, it's gone off.
740
00:36:52,860 --> 00:36:56,100
It WAS a nice, shiny metal.
It was a sort of silvery colour.
741
00:36:56,100 --> 00:36:58,220
Sometimes it has a slight
golden colour,
742
00:36:58,220 --> 00:37:01,580
but when comes into contact
with air, it forms this black oxide.
743
00:37:01,580 --> 00:37:04,140
So, the caesium
is incredibly reactive
744
00:37:04,140 --> 00:37:07,260
and it's given its electron
to the oxygen.
745
00:37:07,260 --> 00:37:10,820
But there are other things that can
take the electron away
746
00:37:10,820 --> 00:37:12,980
from these group 1 elements,
747
00:37:12,980 --> 00:37:16,140
and one of them
is contained in this, in bleach.
748
00:37:16,140 --> 00:37:18,660
Does anyone know
what element is in this?
749
00:37:18,660 --> 00:37:20,380
AUDIENCE MEMBER: Chlorine!
750
00:37:20,380 --> 00:37:22,340
Chlorine! Where's chlorine?
751
00:37:22,340 --> 00:37:25,260
Yes, you're in bleach.
This gives the bleach its colour.
752
00:37:25,260 --> 00:37:28,140
You're a really poisonous,
nasty element, I'm afraid.
753
00:37:28,140 --> 00:37:31,780
You were used in World War I
as a toxic gas.
754
00:37:31,780 --> 00:37:33,340
Not very nice!
755
00:37:33,340 --> 00:37:36,940
But you're very efficient, though,
at taking electrons from things.
756
00:37:36,940 --> 00:37:39,580
OK, we're going to see some chlorine
in just a moment,
757
00:37:39,580 --> 00:37:42,620
but before I show you that,
I want to show you something else.
758
00:37:42,620 --> 00:37:45,260
This is a really,
really remarkable book.
759
00:37:45,260 --> 00:37:48,820
This is from the archives
in the Royal Institution here.
760
00:37:48,820 --> 00:37:51,860
And this was from a lecture
761
00:37:51,860 --> 00:37:55,180
that was delivered exactly
200 years ago, in 1812.
762
00:37:55,180 --> 00:37:57,740
And the lectures
were four lectures,
763
00:37:57,740 --> 00:38:01,540
being part of a course on
the elements of chemical philosophy,
764
00:38:01,540 --> 00:38:05,060
delivered by Sir Humphrey Davy
exactly 200 years ago.
765
00:38:05,060 --> 00:38:08,020
Sir Humphrey Davy was
the first person to isolate,
766
00:38:08,020 --> 00:38:10,860
among other elements,
sodium and potassium,
767
00:38:10,860 --> 00:38:13,100
and he also named chlorine
over there.
768
00:38:13,100 --> 00:38:16,540
And these lectures were written down
during the lecture course
769
00:38:16,540 --> 00:38:18,780
by a young Michael Faraday,
770
00:38:18,780 --> 00:38:21,940
who was sitting in the audience,
exactly where you are now.
771
00:38:21,940 --> 00:38:24,660
Davy was so impressed
with these notes
772
00:38:24,660 --> 00:38:26,860
that Faraday wrote up
of the lectures,
773
00:38:26,860 --> 00:38:28,340
that he gave him a job.
774
00:38:28,340 --> 00:38:30,940
He got a job here
at the Royal Institution
775
00:38:30,940 --> 00:38:34,140
and became one of the world's
most famous scientists ever.
776
00:38:34,140 --> 00:38:36,260
Now, I'm certainly no Humphrey Davy,
777
00:38:36,260 --> 00:38:38,580
but who knows,
sitting in this audience
778
00:38:38,580 --> 00:38:41,540
there may well be
the next Michael Faraday.
779
00:38:41,540 --> 00:38:43,980
Now, this is what
I wanted to show you, though.
780
00:38:43,980 --> 00:38:47,620
In this book, Experiments Belonging
To The Lecture On Chlorine,
781
00:38:47,620 --> 00:38:51,900
it says, "Mr Davy exhibited
a specimen of chlorine gas.
782
00:38:51,900 --> 00:38:54,180
"It was in a clean glass tube."
783
00:38:54,180 --> 00:39:00,380
OK, now, we actually have that
original sample of chlorine gas.
784
00:39:00,380 --> 00:39:05,260
Here it is. This is the one
that Davy exhibited back in 1812,
785
00:39:05,260 --> 00:39:07,260
which is quite remarkable.
786
00:39:07,260 --> 00:39:10,380
So chlorine gets its name,
Davy gave it its name,
787
00:39:10,380 --> 00:39:12,940
from the Greek, "chloros"
meaning "green",
788
00:39:12,940 --> 00:39:15,460
because of this
greeny colour that it has.
789
00:39:15,460 --> 00:39:18,900
We even have a sample
of the original sodium,
790
00:39:18,900 --> 00:39:22,780
and this is Davy's original sodium,
791
00:39:22,780 --> 00:39:25,100
prepared here at
the Royal Institution.
792
00:39:25,100 --> 00:39:27,940
This is the metal,
floating, protected in oil,
793
00:39:27,940 --> 00:39:31,980
because, as we've seen,
it goes off in air very quickly.
794
00:39:31,980 --> 00:39:34,940
So, we've got sodium
and we've got chlorine.
795
00:39:34,940 --> 00:39:37,580
Well, what happens
when you mix the two?
796
00:39:37,580 --> 00:39:39,460
Well, you get some sodium chloride.
797
00:39:39,460 --> 00:39:42,460
Now, they would kill me if
I did this, of course, with these,
798
00:39:42,460 --> 00:39:46,340
so I'm not going to use the original
samples of sodium and chlorine.
799
00:39:46,340 --> 00:39:49,340
But we do have some
other samples here.
800
00:39:49,340 --> 00:39:52,180
Here's our sodium,
here's our chlorine.
801
00:39:52,180 --> 00:39:56,220
And you can see this beautiful
green colour now of the chlorine,
802
00:39:56,220 --> 00:39:59,700
you can see the beautiful
silvery colour of the sodium.
803
00:39:59,700 --> 00:40:01,780
We've taken all the air
out of this side,
804
00:40:01,780 --> 00:40:05,020
because we know that sodium
reacts very violently with air,
805
00:40:05,020 --> 00:40:06,620
so there's no air here.
806
00:40:06,620 --> 00:40:09,900
I'm just going to pop my goggles on,
if I can do that one-handedly.
807
00:40:09,900 --> 00:40:14,140
There we go. And I'm now going to
let the chlorine from this side
808
00:40:14,140 --> 00:40:16,380
into this side,
and see what happens.
809
00:40:16,380 --> 00:40:18,020
So let's have a look.
810
00:40:18,020 --> 00:40:21,260
Look at that.
This is sodium meets chlorine,
811
00:40:21,260 --> 00:40:24,180
and the silver mirror
has disappeared,
812
00:40:24,180 --> 00:40:28,580
and we've got this white crust
forming all the way round here.
813
00:40:28,580 --> 00:40:32,420
It's gone white,
looks like salt, and, well,
814
00:40:32,420 --> 00:40:34,660
that's because what
we've made here is salt -
815
00:40:34,660 --> 00:40:36,700
it's sodium chloride.
816
00:40:36,700 --> 00:40:39,300
So the chlorine reacts
with the sodium,
817
00:40:39,300 --> 00:40:42,380
the chlorine takes
the electron from the sodium,
818
00:40:42,380 --> 00:40:44,020
to form white sodium chloride.
819
00:40:44,020 --> 00:40:46,860
This is just the sort of thing
you would put on your chips.
820
00:40:46,860 --> 00:40:48,780
The chlorine itself is poisonous.
821
00:40:48,780 --> 00:40:52,140
It reacts by taking electrons
from your body and poisons you.
822
00:40:52,140 --> 00:40:54,780
The sodium is poisonous.
It gives its electron to you.
823
00:40:54,780 --> 00:40:56,620
But once they've reacted,
824
00:40:56,620 --> 00:40:59,380
we've got sodium chloride
and you eat it.
825
00:40:59,380 --> 00:41:01,180
OK, thank you very much.
826
00:41:01,180 --> 00:41:04,300
APPLAUSE
827
00:41:09,820 --> 00:41:12,460
But there are actually
different sorts of salt.
828
00:41:12,460 --> 00:41:15,700
Sodium chloride is just one salt.
There are others.
829
00:41:15,700 --> 00:41:18,740
And if we have
our halogens up for a moment...
830
00:41:18,740 --> 00:41:21,420
OK, all of you are very good
at forming salts,
831
00:41:21,420 --> 00:41:24,420
especially with group 1. Can we have
group 1 up, as well, please?
832
00:41:24,420 --> 00:41:26,580
OK, any mixtures of you
would form salts.
833
00:41:26,580 --> 00:41:28,700
Not only could we have
sodium chloride,
834
00:41:28,700 --> 00:41:31,820
we could have potassium bromide,
potassium chloride, or so on.
835
00:41:31,820 --> 00:41:34,100
In fact, all of you halogens...
836
00:41:34,100 --> 00:41:37,940
Do you know what the name "halogen"
actually means? Does anyone know?
837
00:41:37,940 --> 00:41:40,260
Does anyone know anywhere?
838
00:41:40,260 --> 00:41:43,220
It means "salt-former".
839
00:41:43,220 --> 00:41:45,940
So you're all really good
forming salts.
840
00:41:45,940 --> 00:41:49,180
In fact, that's how, as a group,
you get your name.
841
00:41:49,180 --> 00:41:51,780
So salts, though,
have very different properties
842
00:41:51,780 --> 00:41:53,700
when they're dissolved in the water.
843
00:41:53,700 --> 00:41:56,140
The water itself
is completely different.
844
00:41:56,140 --> 00:41:58,180
Seawater is not the same
as normal water,
845
00:41:58,180 --> 00:42:00,860
and, well, we have some seawater
here to show you.
846
00:42:00,860 --> 00:42:05,020
Thank you very much, periodic
tables. If you go down for a moment.
847
00:42:05,020 --> 00:42:07,300
So I was fortunate enough
to visit the Dead Sea.
848
00:42:07,300 --> 00:42:10,340
In fact, this is me floating
in the Dead Sea up here.
849
00:42:10,340 --> 00:42:12,380
LAUGHTER
So while I was floating,
850
00:42:12,380 --> 00:42:15,340
I was thinking,
"Well, what would it be like?
851
00:42:15,340 --> 00:42:19,460
"What sort of things could we get
to float on the Dead Sea?"
852
00:42:19,460 --> 00:42:22,700
Well, I need a volunteer, actually,
to help out with this.
853
00:42:22,700 --> 00:42:24,660
And we'll have somebody from...
854
00:42:24,660 --> 00:42:27,140
Yes, yes. If you'd like
to come down. Lovely.
855
00:42:27,140 --> 00:42:29,420
APPLAUSE
Thank you very much.
856
00:42:29,420 --> 00:42:31,540
If you'd like to
face the front here.
857
00:42:31,540 --> 00:42:33,580
What's your name, please? Katie.
858
00:42:33,580 --> 00:42:36,740
Right, good. We need to put
some protective clothing when you,
859
00:42:36,740 --> 00:42:39,700
so just come over here
and put on some protective clothing.
860
00:42:39,700 --> 00:42:42,420
I've got a block of metal here.
861
00:42:42,420 --> 00:42:44,820
Now, what do you think
to this block of metal?
862
00:42:44,820 --> 00:42:47,300
If you just hold this.
What do you think?
863
00:42:47,300 --> 00:42:49,940
It's really heavy.
It's really heavy, yes?
864
00:42:49,940 --> 00:42:53,100
OK, really heavy.
What do you think? How heavy?
865
00:42:53,100 --> 00:42:54,420
Quite heavy, yeah.
866
00:42:54,420 --> 00:42:56,660
So this IS solid metal.
This is actually...
867
00:42:56,660 --> 00:42:59,100
You're looking very good in those!
Very fetching!
868
00:42:59,100 --> 00:43:01,740
We've got a step here,
which was a very good thing!
869
00:43:01,740 --> 00:43:03,740
If you'd like to stand on this step.
870
00:43:03,740 --> 00:43:07,420
OK, this is some salty water.
This is essentially seawater.
871
00:43:07,420 --> 00:43:09,460
I'm going to put on
my gloves, as well.
872
00:43:09,460 --> 00:43:11,980
You haven't held this yet.
If you just hold that.
873
00:43:11,980 --> 00:43:13,620
Just stand there for a moment.
874
00:43:13,620 --> 00:43:16,100
Right, what you think of that?
Quite heavy?
875
00:43:16,100 --> 00:43:17,940
Yeah! Quite heavy, actually!
876
00:43:17,940 --> 00:43:19,420
Yes, it is quite heavy.
877
00:43:19,420 --> 00:43:22,620
Right, do you think it's going to
float in the Dead Sea,
878
00:43:22,620 --> 00:43:24,060
or sink in the Dead Sea?
879
00:43:26,060 --> 00:43:27,540
What you think? 50-50.
880
00:43:27,540 --> 00:43:30,180
Float or sink? Ask the audience?
Float.
881
00:43:30,180 --> 00:43:32,980
Ah, float, OK. Float in the
Dead Sea. Maybe. It's quite heavy.
882
00:43:32,980 --> 00:43:34,420
Covering your bets there.
883
00:43:34,420 --> 00:43:36,500
OK, it is quite heavy,
though, isn't it?
884
00:43:36,500 --> 00:43:38,860
Let's see, shall we?
We're going to drop it in.
885
00:43:38,860 --> 00:43:40,500
You take that side. That's it.
886
00:43:40,500 --> 00:43:41,940
And you put that in the water.
887
00:43:41,940 --> 00:43:45,220
Lower it in gently, you don't want
to splash it everywhere.
888
00:43:45,220 --> 00:43:47,980
That's it. OK, very good.
And just let go.
889
00:43:47,980 --> 00:43:50,060
And... Oh, no!
890
00:43:50,060 --> 00:43:51,500
Aw! Well, it sinks.
891
00:43:51,500 --> 00:43:54,500
It did sink, yes!
It sank pretty quickly.
892
00:43:54,500 --> 00:43:56,260
It was quite heavy, wasn't it?
893
00:43:56,260 --> 00:43:58,060
It did sink pretty quickly there.
894
00:43:58,060 --> 00:44:00,060
I'll see if I can
fish it out for you.
895
00:44:00,060 --> 00:44:02,060
I'll do this,
I've got longer gloves.
896
00:44:02,060 --> 00:44:04,500
And...ooh, not that long!
LAUGHTER
897
00:44:04,500 --> 00:44:08,100
Anyway, right,
out comes the magnesium here.
898
00:44:08,100 --> 00:44:09,820
This is a block of pure magnesium.
899
00:44:09,820 --> 00:44:12,220
It is actually quite heavy,
you're right!
900
00:44:12,220 --> 00:44:15,140
OK, there we are. Now,
we've got some other water here.
901
00:44:15,140 --> 00:44:17,260
So this one contains sodium salts,
902
00:44:17,260 --> 00:44:19,540
but this one contains caesium salts.
903
00:44:19,540 --> 00:44:22,140
And if we just have our group 1
up again for a moment.
904
00:44:22,140 --> 00:44:23,780
Oh, very good! Very efficient!
905
00:44:23,780 --> 00:44:25,460
Sodium right at the top there,
906
00:44:25,460 --> 00:44:27,460
and as we go down,
we get to caesium.
907
00:44:27,460 --> 00:44:30,500
And, so, caesium is actually
heavier than sodium.
908
00:44:30,500 --> 00:44:34,060
And, now, how quickly do you think
this is going to sink in this one?
909
00:44:34,060 --> 00:44:36,780
Er, maybe a bit longer.
Take a bit longer to sink?
910
00:44:36,780 --> 00:44:39,020
Yep, OK, all right.
So shall we try this one?
911
00:44:39,020 --> 00:44:40,940
I'm just going to
put this in the water.
912
00:44:40,940 --> 00:44:43,420
Are you ready? Do you want to
hold it there, as well?
913
00:44:43,420 --> 00:44:45,740
Just gently let go. And, ready?
914
00:44:45,740 --> 00:44:47,380
After three. 1, 2, 3, go!
915
00:44:49,580 --> 00:44:51,820
AUDIENCE GASPS
916
00:44:51,820 --> 00:44:53,500
Ooh!
917
00:44:53,500 --> 00:44:56,180
LAUGHTER
918
00:44:56,180 --> 00:44:59,540
Watch out for your gloves!
LAUGHTER
919
00:44:59,540 --> 00:45:01,580
No, so it's not
actually going to sink.
920
00:45:01,580 --> 00:45:04,820
It actually floats in the water.
So I'll just fish that out,
921
00:45:04,820 --> 00:45:06,980
and I think you should get
a big round of applause
922
00:45:06,980 --> 00:45:09,380
for your help there.
APPLAUSE
923
00:45:09,380 --> 00:45:10,500
Thank you.
924
00:45:10,500 --> 00:45:13,300
We'll just take those off you.
That's it. Lovely stuff.
925
00:45:13,300 --> 00:45:15,380
Thank you very much indeed.
926
00:45:15,380 --> 00:45:18,860
Yes, the block of metal actually
floats in the caesium salts,
927
00:45:18,860 --> 00:45:23,540
and that's because caesium itself
is a heavier atom than sodium is.
928
00:45:23,540 --> 00:45:26,980
We can get other salts, though,
from the Dead Sea, for instance.
929
00:45:26,980 --> 00:45:29,980
It's not just sodium chloride.
In fact, in the Dead Sea
930
00:45:29,980 --> 00:45:32,020
it's quite rich in another salt.
931
00:45:32,020 --> 00:45:34,140
If we have our halogens
back, please.
932
00:45:34,140 --> 00:45:36,900
OK, we have bromine
in the Dead Sea, as well.
933
00:45:36,900 --> 00:45:40,180
It's not as bromine itself,
not as the element. It's as bromide.
934
00:45:40,180 --> 00:45:42,700
This is where it's taken
an electron from something
935
00:45:42,700 --> 00:45:44,500
and formed a negative bromide ion.
936
00:45:44,500 --> 00:45:47,420
So we'd get things like
potassium bromide, sodium bromide,
937
00:45:47,420 --> 00:45:49,540
if we evaporated our Dead Sea water.
938
00:45:49,540 --> 00:45:52,340
And, actually,
I can demonstrate this
939
00:45:52,340 --> 00:45:54,500
with some of the Dead Sea water.
940
00:45:54,500 --> 00:45:56,940
I've got some concentrated
Dead Sea water.
941
00:45:56,940 --> 00:45:58,900
I brought this back
from the Dead Sea.
942
00:45:58,900 --> 00:46:01,860
Just the sort of thing
you normally bring back, I suppose,
943
00:46:01,860 --> 00:46:03,100
if you're a chemist!
944
00:46:03,100 --> 00:46:05,500
Right, here we are.
Here's my Dead Sea water.
945
00:46:05,500 --> 00:46:09,660
And I'm just going to add
some bleach to that.
946
00:46:09,660 --> 00:46:12,260
Of course, the bleach
has chlorine atoms in it.
947
00:46:12,260 --> 00:46:14,460
Watch what happens,
just give it a bit of a...
948
00:46:14,460 --> 00:46:17,540
AUDIENCE GASPS
949
00:46:17,540 --> 00:46:19,980
OK. This, the colour
that you now see...
950
00:46:19,980 --> 00:46:21,740
And we haven't cheated in any way,
951
00:46:21,740 --> 00:46:24,660
this really is just Dead Sea water
that I brought back.
952
00:46:24,660 --> 00:46:27,060
We just concentrated it a bit
by removing some water.
953
00:46:27,060 --> 00:46:28,500
This is just bleach.
954
00:46:28,500 --> 00:46:30,940
The colour that
you see now is bromine.
955
00:46:30,940 --> 00:46:33,980
So with our halogens,
we've got bromide here,
956
00:46:33,980 --> 00:46:37,140
and I've just added some chlorine
that was in the bleach.
957
00:46:37,140 --> 00:46:40,540
So what we have there, the bromide
reacts with the chlorine,
958
00:46:40,540 --> 00:46:43,340
chlorine takes the electron
from bromide,
959
00:46:43,340 --> 00:46:46,700
and forums bromine element
and leaves chloride ions.
960
00:46:46,700 --> 00:46:49,620
But chlorine, look behind you.
Who's behind you?
961
00:46:49,620 --> 00:46:51,020
Fluorine!
962
00:46:51,020 --> 00:46:52,660
Fluorine, exactly!
963
00:46:52,660 --> 00:46:56,100
No fluorine is even better
at taking electrons away,
964
00:46:56,100 --> 00:46:59,140
and fluorine can take the electron
away from chloride.
965
00:46:59,140 --> 00:47:00,620
OK, fluorine, in fact...
966
00:47:00,620 --> 00:47:02,820
That's right, give us a little wave!
967
00:47:02,820 --> 00:47:05,420
Fluorine, you are THE most
reactive non-metal
968
00:47:05,420 --> 00:47:07,140
in the entire periodic table.
969
00:47:07,140 --> 00:47:09,980
You will steal an electron
from every other element
970
00:47:09,980 --> 00:47:13,140
in the entire periodic table,
with the slight exception
971
00:47:13,140 --> 00:47:15,620
of the very inert noble gases
sitting next to you.
972
00:47:15,620 --> 00:47:18,860
But everything else, you will
react with. Very, very violent.
973
00:47:18,860 --> 00:47:21,300
Fluorine is probably
THE most reactive element
974
00:47:21,300 --> 00:47:22,940
in the entire periodic table.
975
00:47:22,940 --> 00:47:25,180
Certainly the most
reactive non-metal.
976
00:47:25,180 --> 00:47:28,820
Even as a chemist,
I had never seen any fluorine,
977
00:47:28,820 --> 00:47:31,260
and I thought, for these lectures,
978
00:47:31,260 --> 00:47:35,500
it would be really nice to bring
some fluorine into the lectures
979
00:47:35,500 --> 00:47:37,780
and I needed to find
a specialist to do this.
980
00:47:37,780 --> 00:47:41,100
So, would you please welcome,
from the University of Leicester,
981
00:47:41,100 --> 00:47:43,460
Professor Eric Hope,
a fluorine chemist.
982
00:47:43,460 --> 00:47:46,220
APPLAUSE
983
00:47:47,740 --> 00:47:49,500
Eric, thank you
for coming along.
984
00:47:49,500 --> 00:47:51,380
So, Eric is a fluorine specialist.
985
00:47:51,380 --> 00:47:53,420
Fluorine is incredibly reactive.
986
00:47:53,420 --> 00:47:56,380
It reacts with just about
everything, doesn't it? Indeed.
987
00:47:56,380 --> 00:47:59,420
So, the question everyone wants
to ask is, how do you store it?
988
00:47:59,420 --> 00:48:02,180
Doesn't it react with
the container you put it in?
989
00:48:02,180 --> 00:48:03,700
It does react with the container.
990
00:48:03,700 --> 00:48:06,580
You can store it in
metal containers, stainless steel,
991
00:48:06,580 --> 00:48:08,900
or we hold it in nickel
containers in Leicester.
992
00:48:08,900 --> 00:48:11,180
And what happens is
the fluorine reacts
993
00:48:11,180 --> 00:48:12,900
with a coating of the metal,
994
00:48:12,900 --> 00:48:15,700
you get nickel difluoride,
a very few microns thick,
995
00:48:15,700 --> 00:48:17,780
protects the rest
of the nickel metal,
996
00:48:17,780 --> 00:48:19,740
and you get an impervious layer.
997
00:48:19,740 --> 00:48:23,140
So it HAS reacted, and what it's
formed is pretty inert afterwards.
998
00:48:23,140 --> 00:48:24,340
Indeed, yes.
999
00:48:24,340 --> 00:48:27,420
But fluorine is incredibly
reactive and dangerous, isn't it?
1000
00:48:27,420 --> 00:48:30,660
If you control and handle it
under appropriate conditions,
1001
00:48:30,660 --> 00:48:33,700
then it is dangerous,
but it's not THAT dangerous.
1002
00:48:33,700 --> 00:48:36,660
It's very reactive, isn't it?
It'll react, as you said,
1003
00:48:36,660 --> 00:48:39,340
with virtually every element
in the periodic table.
1004
00:48:39,340 --> 00:48:42,980
When I contacted Eric, I thought,
fluorine, really reactive,
1005
00:48:42,980 --> 00:48:46,300
it would be very great if we could
bring some of this into the RI.
1006
00:48:46,300 --> 00:48:49,060
But one reaction that
I've always wanted to try
1007
00:48:49,060 --> 00:48:51,140
is the reaction between fluorine -
1008
00:48:51,140 --> 00:48:54,420
because, you know, it is one of
THE most reactive non-metals -
1009
00:48:54,420 --> 00:48:56,940
I thought I'd like to try
the reaction of fluorine
1010
00:48:56,940 --> 00:48:59,980
with THE most reactive metal
in the periodic table, caesium.
1011
00:48:59,980 --> 00:49:02,780
Yes, you are best electron-giver!
Very generous!
1012
00:49:02,780 --> 00:49:05,260
So this should be
a really violent reaction.
1013
00:49:05,260 --> 00:49:06,940
I thought, I'd love to see this!
1014
00:49:06,940 --> 00:49:09,820
What did you think of this,
when I said I wanted to try
1015
00:49:09,820 --> 00:49:12,260
the reaction of fluorine
with caesium?
1016
00:49:12,260 --> 00:49:15,460
I thought it was the most outlandish
thing I'd ever heard,
1017
00:49:15,460 --> 00:49:18,540
and it took me a good 24 hours
to think about whether or not
1018
00:49:18,540 --> 00:49:20,660
it was feasible or possible
to actually do.
1019
00:49:20,660 --> 00:49:23,820
OK. Yes, exactly, we did wonder
whether we could actually do this.
1020
00:49:23,820 --> 00:49:25,980
Shall we just have
the periodic table down?
1021
00:49:25,980 --> 00:49:28,060
We thought,
"How could we do this safely?"
1022
00:49:28,060 --> 00:49:29,620
And we did have a practice
1023
00:49:29,620 --> 00:49:31,780
just to make sure
we could do this safely.
1024
00:49:31,780 --> 00:49:33,900
In fact, the remarkable thing was,
1025
00:49:33,900 --> 00:49:37,020
as I say, I'm a chemist,
and I've never actually seen...
1026
00:49:37,020 --> 00:49:39,660
I hadn't seen fluorine before,
before I went up to Leicester,
1027
00:49:39,660 --> 00:49:42,260
and remarkably, well...
I've never seen caesium before!
1028
00:49:42,260 --> 00:49:44,060
Eric had never seen caesium!
1029
00:49:44,060 --> 00:49:46,980
So we thought we HAD to
get together, really!
1030
00:49:46,980 --> 00:49:49,780
So I thought I'd bring
my caesium along to Leicester,
1031
00:49:49,780 --> 00:49:51,340
and we did test things,
1032
00:49:51,340 --> 00:49:53,700
and we're going to try
and do this for you now.
1033
00:49:53,700 --> 00:49:56,700
I'm actually just going to
hold this in my hand.
1034
00:49:56,700 --> 00:50:00,100
Just holding this in my hand
actually just melts the caesium.
1035
00:50:00,100 --> 00:50:03,860
So the bond between the
caesium atoms here are so weak,
1036
00:50:03,860 --> 00:50:06,940
just holding it in my hand
melts this. There we are.
1037
00:50:06,940 --> 00:50:09,780
We've certainly got some caesium
at the bottom of this tube.
1038
00:50:11,620 --> 00:50:13,540
Right, we're going to try, then,
1039
00:50:13,540 --> 00:50:16,420
the reaction between
caesium and fluorine.
1040
00:50:16,420 --> 00:50:21,860
The caesium is protected
by this blanket of argon...
1041
00:50:24,700 --> 00:50:27,180
..which is heavier than air.
1042
00:50:27,180 --> 00:50:29,980
And we've seen that caesium
reacts with the air.
1043
00:50:33,100 --> 00:50:36,060
And I'm just going to
lower this on...
1044
00:50:41,780 --> 00:50:44,500
..like so, and push this down.
1045
00:50:47,020 --> 00:50:49,100
OK, and I think we're ready
to try, then.
1046
00:50:51,060 --> 00:50:52,380
Ah!
1047
00:50:52,380 --> 00:50:55,380
AUDIENCE GASPS
APPLAUSE
1048
00:51:18,380 --> 00:51:19,780
We have to just use a tiny,
tiny bit. It's in this tube here.
1049
00:51:19,780 --> 00:51:23,020
But it did react very,
very violently with the caesium,
1050
00:51:23,020 --> 00:51:24,660
to form caesium fluoride.
1051
00:51:24,660 --> 00:51:27,460
OK, well, I think we need to give
a big round of applause
1052
00:51:27,460 --> 00:51:29,300
to Professor Eric Hope.
1053
00:51:29,300 --> 00:51:31,220
APPLAUSE
1054
00:51:34,420 --> 00:51:37,860
So, once the caesium has reacted
with the fluorine,
1055
00:51:37,860 --> 00:51:40,500
again, the caesium
gives up its electron,
1056
00:51:40,500 --> 00:51:43,980
and it's no longer the reactive
caesium metal that we started with.
1057
00:51:43,980 --> 00:51:46,820
And, of course, the fluorine,
once it grabs the electron,
1058
00:51:46,820 --> 00:51:49,420
it's no longer the reactive
fluorine we started with.
1059
00:51:49,420 --> 00:51:51,460
We've got fluoride ion.
1060
00:51:51,460 --> 00:51:54,500
And actually, remarkably,
fluoride is something that, again,
1061
00:51:54,500 --> 00:51:57,380
you can find in every
glass of drinking water you have.
1062
00:51:57,380 --> 00:52:00,100
This is actually added
to our tap water
1063
00:52:00,100 --> 00:52:03,420
because it protects our teeth
and prevents decay.
1064
00:52:03,420 --> 00:52:05,540
Now, talking of preventing decay,
1065
00:52:05,540 --> 00:52:09,140
I think we need to see how our
Fountain of Youth volunteer got on,
1066
00:52:09,140 --> 00:52:12,380
and see how whether it
really has worked after all.
1067
00:52:12,380 --> 00:52:14,860
So, Tim, how's it doing?
1068
00:52:14,860 --> 00:52:18,060
Has it worked?
I feel a lot younger!
1069
00:52:18,060 --> 00:52:20,100
Tim, is that really you?!
1070
00:52:21,420 --> 00:52:24,300
Ah, I can see what they did there!
1071
00:52:24,300 --> 00:52:27,580
LAUGHTER AND APPLAUSE
1072
00:52:31,260 --> 00:52:33,500
Tim, do you feel
any different at all?
1073
00:52:33,500 --> 00:52:35,940
No different at all, I'm afraid.
Just the same age.
1074
00:52:35,940 --> 00:52:39,620
OK, so it really looks like
our Fountain of Youth water
1075
00:52:39,620 --> 00:52:42,860
perhaps isn't restoring
Tim's youth to him.
1076
00:52:42,860 --> 00:52:46,540
But, nonetheless, water does play
a very important role in our lives.
1077
00:52:46,540 --> 00:52:48,340
Without it, we'd all be dead.
1078
00:52:48,340 --> 00:52:51,140
And this is because water
actually enables
1079
00:52:51,140 --> 00:52:53,300
chemical reactions to take place,
1080
00:52:53,300 --> 00:52:56,820
both inside the cells in your body
and in other reactions.
1081
00:52:56,820 --> 00:53:01,540
And this is what we're going to
demonstrate now. I have...
1082
00:53:01,540 --> 00:53:06,740
We've placed some magnesium powder
and some silver nitrate.
1083
00:53:06,740 --> 00:53:09,300
Now, they are touching
each other at the moment.
1084
00:53:09,300 --> 00:53:12,740
They're mixed up very intimately,
but not quite intimately enough.
1085
00:53:12,740 --> 00:53:15,500
What they need is to get
into really close contact,
1086
00:53:15,500 --> 00:53:17,780
and we do that
by adding a drop of water.
1087
00:53:17,780 --> 00:53:21,860
OK, now, they've given me
a glass of water and a pipette,
1088
00:53:21,860 --> 00:53:25,940
but I think I'm going to need the
slightly longer pipette, please.
1089
00:53:25,940 --> 00:53:27,380
This is quite a violent...
1090
00:53:27,380 --> 00:53:29,940
Thank you, that's a better one.
Right, now...
1091
00:53:31,820 --> 00:53:34,060
I'm going to take
the lid off of this.
1092
00:53:34,060 --> 00:53:36,500
It's sitting here
quite happily the moment,
1093
00:53:36,500 --> 00:53:38,300
nothing is taking place,
1094
00:53:38,300 --> 00:53:41,660
until we add a drop of water.
1095
00:53:41,660 --> 00:53:43,860
OK, I'm adding it now.
1096
00:53:45,220 --> 00:53:47,820
AUDIENCE GASPS
1097
00:53:47,820 --> 00:53:50,740
APPLAUSE
1098
00:53:58,380 --> 00:54:02,180
So this is an incredibly
violent reaction that takes place,
1099
00:54:02,180 --> 00:54:06,140
but it didn't take place
until we added the water.
1100
00:54:06,140 --> 00:54:09,740
So, maybe this gives us a method
for slowing reactions down,
1101
00:54:09,740 --> 00:54:11,620
if we remove the water.
1102
00:54:11,620 --> 00:54:14,700
Well, I think, actually,
it's getting time for my dinner,
1103
00:54:14,700 --> 00:54:17,940
and they've brought on some bananas!
1104
00:54:17,940 --> 00:54:21,580
Great! And these bananas
have seen better days.
1105
00:54:21,580 --> 00:54:26,780
Now, these bananas, I know,
are two weeks old, actually.
1106
00:54:26,780 --> 00:54:28,220
They've been sort of...eurgh!
1107
00:54:30,100 --> 00:54:31,660
AUDIENCE GROANS
1108
00:54:31,660 --> 00:54:33,940
It's actually a banana...
1109
00:54:33,940 --> 00:54:36,540
AUDIENCE GROANS LOUDLY
1110
00:54:37,980 --> 00:54:41,420
It's seen better days, I think.
1111
00:54:41,420 --> 00:54:43,740
But this banana...
1112
00:54:43,740 --> 00:54:46,780
..this banana, this one
was two weeks old.
1113
00:54:46,780 --> 00:54:50,340
This banana here is
actually six YEARS old.
1114
00:54:50,340 --> 00:54:53,260
AUDIENCE GROANS
Yeah, if I was going to eat one,
1115
00:54:53,260 --> 00:54:55,220
I know which one I'd rather have!
1116
00:54:55,220 --> 00:54:57,140
Now, why has this one
lasted so long?
1117
00:54:57,140 --> 00:54:59,180
Actually, what do you think?
Have a look at this.
1118
00:54:59,180 --> 00:55:01,780
What do you think?
What does it feel like?
1119
00:55:01,780 --> 00:55:03,140
Scaly. Scaly? Uh-huh.
1120
00:55:03,140 --> 00:55:06,660
What do you think?
What do you think it feels like?
1121
00:55:06,660 --> 00:55:09,020
Quite hard. Quite hard, yes.
1122
00:55:09,020 --> 00:55:10,540
It IS quite hard.
1123
00:55:10,540 --> 00:55:13,940
And this is because we've removed
all the water from this banana.
1124
00:55:13,940 --> 00:55:15,820
But this has actually preserved it.
1125
00:55:15,820 --> 00:55:18,060
It's stopped the reactions
taking place,
1126
00:55:18,060 --> 00:55:20,100
the normal reactions
where things go bad,
1127
00:55:20,100 --> 00:55:22,100
reactions taking place in the cells.
1128
00:55:22,100 --> 00:55:24,340
If we remove the water,
they can't happen.
1129
00:55:24,340 --> 00:55:27,580
And, well, maybe this could be
a way of preserving our good looks,
1130
00:55:27,580 --> 00:55:29,220
if we just remove the water?
1131
00:55:29,220 --> 00:55:31,820
Well, you could, and this is what
you might look like.
1132
00:55:31,820 --> 00:55:34,900
LAUGHTER
Well, this chap
might not look too good,
1133
00:55:34,900 --> 00:55:39,500
but he is 800 years old,
which is quite remarkable!
1134
00:55:39,500 --> 00:55:42,060
And the reason he's survived
looking like this
1135
00:55:42,060 --> 00:55:45,060
is because all the water
was removed when he died.
1136
00:55:45,060 --> 00:55:47,100
He died in the north coast of Peru.
1137
00:55:47,100 --> 00:55:49,780
It's very dry there,
and removing the water
1138
00:55:49,780 --> 00:55:52,420
has actually preserved
the cells of his body.
1139
00:55:52,420 --> 00:55:56,500
So maybe, then, this does give us
a clue to eternal life -
1140
00:55:56,500 --> 00:55:59,140
Remove the water and you can live
a long time -
1141
00:55:59,140 --> 00:56:00,740
well, looking like that -
1142
00:56:00,740 --> 00:56:04,780
but, of course, we need water
for our reactions to take place,
1143
00:56:04,780 --> 00:56:08,020
and so, well, I certainly know
which one I'm going to choose.
1144
00:56:08,020 --> 00:56:09,860
I think I'm going to stick to
1145
00:56:09,860 --> 00:56:13,100
keeping drinking the water
and staying alive.
1146
00:56:13,100 --> 00:56:15,740
Mmm! Freshly synthesised water,
delicious!
1147
00:56:15,740 --> 00:56:19,780
And I think, actually,
it's time for you to all have some
1148
00:56:19,780 --> 00:56:22,580
freshly synthesised water, as well.
1149
00:56:22,580 --> 00:56:25,900
So you may have noticed that
all around the lecture theatre
1150
00:56:25,900 --> 00:56:27,940
here is this very long tube.
1151
00:56:27,940 --> 00:56:30,980
This is over
half a kilometre of tubing,
1152
00:56:30,980 --> 00:56:35,700
filled with hydrogen and oxygen in
the right proportions to make water.
1153
00:56:35,700 --> 00:56:38,500
So we're going to synthesise
some water now.
1154
00:56:38,500 --> 00:56:41,900
So I need the end of the tubes,
please. OK, here they come.
1155
00:56:41,900 --> 00:56:44,020
Excellent. Thank you very much.
1156
00:56:44,020 --> 00:56:46,500
APPLAUSE
1157
00:56:50,940 --> 00:56:52,980
OK, now, the ends have some corks in
1158
00:56:52,980 --> 00:56:55,740
and we don't want to fire these
into our audience,
1159
00:56:55,740 --> 00:56:58,620
so we're going to fire them
into this bucket of water.
1160
00:56:58,620 --> 00:57:00,940
AUDIENCE: Aw!
HE LAUGHS
1161
00:57:00,940 --> 00:57:04,100
No, don't say "Aw!" - you wouldn't
want this! I can assure you!
1162
00:57:04,100 --> 00:57:06,900
Right, OK. But before
I do this, though,
1163
00:57:06,900 --> 00:57:09,180
before we do this final thing here,
1164
00:57:09,180 --> 00:57:11,620
I hope you don't feel
too disappointed
1165
00:57:11,620 --> 00:57:15,100
that we haven't found
the secret to eternal youth.
1166
00:57:15,100 --> 00:57:18,220
But we have discovered
a whole host of exciting elements
1167
00:57:18,220 --> 00:57:19,860
in that one glass of water.
1168
00:57:19,860 --> 00:57:21,940
Some of these elements
were deadly toxic
1169
00:57:21,940 --> 00:57:24,140
and others were explosive metals.
1170
00:57:24,140 --> 00:57:26,740
In the next lecture,
we're going to find out
1171
00:57:26,740 --> 00:57:30,780
how chemists are trying to extract
exciting elements from the Earth.
1172
00:57:30,780 --> 00:57:32,780
These are elements that have been
1173
00:57:32,780 --> 00:57:35,140
trapped in rocks
for billions of years.
1174
00:57:35,140 --> 00:57:36,580
And we'll also try to solve
1175
00:57:36,580 --> 00:57:38,820
the biggest alchemical
mystery of them all,
1176
00:57:38,820 --> 00:57:41,460
how to turn lead into gold.
1177
00:57:41,460 --> 00:57:43,340
But before we finish, though,
1178
00:57:43,340 --> 00:57:47,820
I think it's time for everyone to
get their freshly synthesised water.
1179
00:57:47,820 --> 00:57:49,100
So we'll have...
1180
00:57:49,100 --> 00:57:51,260
Yes, I need to move this from here!
1181
00:57:51,260 --> 00:57:55,420
OK, and we'll have a countdown
from three when you're ready.
1182
00:57:55,420 --> 00:57:57,460
So we're just going to aim these.
1183
00:57:57,460 --> 00:57:59,540
And if we have the lights down? OK.
1184
00:57:59,540 --> 00:58:02,980
So, you might want to be looking up,
rather than down at us.
1185
00:58:02,980 --> 00:58:04,980
OK, you look up at the pipe.
1186
00:58:04,980 --> 00:58:07,020
OK, so, three, two, one!
1187
00:58:08,300 --> 00:58:11,380
EXPLOSION
SCREAMS
1188
00:58:11,380 --> 00:58:13,820
HE LAUGHS
Thank you very much!
1189
00:58:13,820 --> 00:58:16,420
APPLAUSE AND CHEERING
Good night, thank you!
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00:58:44,820 --> 00:58:48,860
Subtitles by Red Bee Media Ltd
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