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Would you like to inspect the original subtitles? These are the user uploaded subtitles that are being translated: 1 00:00:07,173 --> 00:00:10,343 DAVID POGUE: Why do bombs go boom? 2 00:00:10,376 --> 00:00:12,311 You have created fire! 3 00:00:12,344 --> 00:00:13,379 I could feel that puppy! 4 00:00:13,412 --> 00:00:16,149 How much gold is in 400 tons of dirt? 5 00:00:16,182 --> 00:00:17,917 MIKE LASSITER: There's about a million and a half dollars there. 6 00:00:17,950 --> 00:00:19,786 Oh, man! 7 00:00:19,819 --> 00:00:20,987 What's that gorilla doing there? 8 00:00:21,020 --> 00:00:23,089 POGUE: And how come rare earths, 9 00:00:23,122 --> 00:00:25,525 the metals that make our gadgets go, 10 00:00:25,558 --> 00:00:27,126 aren't that rare at all? 11 00:00:27,159 --> 00:00:28,261 Watch out with the hammer. What are you... ? 12 00:00:28,294 --> 00:00:30,229 Oh yeah, cerium, lanthanum, praseodymium. 13 00:00:30,262 --> 00:00:34,600 POGUE: We live in a world of incredible material variety. 14 00:00:34,633 --> 00:00:35,835 Yet everything we know-- 15 00:00:35,868 --> 00:00:39,472 the stars, the planets, and life itself-- 16 00:00:39,505 --> 00:00:42,842 comes from about 90 basic building blocks. 17 00:00:42,875 --> 00:00:44,410 You have a periodic table table! 18 00:00:44,443 --> 00:00:49,048 All right here on this remarkable chart: 19 00:00:49,081 --> 00:00:52,618 the periodic table of the elements. 20 00:00:52,651 --> 00:00:54,821 It's a story that begins with the Big Bang 21 00:00:54,854 --> 00:00:56,923 and eventually leads to us. 22 00:00:56,956 --> 00:00:59,192 And we're made almost entirely 23 00:00:59,225 --> 00:01:01,828 of just a handful of ingredients, 24 00:01:01,861 --> 00:01:06,899 including one that burns with secret fire inside us all. 25 00:01:06,932 --> 00:01:10,336 Join me as I explore the basic building blocks of the universe. 26 00:01:10,369 --> 00:01:10,369 (explosion) 27 00:01:10,369 --> 00:01:11,838 Oh! 28 00:01:11,871 --> 00:01:14,207 From some of the most common, like oxygen... 29 00:01:14,240 --> 00:01:15,141 How do you feel at this stage? 30 00:01:15,174 --> 00:01:16,576 POGUE: ...to the least-- 31 00:01:16,609 --> 00:01:20,146 man-made elements that last only fractions of a second. 32 00:01:20,179 --> 00:01:23,516 Strange metals with repellant powers. 33 00:01:23,549 --> 00:01:24,817 And you're saying that this will repel the sharks. 34 00:01:24,850 --> 00:01:26,285 Oh my gosh! 35 00:01:26,318 --> 00:01:26,953 Ugh! 36 00:01:26,986 --> 00:01:28,321 Poisonous gases... 37 00:01:28,354 --> 00:01:29,422 Isn't chlorine deadly? 38 00:01:29,455 --> 00:01:30,490 MAN: Absolutely. 39 00:01:30,523 --> 00:01:32,625 POGUE: ...in stuff we eat every day. 40 00:01:32,658 --> 00:01:35,895 And now we can even see what they're made of. 41 00:01:35,928 --> 00:01:37,296 The dots are actual atoms? 42 00:01:37,329 --> 00:01:38,931 If you're like me, 43 00:01:38,964 --> 00:01:41,534 you care about the elements and how they go together. 44 00:01:41,567 --> 00:01:42,768 Oh, the humanity! 45 00:01:42,801 --> 00:01:43,836 Because more than ever... 46 00:01:43,869 --> 00:01:46,072 Incoming neutron! 47 00:01:46,105 --> 00:01:48,374 ... matter matters. 48 00:01:48,407 --> 00:01:49,475 Copper is king. 49 00:01:49,508 --> 00:01:51,344 Commodities! Copper at 80 cents a pound! 50 00:01:51,377 --> 00:01:52,912 Can we crack the code... 51 00:01:52,945 --> 00:01:54,113 (bell rings) 52 00:01:54,146 --> 00:01:55,948 ...to build the world of the future? 53 00:01:55,981 --> 00:01:59,652 Join me on my hunt for the elements. 54 00:01:59,685 --> 00:02:02,055 Right now, on NOVA. 55 00:02:29,215 --> 00:02:33,953 POGUE: Far from prying eyes, the ground erupts. 56 00:02:33,986 --> 00:02:37,023 Heavy equipment moving millions of tons of earth 57 00:02:37,056 --> 00:02:40,593 in search of... something. 58 00:02:40,626 --> 00:02:44,297 A secret deep underground. 59 00:02:46,699 --> 00:02:48,534 I'm David Pogue. 60 00:02:48,567 --> 00:02:52,805 I've managed to talk my way into this hidden lair. 61 00:02:52,838 --> 00:02:55,074 Probably almost a mile from where we first came in. 62 00:02:55,107 --> 00:02:57,076 POGUE: Boy, I hope I can talk my way out. 63 00:02:57,109 --> 00:02:59,612 MAN: This area here has been back-filled. 64 00:02:59,645 --> 00:03:02,114 POGUE: They tell me that so much money flows out of this place, 65 00:03:02,147 --> 00:03:04,417 it's like a gold mine. 66 00:03:05,284 --> 00:03:06,719 Wait a minute... 67 00:03:06,752 --> 00:03:09,522 It is a gold mine! 68 00:03:09,555 --> 00:03:11,624 But where's the gold? 69 00:03:11,657 --> 00:03:14,060 It turns out that nature has concealed 70 00:03:14,093 --> 00:03:15,761 thousands of pounds of the stuff 71 00:03:15,794 --> 00:03:18,764 under billions of cubic feet of earth. 72 00:03:18,797 --> 00:03:22,969 By digging, these guys are hoping to strike it rich. 73 00:03:23,002 --> 00:03:25,404 But that's not why I'm here. 74 00:03:25,437 --> 00:03:28,241 I'm on a quest to understand 75 00:03:28,274 --> 00:03:31,110 the basic building blocks of everyday matter. 76 00:03:31,143 --> 00:03:34,413 They're called the elements. 77 00:03:34,446 --> 00:03:36,515 These symbols represent the atoms 78 00:03:36,548 --> 00:03:39,986 that make up every single thing in our universe. 79 00:03:40,019 --> 00:03:44,724 118 unique substances arranged on an amazing chart 80 00:03:44,757 --> 00:03:47,126 that reveals their hidden secrets 81 00:03:47,159 --> 00:03:49,762 to anyone who knows how to read it. 82 00:03:49,795 --> 00:03:53,933 It's a journey that dives deep into the metals of civilization, 83 00:03:53,966 --> 00:03:59,739 marvels at the mysteries of the extremely reactive, 84 00:03:59,772 --> 00:04:01,340 reveals hidden powers, 85 00:04:01,373 --> 00:04:04,443 and harnesses secrets of life, 86 00:04:04,476 --> 00:04:06,912 from hydrogen 87 00:04:06,945 --> 00:04:10,116 to uranium and beyond. 88 00:04:10,149 --> 00:04:12,518 I'm starting with one of humanity's 89 00:04:12,551 --> 00:04:14,387 first elemental loves: 90 00:04:14,420 --> 00:04:15,655 gold. 91 00:04:15,688 --> 00:04:17,390 Symbol: Au. 92 00:04:17,423 --> 00:04:19,792 Like all elements, gold is an atom 93 00:04:19,825 --> 00:04:22,795 that gets its identity from tiny particles-- 94 00:04:22,828 --> 00:04:25,898 positively charged protons in the nucleus 95 00:04:25,931 --> 00:04:30,836 balanced by negatively charged electrons all around, 96 00:04:30,869 --> 00:04:34,407 plus neutrons, which have no charge at all. 97 00:04:34,440 --> 00:04:37,109 Gold has been sought since ancient times, 98 00:04:37,142 --> 00:04:41,414 yet all the gold ever mined would fit into a single cube 99 00:04:41,447 --> 00:04:44,116 about 60 feet on a side. 100 00:04:44,149 --> 00:04:46,519 Gold is unique among the metals. 101 00:04:46,552 --> 00:04:49,121 It doesn't rust or tarnish. 102 00:04:49,154 --> 00:04:54,360 It's virtually indestructible, yet also soft and malleable. 103 00:04:54,393 --> 00:04:57,263 It was a sacred material to ancient people. 104 00:04:58,997 --> 00:05:02,735 And it's never lost its luster. 105 00:05:02,768 --> 00:05:07,840 The problem is, it's exceedingly rare stuff in the earth's crust, 106 00:05:07,873 --> 00:05:11,277 and it's getting harder to find all the time. 107 00:05:11,310 --> 00:05:13,746 Here at the Cortez Mine in Nevada, 108 00:05:13,779 --> 00:05:16,282 high-tech prospectors are moving mountains, 109 00:05:16,315 --> 00:05:21,220 closing in from above and below. 110 00:05:23,655 --> 00:05:27,326 This rock face is about a quarter mile below the surface. 111 00:05:27,359 --> 00:05:31,697 And according to John Taule, it's loaded with gold. 112 00:05:31,730 --> 00:05:32,965 Somewhere... 113 00:05:32,998 --> 00:05:34,200 And what would it look like? 114 00:05:34,233 --> 00:05:37,136 Like yellow, metallic streaks in the walls? 115 00:05:39,805 --> 00:05:41,574 No, it's really hard to tell from the rock, 116 00:05:41,607 --> 00:05:44,276 because it's microscopic, you can't see the gold. 117 00:05:44,309 --> 00:05:45,845 The gold is microscopic? 118 00:05:45,878 --> 00:05:47,513 Yes, you can't see it with the naked eye. 119 00:05:47,546 --> 00:05:49,982 So we're way past the days 120 00:05:50,015 --> 00:05:52,885 of finding big gold nuggets sticking out of the wall, going, 121 00:05:52,918 --> 00:05:54,320 "Hey Bob, I got one here!" 122 00:05:54,353 --> 00:05:55,688 We're past that now, huh? 123 00:05:55,721 --> 00:05:56,856 That's correct. 124 00:05:59,057 --> 00:06:02,328 POGUE: Which raises a question: 125 00:06:02,361 --> 00:06:05,498 if the gold is invisible to the naked eye, 126 00:06:05,531 --> 00:06:10,302 how do they even know if they're digging in the right place? 127 00:06:10,335 --> 00:06:14,874 That's where Gayle Fitzwater and the assay team come in. 128 00:06:14,907 --> 00:06:18,277 Every day, she receives hundreds of samples of earth 129 00:06:18,310 --> 00:06:21,180 taken from the mine. 130 00:06:21,213 --> 00:06:23,315 Her job is to figure out 131 00:06:23,348 --> 00:06:26,819 how much gold is in them there rocks. 132 00:06:26,852 --> 00:06:29,789 To get at the color, it has to be crushed... 133 00:06:29,822 --> 00:06:31,357 Do you want ice cream with this? 134 00:06:31,390 --> 00:06:34,560 ... shuffled like a deck of cards... 135 00:06:34,593 --> 00:06:36,829 I think I've seen one of these machines at Starbucks. 136 00:06:36,862 --> 00:06:40,666 ... then pulverized to the consistency of baby powder. 137 00:06:40,699 --> 00:06:42,635 I don't see any more rocks in here. 138 00:06:42,668 --> 00:06:44,837 But the bad news is, I don't see any gold in here, either. 139 00:06:44,870 --> 00:06:47,673 The good news is that we haven't finished. 140 00:06:47,706 --> 00:06:50,776 There may be still gold hiding in the mix. 141 00:06:50,809 --> 00:06:55,581 The sample, mixed with a lead oxide powder, 142 00:06:55,614 --> 00:06:59,585 goes into a furnace heated to 2,000 degrees. 143 00:06:59,618 --> 00:07:04,056 It's a 500-year-old process called a fire assay. 144 00:07:04,089 --> 00:07:07,860 Using extreme heat, gold atoms are gradually coaxed away 145 00:07:07,893 --> 00:07:10,463 from the powdered rock. 146 00:07:13,365 --> 00:07:14,733 So after all that pulverizing 147 00:07:14,766 --> 00:07:16,702 and crushing and weighing and firing, 148 00:07:16,735 --> 00:07:20,272 what we're left with is this, these little teacups? 149 00:07:20,305 --> 00:07:22,308 What you're going to be able to see in here 150 00:07:22,341 --> 00:07:24,977 is a gold bead that was recovered 151 00:07:25,010 --> 00:07:28,013 from that sample that you crushed. 152 00:07:28,046 --> 00:07:29,548 Um, no. 153 00:07:29,581 --> 00:07:30,616 Okay, come on. 154 00:07:30,649 --> 00:07:32,251 This is like the emperor's new teacup. 155 00:07:32,284 --> 00:07:37,356 There's nothing in here except that little tiny piece of dust. 156 00:07:37,389 --> 00:07:38,991 That's a piece of gold. 157 00:07:39,024 --> 00:07:41,727 That actually weighs about a half a milligram. 158 00:07:41,760 --> 00:07:45,331 So all that work gave you only a half a milligram of gold? 159 00:07:45,364 --> 00:07:46,565 It equals out 160 00:07:46,598 --> 00:07:48,067 to about one ounce per ton. 161 00:07:48,100 --> 00:07:50,803 An ounce of gold for every ton of rock? 162 00:07:50,836 --> 00:07:51,670 That's right, and... 163 00:07:51,703 --> 00:07:52,872 That's a terrible business! 164 00:07:52,905 --> 00:07:54,740 You'll never make any money. 165 00:07:56,608 --> 00:07:59,044 FITZWATER: When you went in the mine 166 00:07:59,077 --> 00:08:01,714 and you were able to see the trucks that we had, 167 00:08:01,747 --> 00:08:04,683 those are 400-ton haul packs. 168 00:08:04,716 --> 00:08:06,852 If you had 400 tons of material at one ounce per ton... 169 00:08:06,885 --> 00:08:13,092 400 tons and one ounce of gold for each ton. 170 00:08:13,125 --> 00:08:17,963 At that rate, that's 25 pounds of gold for every truck. 171 00:08:17,996 --> 00:08:20,666 And at $1,800 an ounce... 172 00:08:20,699 --> 00:08:22,868 $1,800 times... 173 00:08:22,901 --> 00:08:26,105 $720,000 a truck! 174 00:08:27,372 --> 00:08:29,308 This is a fantastic business! 175 00:08:29,341 --> 00:08:30,643 How do I get in on this? 176 00:08:30,676 --> 00:08:33,712 POGUE: Turns out that an ounce per ton 177 00:08:33,745 --> 00:08:37,016 is pretty much optimal for the underground mine. 178 00:08:37,049 --> 00:08:42,121 The surface mine produces less, about half an ounce per ton. 179 00:08:43,689 --> 00:08:44,823 To see what it takes 180 00:08:44,856 --> 00:08:47,426 to get something bigger than that tiny bead, 181 00:08:47,459 --> 00:08:50,896 I visit the processing plant where the ore ends up. 182 00:08:50,929 --> 00:08:53,098 Just another day in the gold refinery. 183 00:08:53,131 --> 00:08:57,469 Here too, extraction begins with crushing 184 00:08:57,502 --> 00:09:00,940 in these huge tumblers. 185 00:09:00,973 --> 00:09:02,841 And that sets the stage for the trickiest step: 186 00:09:02,874 --> 00:09:07,780 coaxing the microscopic gold out of the rocky ore. 187 00:09:07,813 --> 00:09:11,951 About three quarters of the elements are metals. 188 00:09:11,984 --> 00:09:15,688 And gold is one of the most standoffish. 189 00:09:15,721 --> 00:09:19,391 How an atom reacts chemically depends on how willing it is 190 00:09:19,424 --> 00:09:21,660 to share electrons with others. 191 00:09:21,693 --> 00:09:24,830 And gold is not very social. 192 00:09:24,863 --> 00:09:26,432 Like Greta Garbo, 193 00:09:26,465 --> 00:09:29,234 (uses German accent): it wants to be alone. 194 00:09:29,267 --> 00:09:32,538 So do other so-called noble metals-- 195 00:09:32,571 --> 00:09:38,110 silver, platinum, palladium, osmium and iridium-- 196 00:09:38,143 --> 00:09:40,546 all located in the same quiet neighborhood 197 00:09:40,579 --> 00:09:42,214 of the periodic table. 198 00:09:42,247 --> 00:09:45,751 Using cyanide to react with the gold 199 00:09:45,784 --> 00:09:47,586 allows them to gradually reduce 200 00:09:47,619 --> 00:09:51,957 40,000 gallon tanks of pulverized sludge... 201 00:09:51,990 --> 00:09:53,392 to this. 202 00:09:53,425 --> 00:09:56,228 Three trays full of... mud? 203 00:09:56,261 --> 00:09:58,430 But there's not gold in here, is there? 204 00:09:58,463 --> 00:10:00,566 There's a little bit of carbon that's mixed in with this 205 00:10:00,599 --> 00:10:02,134 that's changed the color on it. 206 00:10:02,167 --> 00:10:04,003 But I assure you that when we melt it and pour it down, Dave, 207 00:10:04,036 --> 00:10:05,371 we're going to have gold. 208 00:10:05,404 --> 00:10:07,973 All right, and how much gold-- like, how many gold bars-- 209 00:10:08,006 --> 00:10:09,642 will this array make? 210 00:10:09,675 --> 00:10:12,244 This should produce about a bar and a half. 211 00:10:12,277 --> 00:10:14,613 All right, and all derived 212 00:10:14,646 --> 00:10:18,617 from one 40,000-gallon batch of solution? 213 00:10:18,650 --> 00:10:19,718 Right. 214 00:10:19,751 --> 00:10:21,620 So, 40,000 gallons got distilled down to this, 215 00:10:21,653 --> 00:10:23,656 and that will get distilled down to a bar and a half? 216 00:10:23,689 --> 00:10:23,689 Right, exactly. 217 00:10:23,689 --> 00:10:25,257 Wow. 218 00:10:25,290 --> 00:10:30,062 POGUE: The golden mud goes into a 2,000-degree induction furnace 219 00:10:30,095 --> 00:10:33,465 along with a white powder called flux, 220 00:10:33,498 --> 00:10:35,634 chemicals that prevent the molten gold 221 00:10:35,667 --> 00:10:38,838 from reacting with or sticking to anything. 222 00:10:46,578 --> 00:10:49,081 This is the first time an outsider 223 00:10:49,114 --> 00:10:51,217 has been allowed to pour gold. 224 00:10:54,820 --> 00:10:57,589 Just call me King Midas. 225 00:10:57,622 --> 00:11:00,059 I'm not sure they entirely know what they're doing, 226 00:11:00,092 --> 00:11:03,429 but they are going to let me pour the gold 227 00:11:03,462 --> 00:11:05,330 into a gold bar mold. 228 00:11:05,363 --> 00:11:09,068 If it goes over 70 pounds, it's a reject. 229 00:11:09,101 --> 00:11:10,569 They'll have to throw it away 230 00:11:10,602 --> 00:11:12,771 or just let me take it home in my luggage. 231 00:11:12,804 --> 00:11:18,444 So, you know, I'll... I'll do my best not to spill. 232 00:11:18,477 --> 00:11:21,513 There's a lot of money at stake here. 233 00:11:21,546 --> 00:11:23,615 Here it comes. 234 00:11:23,648 --> 00:11:25,617 Hot gold. 235 00:11:25,650 --> 00:11:27,453 Get your hot gold here. 236 00:11:33,125 --> 00:11:34,526 Right there. 237 00:11:34,559 --> 00:11:37,763 It's a gold bar, ladies and gentlemen. 238 00:11:37,796 --> 00:11:38,897 It's been my pleasure. 239 00:11:38,930 --> 00:11:40,066 See you next week! 240 00:11:42,367 --> 00:11:46,271 Perfect job. 241 00:11:46,304 --> 00:11:49,875 Final steps: cool and clean the bars. 242 00:11:52,077 --> 00:11:55,147 Stamp them with their unique serial numbers 243 00:11:55,180 --> 00:11:58,084 and their weights. 244 00:12:00,719 --> 00:12:02,421 So this is it, the proverbial gold bars. 245 00:12:02,454 --> 00:12:03,555 And you know what? 246 00:12:03,588 --> 00:12:04,790 They're still warm. 247 00:12:04,823 --> 00:12:06,225 They're still warm, hot off the press. 248 00:12:06,258 --> 00:12:07,359 Can I pick one of these up? 249 00:12:07,392 --> 00:12:09,294 It's not may I, it's can I. 250 00:12:09,327 --> 00:12:11,196 Oh man! 251 00:12:11,229 --> 00:12:12,598 This thing... 252 00:12:12,631 --> 00:12:14,399 So this is, what, 70 pounds? 253 00:12:14,432 --> 00:12:15,267 It's about 60 pounds. 254 00:12:15,300 --> 00:12:16,268 60 pounds? 255 00:12:16,301 --> 00:12:16,935 Yes. 256 00:12:16,968 --> 00:12:18,070 Oh, it's nothing. 257 00:12:18,103 --> 00:12:19,838 And about how much value here? 258 00:12:19,871 --> 00:12:22,307 There is about a million- and-a-half dollars there, Dave. 259 00:12:22,340 --> 00:12:23,876 Oh, man. 260 00:12:23,909 --> 00:12:26,378 Mike, what's that gorilla doing there? 261 00:12:26,411 --> 00:12:27,479 (laughs) 262 00:12:27,512 --> 00:12:30,415 POGUE: They're deceptively heavy. 263 00:12:30,448 --> 00:12:33,418 Only a few natural elements have greater density than gold: 264 00:12:33,451 --> 00:12:37,823 rhenium, platinum, iridium, and osmium. 265 00:12:37,856 --> 00:12:40,425 Mike tells me that each bar represents 266 00:12:40,458 --> 00:12:42,661 about a million pounds of rock 267 00:12:42,694 --> 00:12:45,864 that had to be moved and processed. 268 00:12:45,897 --> 00:12:49,201 Eight bars, 12 million dollars 269 00:12:49,234 --> 00:12:51,804 sitting on this unassuming little table. 270 00:12:51,837 --> 00:12:55,174 What a transformation. 271 00:12:55,207 --> 00:12:58,043 Of all the elements that touch our lives, 272 00:12:58,076 --> 00:12:59,845 nothing drives humankind 273 00:12:59,878 --> 00:13:03,448 to acts of love or destruction like gold. 274 00:13:03,481 --> 00:13:07,019 It is perhaps the most emotional of the elements. 275 00:13:07,052 --> 00:13:10,455 But two rows above gold is another metal of antiquity 276 00:13:10,488 --> 00:13:15,027 that looms large in our lives: copper. 277 00:13:15,060 --> 00:13:17,429 Symbol: Cu. 278 00:13:17,462 --> 00:13:19,198 Atomic number: 29. 279 00:13:19,231 --> 00:13:23,168 29 protons, 29 electrons. 280 00:13:23,201 --> 00:13:26,605 The ancients first learned how to heat rocks 281 00:13:26,638 --> 00:13:32,244 to extract copper at least 7,000 years ago. 282 00:13:36,615 --> 00:13:39,151 And today, it's one of the most widely bought and sold metals 283 00:13:39,184 --> 00:13:41,387 in the world. 284 00:13:44,222 --> 00:13:46,091 The New York Mercantile Exchange 285 00:13:46,124 --> 00:13:48,894 is a vital hub in the global metals market. 286 00:13:52,330 --> 00:13:55,201 Which is pretty good news for me. 287 00:13:58,737 --> 00:13:59,972 At least, I thought so... 288 00:14:00,005 --> 00:14:03,275 Sorry sir, you can't come in with this. 289 00:14:03,308 --> 00:14:05,010 I thought this is a copper exchange. 290 00:14:05,043 --> 00:14:06,445 I'm here to exchange some copper. 291 00:14:06,478 --> 00:14:07,980 I'm sorry, that's not allowed on the floor, 292 00:14:08,013 --> 00:14:08,947 you can't come in with this. 293 00:14:08,980 --> 00:14:10,316 Seriously? 294 00:14:13,952 --> 00:14:17,289 The only business that they're willing to do here 295 00:14:17,322 --> 00:14:19,992 is to buy or sell copper futures. 296 00:14:20,025 --> 00:14:22,261 Like who would fall for that? 297 00:14:22,294 --> 00:14:23,962 ANTHONY GRISANTI: Oh, this is an old, old business. 298 00:14:23,995 --> 00:14:27,165 This goes back to the 1800s, the late 1800s, 299 00:14:27,198 --> 00:14:28,934 where farmers were looking, actually, 300 00:14:28,967 --> 00:14:31,336 for money to plant their next year's crops. 301 00:14:31,369 --> 00:14:33,872 So what the farmers would do is they would say, for example, 302 00:14:33,905 --> 00:14:36,441 "David, you loan me some money," okay, 303 00:14:36,474 --> 00:14:38,710 "and then in the future, I will sell you that crop 304 00:14:38,743 --> 00:14:40,913 that I planted for this amount of dollars." 305 00:14:40,946 --> 00:14:42,648 Eighteen and a half... 306 00:14:42,681 --> 00:14:44,049 So what I'm doing is, 307 00:14:44,082 --> 00:14:47,619 I'm selling you the right to buy or sell my future crops. 308 00:14:47,652 --> 00:14:50,689 POGUE: So this crazy hi-tech thing 309 00:14:50,722 --> 00:14:52,324 began as a glorified farmers market. 310 00:14:54,259 --> 00:14:56,895 In fact, this exchange in New York 311 00:14:56,928 --> 00:15:00,832 started as a butter and cheese exchange on Harrison Street. 312 00:15:00,865 --> 00:15:03,869 Is it safe to say there's no cheese pit here somewhere? 313 00:15:03,902 --> 00:15:06,071 Uh, gruyere, gruyere, cheddar, cheddar! 314 00:15:06,104 --> 00:15:07,873 David, you have to go to Chicago for that. 315 00:15:07,906 --> 00:15:09,207 They still do that? 316 00:15:09,240 --> 00:15:11,176 Yeah, they still trade agricultural products. 317 00:15:11,209 --> 00:15:14,413 (shouting) 318 00:15:14,446 --> 00:15:16,882 I would think that there would be trading markets like this 319 00:15:16,915 --> 00:15:18,984 for gold, and silver, and platinum, 320 00:15:19,017 --> 00:15:20,585 and things that are valuable. 321 00:15:20,618 --> 00:15:21,954 But copper? 322 00:15:21,987 --> 00:15:23,655 Come on, it's like pennies, it's like... 323 00:15:23,688 --> 00:15:25,590 Copper is king, okay? 324 00:15:25,623 --> 00:15:26,992 Copper is used for everything. 325 00:15:27,025 --> 00:15:28,827 It's a really vital metal. 326 00:15:28,860 --> 00:15:32,297 We use it for infrastructure, we use it for electronic goods. 327 00:15:32,330 --> 00:15:33,899 I can hardly think of anything 328 00:15:33,932 --> 00:15:37,769 that doesn't have either a tiny bit of copper or lots of copper. 329 00:15:37,802 --> 00:15:38,704 I love copper. 330 00:15:38,737 --> 00:15:38,737 I do, I do. 331 00:15:38,737 --> 00:15:40,205 I'm getting that. 332 00:15:40,238 --> 00:15:44,643 POGUE: Harriet tells me that the copper market is huge. 333 00:15:44,676 --> 00:15:47,546 Traders in New York, London, and Shanghai 334 00:15:47,579 --> 00:15:51,516 buy and sell more than 20 million tons a year. 335 00:15:51,549 --> 00:15:56,555 Copper is in wire, electronics and computer chips, 336 00:15:56,588 --> 00:15:59,825 plumbing and other building materials. 337 00:15:59,858 --> 00:16:03,061 It's so important that the rise and fall of copper prices 338 00:16:03,094 --> 00:16:07,099 provide a snapshot of the health of the entire world economy. 339 00:16:07,132 --> 00:16:10,569 When times are bad, copper prices tumble. 340 00:16:10,602 --> 00:16:13,438 And when times are good, they soar. 341 00:16:13,471 --> 00:16:15,874 Some say it should be called Dr. Copper, 342 00:16:15,907 --> 00:16:19,945 because it's the only metal with a Ph.D. in economics. 343 00:16:19,978 --> 00:16:22,614 Copper has been prized for millennia 344 00:16:22,647 --> 00:16:24,783 for its unique properties. 345 00:16:24,816 --> 00:16:28,387 It conducts electricity better than any metal except silver. 346 00:16:28,420 --> 00:16:32,124 It's malleable and has a moderate melting temperature. 347 00:16:32,157 --> 00:16:35,527 It even scares away bacteria. 348 00:16:35,560 --> 00:16:38,997 (shouting) 349 00:16:39,030 --> 00:16:42,901 These guys can trade their copper futures. 350 00:16:42,934 --> 00:16:46,405 I've got to unload my copper today. 351 00:16:46,438 --> 00:16:47,973 Commodities! 352 00:16:48,006 --> 00:16:50,108 Get your commodities! 353 00:16:50,141 --> 00:16:52,477 Got copper at 80 cents a pound. 354 00:16:52,510 --> 00:16:53,979 Anybody? 355 00:16:54,012 --> 00:16:55,514 Anybody? 356 00:17:03,121 --> 00:17:05,590 Copper alone is impressive stuff. 357 00:17:05,623 --> 00:17:07,159 But when ancient metallurgists 358 00:17:07,192 --> 00:17:09,561 combined it with another element, 359 00:17:09,594 --> 00:17:11,830 they invented a much tougher material 360 00:17:11,863 --> 00:17:14,032 that went on to conquer the world. 361 00:17:14,065 --> 00:17:16,435 That secret ingredient? 362 00:17:16,468 --> 00:17:17,903 Tin. 363 00:17:17,936 --> 00:17:19,638 Symbol: Sn. 364 00:17:19,671 --> 00:17:21,807 Atomic Number: 50. 365 00:17:21,840 --> 00:17:24,543 50 protons and 50 electrons. 366 00:17:24,576 --> 00:17:29,448 Tin added in small amounts to copper makes bronze, 367 00:17:29,481 --> 00:17:32,017 the first man-made metal alloy. 368 00:17:32,050 --> 00:17:35,020 Bronze helped to spur global trade. 369 00:17:35,053 --> 00:17:37,622 And once forged into tools and weapons, 370 00:17:37,655 --> 00:17:41,726 it played a defining role in the empires of antiquity. 371 00:17:41,759 --> 00:17:45,931 Bronze named an entire age of human civilization. 372 00:17:45,964 --> 00:17:47,632 (bell ringing) 373 00:17:47,665 --> 00:17:50,135 And even today, it's still hanging around. 374 00:17:55,974 --> 00:17:58,777 This is the Verdin Company, 375 00:17:58,810 --> 00:18:04,249 a 170-year-old family-run business in Cincinnati, Ohio. 376 00:18:04,282 --> 00:18:09,721 I'm here because they're about to cast several bells. 377 00:18:09,754 --> 00:18:13,058 Even with all the other modern materials available, 378 00:18:13,091 --> 00:18:15,560 they still choose bronze. 379 00:18:15,593 --> 00:18:17,896 I want to know why. 380 00:18:17,929 --> 00:18:22,501 Hasn't something better come along after all these years? 381 00:18:22,534 --> 00:18:26,838 Ralph Jung offers to make the case for bronze. 382 00:18:26,871 --> 00:18:29,241 This is our pattern that we're gonna use 383 00:18:29,274 --> 00:18:31,409 to actually make the form in the sand. 384 00:18:31,442 --> 00:18:32,777 So this looks like a finished bell. 385 00:18:32,810 --> 00:18:32,810 This isn't a bell? 386 00:18:32,810 --> 00:18:34,112 Yes, it does. 387 00:18:34,145 --> 00:18:35,647 This is just the pattern, yes. 388 00:18:35,680 --> 00:18:38,450 It's made out of aluminum, so it's real easy to handle. 389 00:18:38,483 --> 00:18:39,618 Well, what's wrong with that? 390 00:18:39,651 --> 00:18:40,652 Aluminum's good. 391 00:18:40,685 --> 00:18:41,887 Aluminum doesn't rust, Aluminum's light... 392 00:18:41,920 --> 00:18:42,988 You're right, it doesn't. 393 00:18:43,021 --> 00:18:44,055 Why don't you make the bells out of this? 394 00:18:44,088 --> 00:18:45,791 Well, the sound. 395 00:18:48,493 --> 00:18:50,095 It doesn't have that lasting ring. 396 00:18:50,128 --> 00:18:51,663 And it just... 397 00:18:51,696 --> 00:18:52,764 You don't like how that sounds? 398 00:18:52,797 --> 00:18:53,899 Not really. 399 00:18:53,932 --> 00:18:55,834 It sounds kinda tinny, also. 400 00:18:55,867 --> 00:18:56,968 Thanks a lot, buddy. 401 00:18:57,001 --> 00:18:58,069 Well, you know... 402 00:18:58,102 --> 00:19:00,005 I practiced. 403 00:19:00,038 --> 00:19:02,307 We'll show you what a real bell sounds like. 404 00:19:02,340 --> 00:19:04,142 POGUE: The quality of the sound 405 00:19:04,175 --> 00:19:07,179 depends on the atomic structure of the material. 406 00:19:07,212 --> 00:19:09,614 In pure metals, the atoms are arranged 407 00:19:09,647 --> 00:19:11,917 in orderly rows and columns. 408 00:19:11,950 --> 00:19:14,653 Each atom gives up some of its electrons 409 00:19:14,686 --> 00:19:16,621 to create a kind of sea 410 00:19:16,654 --> 00:19:19,591 of these randomly-moving charged particles. 411 00:19:19,624 --> 00:19:21,860 It's these free-flowing electrons 412 00:19:21,893 --> 00:19:23,995 that make metals conductive. 413 00:19:24,028 --> 00:19:25,630 When placed in a circuit, 414 00:19:25,663 --> 00:19:27,832 the negatively charged particles line up 415 00:19:27,865 --> 00:19:30,702 and flow as an electric current. 416 00:19:31,336 --> 00:19:33,238 The sea of electrons 417 00:19:33,271 --> 00:19:36,441 also creates flexible metallic bonds among the atoms. 418 00:19:36,474 --> 00:19:39,878 In copper, they can slide past each other easily, 419 00:19:39,911 --> 00:19:43,381 which makes it relatively soft and easy-to-dent. 420 00:19:43,414 --> 00:19:46,084 Not right for a bell. 421 00:19:46,117 --> 00:19:49,421 That's why Verdin uses stiffer stuff. 422 00:19:49,454 --> 00:19:51,089 JUNG: So we'll put this down into here... 423 00:19:51,122 --> 00:19:56,027 POGUE: Ralph places the form into a circular steel sleeve, 424 00:19:56,060 --> 00:20:00,065 then fills the space around it with a mixture of sand and epoxy 425 00:20:00,098 --> 00:20:04,903 to withstand the searing heat of the hot metal. 426 00:20:04,936 --> 00:20:06,738 When this company started, 427 00:20:06,771 --> 00:20:09,207 they used a mixture of horsehair, manure, 428 00:20:09,240 --> 00:20:11,109 and just about anything else 429 00:20:11,142 --> 00:20:14,512 that would hold a shape without burning. 430 00:20:14,545 --> 00:20:18,383 But the goal was the same: to create a hollow shape 431 00:20:18,416 --> 00:20:21,920 that follows the inner and outer perimeter of the bell. 432 00:20:21,953 --> 00:20:26,858 Once he removes the aluminum and joins the two halves, 433 00:20:26,891 --> 00:20:30,562 a bell-shaped space remains on the inside, 434 00:20:30,595 --> 00:20:34,532 ready to accept the molten bronze. 435 00:20:34,565 --> 00:20:35,867 And what we have here, David, 436 00:20:35,900 --> 00:20:39,004 is the bronze ingots that we use to put in the furnace. 437 00:20:39,037 --> 00:20:40,772 As you can see, they're... 438 00:20:40,805 --> 00:20:42,574 they've got a little bit of heft to them. 439 00:20:42,607 --> 00:20:43,775 Yeah, it's like... 440 00:20:43,808 --> 00:20:45,243 They average about 20 pounds. 441 00:20:45,276 --> 00:20:46,711 That's a... that's a mixture, actually, 442 00:20:46,744 --> 00:20:49,347 of 80% copper and 20% tin. 443 00:20:49,380 --> 00:20:52,884 And what we have here is the tin in a raw form. 444 00:20:52,917 --> 00:20:54,519 This is how it comes out of the ground. 445 00:20:54,552 --> 00:20:54,552 This is from Malaysia. 446 00:20:54,552 --> 00:20:56,254 Okay. 447 00:20:56,287 --> 00:20:58,356 And we have a chunk of copper 448 00:20:58,389 --> 00:21:00,058 the way it comes out of the ground. 449 00:21:00,091 --> 00:21:01,726 And that's from South Africa. 450 00:21:01,759 --> 00:21:03,461 So that's the recipe for bronze. 451 00:21:03,494 --> 00:21:04,896 Exactly. 452 00:21:04,929 --> 00:21:06,865 So you've got copper plus tin equals bronze. 453 00:21:06,898 --> 00:21:09,267 Equals bronze, yeah. 454 00:21:09,300 --> 00:21:11,036 Why couldn't you use one of those metals by themselves? 455 00:21:11,069 --> 00:21:12,937 Why don't you make bells out of just copper? 456 00:21:12,970 --> 00:21:14,539 If it was all copper, 457 00:21:14,572 --> 00:21:16,241 it would first of all be too soft, 458 00:21:16,274 --> 00:21:19,644 and we wouldn't get that sound that we want from a bell. 459 00:21:19,677 --> 00:21:23,915 Tin with copper gives us that hardness. 460 00:21:23,948 --> 00:21:27,085 POGUE: Adding tin to copper during melting 461 00:21:27,118 --> 00:21:29,921 changes the properties of the metal. 462 00:21:29,954 --> 00:21:31,423 The larger tin atoms 463 00:21:31,456 --> 00:21:33,591 restrict the movement of the copper atoms, 464 00:21:33,624 --> 00:21:38,530 making the material harder. 465 00:21:38,563 --> 00:21:40,965 A blow causes the atoms to vibrate, 466 00:21:40,998 --> 00:21:44,302 but the tin prevents them from moving too far out of position. 467 00:21:44,335 --> 00:21:46,571 Tin is good for a bell, 468 00:21:46,604 --> 00:21:48,940 but only in the right proportion. 469 00:21:48,973 --> 00:21:53,311 This is what can happen if the amount of tin isn't right. 470 00:21:53,344 --> 00:21:57,182 No one is certain why the Liberty Bell cracked, 471 00:21:57,215 --> 00:22:01,086 but a chemical analysis indicated there was too much tin 472 00:22:01,119 --> 00:22:05,056 and perhaps other impurities in the bronze. 473 00:22:05,089 --> 00:22:06,524 The crack could have been caused 474 00:22:06,557 --> 00:22:09,694 by the way the atoms were arranged within the metal. 475 00:22:09,727 --> 00:22:13,231 Too much tin, and the copper atoms can't move at all. 476 00:22:13,264 --> 00:22:16,835 One good whack, and... 477 00:22:19,237 --> 00:22:21,339 When the bronze has reached the proper temperature-- 478 00:22:21,372 --> 00:22:28,146 2,200 degrees Fahrenheit-- it's time to pour. 479 00:22:28,179 --> 00:22:30,081 Is there any, uh, danger involved in this process? 480 00:22:30,114 --> 00:22:35,020 Well, if you consider getting burned a danger, yes, there is. 481 00:22:38,489 --> 00:22:42,193 POGUE: During the pour, speed is of the essence. 482 00:22:42,226 --> 00:22:44,028 If the metal is allowed to cool, 483 00:22:44,061 --> 00:22:48,900 flaws could develop, ruining the bell. 484 00:22:48,933 --> 00:22:51,169 Even though the foundry has the technology 485 00:22:51,202 --> 00:22:53,872 to precisely control the temperature, 486 00:22:53,905 --> 00:22:59,144 and Ralph and his team have decades of experience, 487 00:22:59,177 --> 00:23:00,678 bronze remains unpredictable. 488 00:23:00,711 --> 00:23:07,886 Out of every hundred bells they pour, 20 or 30 will fail. 489 00:23:10,721 --> 00:23:11,890 That was quite a process. 490 00:23:11,923 --> 00:23:13,458 I appreciate your letting me help out like that. 491 00:23:13,491 --> 00:23:16,795 JUNG: I think we got three successful bells out of this, 492 00:23:16,828 --> 00:23:18,630 but anything can go wrong. 493 00:23:18,663 --> 00:23:22,567 So you just don't know until after you open up the molds 494 00:23:22,600 --> 00:23:25,837 and see what you've got. 495 00:23:27,071 --> 00:23:29,808 (roosters crowing) 496 00:23:29,841 --> 00:23:33,711 The bells have to cool for 24 hours, 497 00:23:33,744 --> 00:23:36,381 so it's the next day before we can find out 498 00:23:36,414 --> 00:23:40,452 if they'll be making music or ending up as scrap. 499 00:23:40,485 --> 00:23:42,620 So what am I gonna see inside? 500 00:23:42,653 --> 00:23:46,391 A gleaming chrome, silver magnificent church bell 501 00:23:46,424 --> 00:23:47,592 ready for hanging? 502 00:23:47,625 --> 00:23:49,394 Actually no, you're gonna see... 503 00:23:49,427 --> 00:23:53,298 I like to refer to them as a newborn baby. 504 00:23:53,331 --> 00:23:56,768 They come out kind of ugly and not so pretty, 505 00:23:56,801 --> 00:23:58,837 but they clean up really well. 506 00:23:58,870 --> 00:24:04,776 (humming "Also Sprach Zarathustra" by Strauss) 507 00:24:04,809 --> 00:24:05,877 Wow, I can feel... 508 00:24:05,910 --> 00:24:07,946 I can feel waves of heat coming off of this. 509 00:24:07,979 --> 00:24:09,380 Yes, it's still quite warm. 510 00:24:09,413 --> 00:24:10,482 Is it... is it touchable? 511 00:24:10,515 --> 00:24:11,549 Yes, it's touchable. 512 00:24:11,582 --> 00:24:13,084 Ow! 513 00:24:13,117 --> 00:24:14,853 Speak for yourself, dude. 514 00:24:14,886 --> 00:24:18,389 POGUE: And what happens to a carefully crafted sand mold? 515 00:24:18,422 --> 00:24:23,394 It's history. 516 00:24:23,427 --> 00:24:26,464 Is this an actual bell that you can actually sell to somebody? 517 00:24:26,497 --> 00:24:28,233 Oh, yes, yes, we're gonna... 518 00:24:28,266 --> 00:24:29,334 This will be on the market very soon. 519 00:24:29,367 --> 00:24:33,404 So I really do need to not chip it. 520 00:24:33,437 --> 00:24:37,108 That would be good. 521 00:24:48,653 --> 00:24:50,922 So what about all this black sooty stuff? 522 00:24:50,955 --> 00:24:54,225 So that's going to have to be cleaned off of there. 523 00:24:54,258 --> 00:24:56,160 You got some kind of big hydraulic... ? 524 00:24:56,193 --> 00:24:59,264 Actually no, I got this. 525 00:25:15,179 --> 00:25:17,248 Well, that was a big waste of time. 526 00:25:17,281 --> 00:25:19,617 You missed a big spot over here. 527 00:25:19,650 --> 00:25:22,754 I guess that's okay for a rookie. 528 00:25:22,787 --> 00:25:24,889 Well, thank you so much, Ralph. 529 00:25:24,922 --> 00:25:27,358 POGUE: And now for the moment of truth. 530 00:25:27,391 --> 00:25:30,962 Will this bell be good enough to sing? 531 00:25:30,995 --> 00:25:32,063 What time is it? 532 00:25:32,096 --> 00:25:33,331 Time to celebrate 533 00:25:33,364 --> 00:25:36,501 the millennia-old tradition of bronze. 534 00:25:36,534 --> 00:25:38,603 (bell rings clearly) 535 00:25:38,636 --> 00:25:41,306 Our bell resonates with a beautiful tone, 536 00:25:41,339 --> 00:25:44,242 and it takes many seconds for the note to die out 537 00:25:44,275 --> 00:25:48,813 thanks to the interplay between copper and tin. 538 00:25:48,846 --> 00:25:50,782 Even the best bell makers 539 00:25:50,815 --> 00:25:54,319 can't know whether their bronze will be too stiff, or too soft, 540 00:25:54,352 --> 00:25:56,921 until they pour a bell and strike it. 541 00:25:56,954 --> 00:25:58,356 I wonder, though, 542 00:25:58,389 --> 00:26:01,526 if there's a more scientific way to evaluate the metal. 543 00:26:03,694 --> 00:26:06,164 To find out, I'm taking a piece of it 544 00:26:06,197 --> 00:26:09,100 to David Muller at Cornell University. 545 00:26:09,133 --> 00:26:10,969 He's offered to show me 546 00:26:11,002 --> 00:26:16,608 how the atoms in our bronze stack up... literally. 547 00:26:16,641 --> 00:26:18,643 I brought you a couple of hunks of bronze, 548 00:26:18,676 --> 00:26:20,445 one of which was knocked off of a bell when it was done 549 00:26:20,478 --> 00:26:22,714 and one of which is unpoured. 550 00:26:22,747 --> 00:26:24,849 And I wouldn't mind taking a look at these 551 00:26:24,882 --> 00:26:26,084 under your magic microscope. 552 00:26:26,117 --> 00:26:27,585 Okay. 553 00:26:27,618 --> 00:26:29,420 Now, this is actually a lot of material. 554 00:26:29,453 --> 00:26:31,389 I need an area about the size of a farm, 555 00:26:31,422 --> 00:26:33,524 and you've given me the whole of the United States. 556 00:26:33,557 --> 00:26:35,293 So we're gonna cut it down a little bit. 557 00:26:39,330 --> 00:26:40,365 MULLER: Now watch out, it's hot. 558 00:26:40,398 --> 00:26:42,367 It's what? Ow! 559 00:26:42,400 --> 00:26:44,669 POGUE: First, a polishing wheel gives the bronze 560 00:26:44,702 --> 00:26:45,870 a mirror-like finish. 561 00:26:45,903 --> 00:26:48,206 Then the sample is inserted 562 00:26:48,239 --> 00:26:50,908 into a powerful electron microscope. 563 00:26:50,941 --> 00:26:54,078 David tells me that when we reach full magnification, 564 00:26:54,111 --> 00:26:58,483 we will have images of the actual atoms in the bronze, 565 00:26:58,516 --> 00:27:00,952 something few people have ever seen. 566 00:27:00,985 --> 00:27:03,755 Frankly, it seems a little farfetched. 567 00:27:03,788 --> 00:27:05,156 So what's in there right now? 568 00:27:05,189 --> 00:27:06,557 What are we looking at? 569 00:27:06,590 --> 00:27:08,826 So we have a piece of the bronze that we cut earlier, 570 00:27:08,859 --> 00:27:10,294 very similar to this one. 571 00:27:10,327 --> 00:27:11,596 Now, I have to say, 572 00:27:11,629 --> 00:27:13,498 this microscope is not especially impressive. 573 00:27:13,531 --> 00:27:16,367 I mean, I'm seeing the entire circle, 574 00:27:16,400 --> 00:27:18,436 like I'm just wearing a pair of reading glasses or something. 575 00:27:18,469 --> 00:27:20,672 MULLER: This is like having a map of the United States, 576 00:27:20,705 --> 00:27:22,707 and eventually we want to zoom in, 577 00:27:22,740 --> 00:27:25,943 and we wanna pick out one car parked somewhere in the U.S. 578 00:27:25,976 --> 00:27:31,883 POGUE: We'll have to zoom in a hundred million times to see an atom. 579 00:27:31,916 --> 00:27:33,685 To understand the scale, 580 00:27:33,718 --> 00:27:35,920 imagine if I were floating in space 581 00:27:35,953 --> 00:27:38,056 2,000 miles above the Earth, 582 00:27:38,089 --> 00:27:40,058 looking down at the United States. 583 00:27:40,091 --> 00:27:42,593 Zooming in a hundred million times 584 00:27:42,626 --> 00:27:45,463 would allow me to pick out not just a car, 585 00:27:45,496 --> 00:27:50,168 but a bug crawling in the grass next to it. 586 00:27:50,201 --> 00:27:51,035 So we can zoom in from here? 587 00:27:51,068 --> 00:27:52,003 Absolutely. 588 00:27:52,036 --> 00:27:53,371 How do you do that? 589 00:27:53,404 --> 00:27:55,106 So there's the zoom button. 590 00:27:55,139 --> 00:27:57,341 POGUE: The big knob labeled "Magnification"? 591 00:27:57,374 --> 00:27:58,943 MULLER: Absolutely. 592 00:27:58,976 --> 00:28:02,580 So crank up the mag and let's see what happens as you zoom in. 593 00:28:02,613 --> 00:28:04,115 POGUE: Wait! 594 00:28:04,148 --> 00:28:05,817 I see a little tiny cartoon sign 595 00:28:05,850 --> 00:28:08,720 that says, "Welcome to Whoville!" 596 00:28:08,753 --> 00:28:14,358 POGUE: To see atoms, we need to find an interesting region to sample. 597 00:28:14,391 --> 00:28:17,161 Now it's starting to look like an alien surface. 598 00:28:17,194 --> 00:28:18,329 MULLER: Right. 599 00:28:18,362 --> 00:28:19,997 Now what we're actually starting to see 600 00:28:20,030 --> 00:28:23,801 is the microstructure of the grains in that bronze. 601 00:28:23,834 --> 00:28:25,570 And the brighter colors 602 00:28:25,603 --> 00:28:27,839 are things that contain more tin. 603 00:28:27,872 --> 00:28:30,108 And the things with less tin 604 00:28:30,141 --> 00:28:31,375 are the things that are slightly darker. 605 00:28:31,408 --> 00:28:33,277 Oh my gosh, that is so cool. 606 00:28:33,310 --> 00:28:36,981 POGUE: The microscopic structure of metals is not uniform. 607 00:28:37,014 --> 00:28:40,518 Small features called grains become visible. 608 00:28:40,551 --> 00:28:43,488 Boundaries between grains are actually defects 609 00:28:43,521 --> 00:28:46,724 in the orderly arrangement of the atoms. 610 00:28:46,757 --> 00:28:49,594 So you can't see atoms with this microscope. 611 00:28:49,627 --> 00:28:51,796 We can get almost all the way there, but not quite. 612 00:28:51,829 --> 00:28:53,097 Okay. 613 00:28:53,130 --> 00:28:56,100 And to look at atoms, we're gonna need a bigger machine. 614 00:28:56,133 --> 00:28:57,168 Do you have one? 615 00:28:57,201 --> 00:28:58,803 We certainly do. 616 00:28:58,836 --> 00:29:00,538 This huge thing? 617 00:29:00,571 --> 00:29:03,741 This giant room-size thing in a shipping container? 618 00:29:03,774 --> 00:29:07,912 And why is it draped in shipping crate material? 619 00:29:07,945 --> 00:29:09,714 Those are acoustic blankets. 620 00:29:09,747 --> 00:29:12,717 They are meant to absorb and reflect sound 621 00:29:12,750 --> 00:29:15,086 because the microscope itself is so sensitive 622 00:29:15,119 --> 00:29:16,454 that if you were to talk, 623 00:29:16,487 --> 00:29:18,890 just the pressure wave from your voice is gonna... 624 00:29:18,923 --> 00:29:21,425 is gonna give enough mechanical vibration 625 00:29:21,458 --> 00:29:23,561 to shake this thing around. 626 00:29:23,594 --> 00:29:26,764 We only have to shake things by an atom for the image to vanish. 627 00:29:26,797 --> 00:29:28,132 So our little piece of bronze 628 00:29:28,165 --> 00:29:31,068 that we've dug out of the first machine 629 00:29:31,101 --> 00:29:33,171 is now the little black disc there? 630 00:29:33,204 --> 00:29:34,906 Well, that's the three- millimeter support disc. 631 00:29:34,939 --> 00:29:37,141 The actual bronze chip itself 632 00:29:37,174 --> 00:29:39,277 is about a hundredth the thickness of a human hair. 633 00:29:39,310 --> 00:29:41,579 It's too small for us to see, 634 00:29:41,612 --> 00:29:43,347 so we have to mount it on a carrier grid 635 00:29:43,380 --> 00:29:44,582 so we can handle it. 636 00:29:44,615 --> 00:29:46,083 Oh, so you've essentially put it on a little plate. 637 00:29:46,116 --> 00:29:47,351 That's right. 638 00:29:47,384 --> 00:29:49,287 Are you telling me that I can see individual atoms 639 00:29:49,320 --> 00:29:51,355 of my piece of bell? 640 00:29:51,388 --> 00:29:53,124 That's correct. 641 00:29:53,157 --> 00:29:56,727 POGUE: Scientists have understood since the early 20th century 642 00:29:56,760 --> 00:29:58,963 that metals are crystals. 643 00:29:58,996 --> 00:30:02,033 That is, they have an orderly arrangement of atoms. 644 00:30:02,066 --> 00:30:05,036 By bombarding samples with x-rays, 645 00:30:05,069 --> 00:30:07,538 they were able to create shadowy images 646 00:30:07,571 --> 00:30:09,640 of that crystal structure. 647 00:30:09,673 --> 00:30:12,877 But the idea that we might one day see actual atoms 648 00:30:12,910 --> 00:30:15,012 was beyond imagination. 649 00:30:15,045 --> 00:30:18,182 If David's microscope is powerful enough, 650 00:30:18,215 --> 00:30:20,585 we should see regular rows of copper atoms 651 00:30:20,618 --> 00:30:23,754 with tin atoms packed in between. 652 00:30:23,787 --> 00:30:25,523 Or so the theory predicts. 653 00:30:25,556 --> 00:30:26,424 The dots are atoms? 654 00:30:26,457 --> 00:30:28,292 That's right. 655 00:30:28,325 --> 00:30:29,927 Each individual dot is an atom. 656 00:30:29,960 --> 00:30:33,264 We are seeing actual atoms of my little bell piece? 657 00:30:33,297 --> 00:30:36,167 MULLER: The bright ones, those are the tin atoms, 658 00:30:36,200 --> 00:30:39,704 and the slightly darker ones, those are the copper atoms. 659 00:30:39,737 --> 00:30:41,606 And isn't it kind of like a mind-blower 660 00:30:41,639 --> 00:30:45,476 that we're actually looking at actual atoms? 661 00:30:45,509 --> 00:30:48,679 I mean, isn't this a historic technological achievement? 662 00:30:48,712 --> 00:30:51,048 Every time people see that for the first time, 663 00:30:51,081 --> 00:30:52,183 they get really excited. 664 00:30:52,216 --> 00:30:57,588 POGUE: To actually see atoms-- amazing! 665 00:30:57,621 --> 00:30:59,957 Well, what can we learn about this? 666 00:30:59,990 --> 00:31:01,058 Like, for one thing, 667 00:31:01,091 --> 00:31:02,426 I notice they're really, really grid-like. 668 00:31:02,459 --> 00:31:06,130 They're like a little aerial photo of a planned community. 669 00:31:06,163 --> 00:31:09,100 That's actually the stacking of the atoms in the material. 670 00:31:09,133 --> 00:31:10,701 The pattern that it orders into, 671 00:31:10,734 --> 00:31:12,837 that is the crystal structure directly. 672 00:31:12,870 --> 00:31:15,973 POGUE: David tells me we got very lucky. 673 00:31:16,006 --> 00:31:19,110 The atoms in our bronze are unusually well-ordered. 674 00:31:19,143 --> 00:31:24,282 Our bell makers must be true masters of their craft. 675 00:31:24,315 --> 00:31:25,316 Well, thanks for my tour 676 00:31:25,349 --> 00:31:27,018 into the... to the unseen 677 00:31:27,051 --> 00:31:29,020 and to what used to be the purely theoretical. 678 00:31:29,053 --> 00:31:32,323 I can't believe I can now put on my resume that I've seen atoms. 679 00:31:32,356 --> 00:31:33,658 Thanks for the tour. 680 00:31:33,691 --> 00:31:35,026 It was a pleasure. 681 00:31:35,059 --> 00:31:38,229 POGUE: This amazing ability to see atoms 682 00:31:38,262 --> 00:31:40,398 has opened up new worlds for scientists. 683 00:31:40,431 --> 00:31:43,601 Muller's lab has successfully captured 684 00:31:43,634 --> 00:31:49,974 many other images of atoms in gold and computer chips, 685 00:31:50,007 --> 00:31:56,480 oxygen, powerful magnets, and even glass. 686 00:31:56,513 --> 00:31:59,750 But even so, they've barely scratched the surface 687 00:31:59,783 --> 00:32:01,185 because they can discern 688 00:32:01,218 --> 00:32:04,755 only the outermost boundaries around atoms. 689 00:32:04,788 --> 00:32:08,125 The interior is 10,000 times smaller. 690 00:32:08,158 --> 00:32:12,029 If the outer boundary of a hydrogen atom, 691 00:32:12,062 --> 00:32:13,698 where the electron is found, 692 00:32:13,731 --> 00:32:18,169 were enlarged to be two miles wide, about the size of a city, 693 00:32:18,202 --> 00:32:20,404 the single proton in its nucleus 694 00:32:20,437 --> 00:32:22,640 would be the size of a golf ball. 695 00:32:22,673 --> 00:32:26,177 It's here we find elements at their most elemental, 696 00:32:26,210 --> 00:32:28,679 because every nucleus contains protons 697 00:32:28,712 --> 00:32:30,481 and it's the number of protons 698 00:32:30,514 --> 00:32:33,884 that determines what kind of element the atom is. 699 00:32:33,917 --> 00:32:36,087 One proton is hydrogen. 700 00:32:37,855 --> 00:32:40,191 Two protons, helium. 701 00:32:41,125 --> 00:32:42,927 Three protons, lithium. 702 00:32:42,960 --> 00:32:45,730 Four protons, beryllium. 703 00:32:45,763 --> 00:32:50,601 All the way up to element 118, with 118 protons. 704 00:32:50,634 --> 00:32:53,771 The number of protons is called the atomic number, 705 00:32:53,804 --> 00:32:56,674 and it's the fundamental organizing principle 706 00:32:56,707 --> 00:32:58,743 of every table of the elements. 707 00:32:58,776 --> 00:33:01,078 Including this one. 708 00:33:01,111 --> 00:33:03,347 Wow, this is cool. 709 00:33:03,380 --> 00:33:06,017 You have a periodic table table! 710 00:33:06,050 --> 00:33:08,119 THEO GRAY: Well, it's called the periodic table, 711 00:33:08,152 --> 00:33:09,720 why do people keep putting them on the wall? 712 00:33:09,753 --> 00:33:13,124 POGUE: Every high school student has seen the elements chart 713 00:33:13,157 --> 00:33:16,727 but author Theo Gray's version is unique-- 714 00:33:16,760 --> 00:33:19,930 handmade, with each element's identity card 715 00:33:19,963 --> 00:33:23,768 meticulously carved into the wood. 716 00:33:23,801 --> 00:33:26,203 But I have to say I've never completely gotten it, right? 717 00:33:26,236 --> 00:33:28,139 They're filled with stats and figures 718 00:33:28,172 --> 00:33:30,207 that don't make any sense to the ordinary person. 719 00:33:30,240 --> 00:33:31,375 Theo gives me a refresher. 720 00:33:31,408 --> 00:33:34,011 You've got the name of the element. 721 00:33:34,044 --> 00:33:35,713 You've got the atomic symbol. 722 00:33:35,746 --> 00:33:36,814 Ca for calcium. 723 00:33:36,847 --> 00:33:38,149 Calcium. 724 00:33:38,182 --> 00:33:39,550 Uh, you've got the atomic number, 725 00:33:39,583 --> 00:33:41,085 which is the number of protons 726 00:33:41,118 --> 00:33:43,154 in the nucleus of each atom of that element. 727 00:33:43,187 --> 00:33:45,589 It's probably the most important thing on this tile. 728 00:33:45,622 --> 00:33:46,524 So where's gold? 729 00:33:46,557 --> 00:33:47,625 Gold's right there, number 79. 730 00:33:47,658 --> 00:33:49,527 Okay, so here's a classic example. 731 00:33:49,560 --> 00:33:52,763 They would do much better with marketing this table 732 00:33:52,796 --> 00:33:54,532 if the name and the symbol matched. 733 00:33:54,565 --> 00:33:57,535 Gold doesn't even have "Au" in it. 734 00:33:57,568 --> 00:34:00,037 The symbol is based on the Latin name, aurum. 735 00:34:00,070 --> 00:34:02,573 And if you think about it, the name of each element 736 00:34:02,606 --> 00:34:04,275 is the least important piece of information 737 00:34:04,308 --> 00:34:05,576 you could possibly have. 738 00:34:05,609 --> 00:34:06,911 What matters about elements 739 00:34:06,944 --> 00:34:08,679 is that they are real physical substances 740 00:34:08,712 --> 00:34:10,581 with properties and things you can do with them. 741 00:34:10,614 --> 00:34:15,453 POGUE: Theo makes the point by putting me in touch with the real deal. 742 00:34:15,486 --> 00:34:17,254 Oh... 743 00:34:17,287 --> 00:34:20,057 I see what you've done. 744 00:34:20,090 --> 00:34:22,026 To make the entire table less abstract, 745 00:34:22,059 --> 00:34:23,227 he invites me to lay out 746 00:34:23,260 --> 00:34:27,098 the rest of his collection of pure elements. 747 00:34:33,604 --> 00:34:36,574 Well, this is really pretty amazing. 748 00:34:36,607 --> 00:34:39,944 This is a visual representation of every single element 749 00:34:39,977 --> 00:34:41,745 that makes up this entire planet and everything on it. 750 00:34:41,778 --> 00:34:45,516 POGUE: Then Theo reminds me of something I'd forgotten. 751 00:34:45,549 --> 00:34:47,384 As we can clearly see, 752 00:34:47,417 --> 00:34:51,622 more than 70% of the elements on the table are metals-- 753 00:34:51,655 --> 00:34:54,125 shiny, malleable materials that conduct electricity. 754 00:34:54,158 --> 00:34:55,893 GRAY: There's sort of a diagonal line here. 755 00:34:55,926 --> 00:34:57,728 Everything from here on over, 756 00:34:57,761 --> 00:35:00,664 including the bottom part, is all metals. 757 00:35:00,697 --> 00:35:03,200 Everything from here on over is non-metals. 758 00:35:03,233 --> 00:35:04,668 And down the middle 759 00:35:04,701 --> 00:35:06,737 are these kind of halfway in between things 760 00:35:06,770 --> 00:35:08,873 which include, for example, semiconductors. 761 00:35:08,906 --> 00:35:08,906 Like silicon. 762 00:35:08,906 --> 00:35:10,040 Silicon, right. 763 00:35:10,073 --> 00:35:12,877 I have to say, many of these elements 764 00:35:12,910 --> 00:35:14,478 look the way you would think-- 765 00:35:14,511 --> 00:35:16,280 gold looks like gold, silver looks like silver-- 766 00:35:16,313 --> 00:35:17,548 but not all of them. 767 00:35:17,581 --> 00:35:20,484 The one I was looking at in particular was calcium. 768 00:35:20,517 --> 00:35:21,585 Most people probably think of calcium 769 00:35:21,618 --> 00:35:22,786 as white and chalky, you know. 770 00:35:22,819 --> 00:35:25,055 It's bone, it's chalk, 771 00:35:25,088 --> 00:35:26,790 it's, uh, it's milk. 772 00:35:26,823 --> 00:35:29,793 But this is a silver, shiny metal. 773 00:35:29,826 --> 00:35:31,929 POGUE: This is when Theo's collection 774 00:35:31,962 --> 00:35:33,831 starts to get really interesting: 775 00:35:33,864 --> 00:35:37,902 when he pairs the pure elements with their more familiar forms. 776 00:35:37,935 --> 00:35:40,271 Like pure calcium metal 777 00:35:40,304 --> 00:35:43,607 combine with other elements to make bone. 778 00:35:43,640 --> 00:35:46,477 Bismuth, in stomach medicine. 779 00:35:46,510 --> 00:35:50,814 Bromine, in soda. 780 00:35:50,847 --> 00:35:52,716 And even this element, 781 00:35:52,749 --> 00:35:55,853 hiding out in collectible Fiesta ware. 782 00:35:55,886 --> 00:36:00,291 This bowl from the 1930s gets its orange color from uranium, 783 00:36:00,324 --> 00:36:03,827 and it's actually dangerously radioactive. 784 00:36:03,860 --> 00:36:06,664 Theo's table and his remarkable collection 785 00:36:06,697 --> 00:36:08,566 make a powerful point. 786 00:36:08,599 --> 00:36:10,668 From about 90 elements found on earth, 787 00:36:10,701 --> 00:36:14,238 nature and man have derived millions of different substances 788 00:36:14,271 --> 00:36:16,240 that make our world. 789 00:36:16,273 --> 00:36:19,476 But to me, there's something even more amazing: 790 00:36:19,509 --> 00:36:22,680 the table organizes the elements by atomic number-- 791 00:36:22,713 --> 00:36:26,250 that is, the number of protons in each atom. 792 00:36:26,283 --> 00:36:28,319 Yet the table's creator-- 793 00:36:28,352 --> 00:36:30,888 a 19th-century Russian chemistry professor 794 00:36:30,921 --> 00:36:33,190 named Dmitri Mendeleev-- 795 00:36:33,223 --> 00:36:36,827 knew nothing about protons or atomic numbers. 796 00:36:36,860 --> 00:36:40,998 Even the atom itself hadn't been discovered. 797 00:36:41,031 --> 00:36:45,169 To understand how he cracked the code of the table, 798 00:36:45,202 --> 00:36:49,473 I've come to St. Petersburg, Russia, to the State University 799 00:36:49,506 --> 00:36:52,476 and to Mendeleev's apartment and office. 800 00:36:52,509 --> 00:36:55,946 In the late 1860s, at this very desk, 801 00:36:55,979 --> 00:36:57,715 Mendeleev set out to discover 802 00:36:57,748 --> 00:37:01,518 the underlying order to the elements. 803 00:37:01,551 --> 00:37:03,420 In one often-repeated story, 804 00:37:03,453 --> 00:37:07,558 Mendeleev is said to have created 63 cards, 805 00:37:07,591 --> 00:37:10,894 one for each of the elements known at the time. 806 00:37:10,927 --> 00:37:13,097 He distinguished them not by atomic number, 807 00:37:13,130 --> 00:37:15,899 but by atomic weight. 808 00:37:15,932 --> 00:37:17,768 So he didn't know about atoms, 809 00:37:17,801 --> 00:37:19,837 but isn't this the atomic weight? 810 00:37:19,870 --> 00:37:22,606 How does he know the weight if he doesn't know about atoms? 811 00:37:22,639 --> 00:37:26,243 (speaking Russian) 812 00:37:26,276 --> 00:37:31,715 (translated): It's not in grams or pounds or kilograms. 813 00:37:31,748 --> 00:37:34,551 In the 19th century, they did it like this. 814 00:37:34,584 --> 00:37:37,254 They compared the weights of different elements 815 00:37:37,287 --> 00:37:39,089 to the lightest, hydrogen. 816 00:37:39,122 --> 00:37:40,324 So when they say oxygen is 16, 817 00:37:40,357 --> 00:37:45,296 that means 16 times the weight of hydrogen. 818 00:37:45,329 --> 00:37:49,300 POGUE: 19th-century scientists relied on relative weight 819 00:37:49,333 --> 00:37:51,502 to order the elements. 820 00:37:51,535 --> 00:37:53,971 Imagine if you have two containers, 821 00:37:54,004 --> 00:37:57,074 one full of red marbles, one full of blue marbles. 822 00:37:57,107 --> 00:37:59,843 If both contain the same number of marbles, 823 00:37:59,876 --> 00:38:02,813 but the blue container weighs twice as much, 824 00:38:02,846 --> 00:38:05,983 you can infer that the blue marbles weigh twice as much 825 00:38:06,016 --> 00:38:07,651 as the red marbles, 826 00:38:07,684 --> 00:38:10,187 even if you can't see the marbles at all. 827 00:38:10,220 --> 00:38:13,290 Early chemists devised clever ways 828 00:38:13,323 --> 00:38:16,794 of calculating the weights of elements-- even gases-- 829 00:38:16,827 --> 00:38:21,598 relative to the lightest one: hydrogen. 830 00:38:21,631 --> 00:38:23,100 So the chemists knew that different elements 831 00:38:23,133 --> 00:38:24,568 have different weights. 832 00:38:24,601 --> 00:38:27,438 But why not just one big line forever? 833 00:38:27,471 --> 00:38:31,375 (translated): Mendeleev decided that he would arrange them by weight, 834 00:38:31,408 --> 00:38:35,079 but also by family. 835 00:38:35,112 --> 00:38:37,481 POGUE: This is one of Mendeleev's charts. 836 00:38:37,514 --> 00:38:41,285 You can see hydrogen sticking out just as it does today. 837 00:38:41,318 --> 00:38:44,388 The families he knew are now arranged in columns. 838 00:38:44,421 --> 00:38:48,992 This one has the metals-- lithium, sodium, and potassium-- 839 00:38:49,025 --> 00:38:51,261 that explode in water. 840 00:38:51,294 --> 00:38:53,864 Next door, calcium and magnesium, 841 00:38:53,897 --> 00:38:56,233 which also react with water. 842 00:38:56,266 --> 00:38:59,370 This big block in the middle are metals that are safe to handle, 843 00:38:59,403 --> 00:39:03,107 like nickel, iron, zinc, and gold. 844 00:39:03,140 --> 00:39:07,344 As we go to the right, the elements become less metallic. 845 00:39:07,377 --> 00:39:10,914 These columns are headed by boron, carbon, and nitrogen. 846 00:39:10,947 --> 00:39:12,750 In this neighborhood, 847 00:39:12,783 --> 00:39:15,753 some elements conduct electricity, some don't, 848 00:39:15,786 --> 00:39:18,155 and some can't make up their minds. 849 00:39:18,188 --> 00:39:20,624 But next door is a more volatile crowd, 850 00:39:20,657 --> 00:39:23,594 headed by oxygen and fluorine. 851 00:39:23,627 --> 00:39:27,698 The table gets its shape from the properties of the elements, 852 00:39:27,731 --> 00:39:31,769 like relative weight, conductivity, and reactivity. 853 00:39:31,802 --> 00:39:35,773 It's true today as it was in Mendeleev's time. 854 00:39:35,806 --> 00:39:37,941 Though his chart displayed 855 00:39:37,974 --> 00:39:40,511 only the 63 elements known at the time, 856 00:39:40,544 --> 00:39:43,714 his understanding of the family properties was so strong 857 00:39:43,747 --> 00:39:46,683 he was able to leave gaps in his chart, 858 00:39:46,716 --> 00:39:51,321 bold predictions of elements yet to be discovered. 859 00:39:51,354 --> 00:39:53,857 And when they were eventually found, they proved 860 00:39:53,890 --> 00:39:56,760 completely consistent with his descriptions. 861 00:39:56,793 --> 00:39:59,763 Mendeleev lived until 1907, 862 00:39:59,796 --> 00:40:02,666 long enough to see three gaps filled 863 00:40:02,699 --> 00:40:07,070 by the discoveries of scandium, gallium, and germanium. 864 00:40:07,103 --> 00:40:11,241 Since his death, dozens of new elements have been discovered. 865 00:40:11,274 --> 00:40:12,709 And, incredibly, 866 00:40:12,742 --> 00:40:15,746 his chart perfectly accommodates all of them, 867 00:40:15,779 --> 00:40:18,348 including an entire group that fits neatly 868 00:40:18,381 --> 00:40:20,217 onto the end of the table: 869 00:40:20,250 --> 00:40:22,286 the noble gases. 870 00:40:22,319 --> 00:40:24,721 Where does that term "noble gases" come from? 871 00:40:24,754 --> 00:40:26,657 Are they nobility? 872 00:40:26,690 --> 00:40:28,158 Do they rush to rescue maidens? 873 00:40:28,191 --> 00:40:29,893 No, you're thinking of heroes. 874 00:40:29,926 --> 00:40:31,595 They are like nobility in the sense that 875 00:40:31,628 --> 00:40:33,030 they don't mix with the riff-raff. 876 00:40:33,063 --> 00:40:35,299 They don't like to react with any other elements. 877 00:40:35,332 --> 00:40:38,135 By and large, it's not possible to form compounds with them. 878 00:40:38,168 --> 00:40:40,938 Well, it's a shame for your collection that they're gases, 879 00:40:40,971 --> 00:40:43,707 because you've got big blanks here. 880 00:40:43,740 --> 00:40:47,144 Oh, ho-ho-ho! 881 00:40:47,177 --> 00:40:49,680 POGUE: The noble gases, like neon and argon, 882 00:40:49,713 --> 00:40:52,416 pose a problem for chemists who prefer their elements 883 00:40:52,449 --> 00:40:55,552 to join forces and react with each other. 884 00:40:55,585 --> 00:40:58,155 You can run an electric current through them, 885 00:40:58,188 --> 00:41:01,158 excite their electrons, and get pretty colors-- 886 00:41:01,191 --> 00:41:03,327 which is how neon lights work-- 887 00:41:03,360 --> 00:41:05,162 but the noble gases don't react. 888 00:41:05,195 --> 00:41:09,399 They pretty much refuse to combine with other elements. 889 00:41:09,432 --> 00:41:11,335 GRAY: Being an inert gas, being unwilling to mix 890 00:41:11,368 --> 00:41:13,303 with the other elements, react with them-- 891 00:41:13,336 --> 00:41:15,038 this is a very clear-cut distinction 892 00:41:15,071 --> 00:41:16,807 that sets apart this particular column 893 00:41:16,840 --> 00:41:18,742 from all the others in the periodic table. 894 00:41:18,775 --> 00:41:21,378 POGUE: So why are these guys so aloof? 895 00:41:21,411 --> 00:41:22,913 As it turns out, 896 00:41:22,946 --> 00:41:26,183 protons may determine the identity of an element, 897 00:41:26,216 --> 00:41:29,119 but electrons rule its reactivity. 898 00:41:29,152 --> 00:41:32,289 And reactivity is a shell game. 899 00:41:32,322 --> 00:41:34,592 Here's how the game is played. 900 00:41:35,592 --> 00:41:38,161 Imagine that these balls are electrons 901 00:41:38,194 --> 00:41:40,163 and the target is an atom. 902 00:41:40,196 --> 00:41:44,735 Electrons don't just pile on around the nucleus. 903 00:41:44,768 --> 00:41:46,069 As with skee ball, 904 00:41:46,102 --> 00:41:48,872 where you land relative to the center counts. 905 00:41:48,905 --> 00:41:50,707 Oh come on! 906 00:41:50,740 --> 00:41:52,576 The electrons take up positions 907 00:41:52,609 --> 00:41:56,313 in what can be thought of as concentric shells. 908 00:41:56,346 --> 00:42:00,150 The first shell maxes out at just two electrons. 909 00:42:00,183 --> 00:42:02,085 The next holds eight, 910 00:42:02,118 --> 00:42:04,688 then it goes up to eighteen. 911 00:42:04,721 --> 00:42:07,190 An atom with eight electrons in its outer shell 912 00:42:07,223 --> 00:42:10,694 makes one happy, satisfied atom. 913 00:42:10,727 --> 00:42:12,829 And noble gases come pre-equipped 914 00:42:12,862 --> 00:42:16,733 with completely satisfied shells. 915 00:42:16,766 --> 00:42:18,135 And is this the only column like that? 916 00:42:18,168 --> 00:42:19,169 It's the only column 917 00:42:19,202 --> 00:42:21,171 where all the shells are completely filled. 918 00:42:21,204 --> 00:42:25,175 POGUE: But what about the column just before those stable noble gases? 919 00:42:25,208 --> 00:42:27,477 They're called the halogens. 920 00:42:27,510 --> 00:42:29,012 They have an outer shell 921 00:42:29,045 --> 00:42:31,848 that needs just one more electron to be full. 922 00:42:31,881 --> 00:42:35,018 And they'll grab it any way they can. 923 00:42:35,051 --> 00:42:37,354 The group includes fluorine and bromine, 924 00:42:37,387 --> 00:42:41,692 but the most notorious is chlorine-- 925 00:42:41,725 --> 00:42:46,997 17 protons surrounded by 17 electrons, 926 00:42:47,030 --> 00:42:50,767 arranged in three shells of two, eight, and seven, 927 00:42:50,800 --> 00:42:53,036 one short of being full. 928 00:42:53,069 --> 00:42:54,771 It's that extra electron 929 00:42:54,804 --> 00:42:56,940 chlorine will get any way it can, 930 00:42:56,973 --> 00:42:59,777 sometimes with violent results. 931 00:43:01,011 --> 00:43:03,146 That's why chlorine gas was used 932 00:43:03,179 --> 00:43:07,117 as a deadly poison in World War One. 933 00:43:07,150 --> 00:43:09,286 Chlorine, I mean, this is nasty stuff. 934 00:43:09,319 --> 00:43:12,022 This will take electrons from kittens. 935 00:43:12,055 --> 00:43:14,458 It'll go and steal an electron off the water in your lungs 936 00:43:14,491 --> 00:43:17,461 and turn into hydrochloric acid 937 00:43:17,494 --> 00:43:19,363 because it really wants an electron. 938 00:43:19,396 --> 00:43:21,398 Yeah, maybe I'll leave that where it was. 939 00:43:21,431 --> 00:43:23,100 Now, if you go the other direction, 940 00:43:23,133 --> 00:43:24,868 you end up with the alkali metals. 941 00:43:24,901 --> 00:43:27,771 POGUE: The alkali metals are the first column. 942 00:43:27,804 --> 00:43:30,340 Each of them has full shells 943 00:43:30,373 --> 00:43:34,444 plus one extra electron sitting in a new, outer shell. 944 00:43:34,477 --> 00:43:38,715 They have familiar names like lithium, sodium, and potassium. 945 00:43:38,748 --> 00:43:42,486 And they all want to get rid of that single, lonely electron 946 00:43:42,519 --> 00:43:44,521 any way they can. 947 00:43:44,554 --> 00:43:47,090 So those on that end of the table all have one extra. 948 00:43:47,123 --> 00:43:49,660 This column all has one too few. 949 00:43:49,693 --> 00:43:51,294 I shudder to ask what happens 950 00:43:51,327 --> 00:43:52,796 if you put those two alone in a room. 951 00:43:52,829 --> 00:43:55,132 I happen to have a place where we might be able to do that. 952 00:43:55,165 --> 00:43:57,234 Am I invited? 953 00:43:57,267 --> 00:43:59,403 Please, come to my lair. 954 00:43:59,436 --> 00:44:02,205 POGUE: Turns out there's more to my friend Theo 955 00:44:02,238 --> 00:44:04,341 than mere love of table. 956 00:44:04,374 --> 00:44:08,211 He's also got a deep love of chemical reactions, 957 00:44:08,244 --> 00:44:12,649 and a very remote location where he's free to indulge it. 958 00:44:12,682 --> 00:44:14,951 Okay, they told me you were outstanding in your field, 959 00:44:14,984 --> 00:44:16,186 but this is ridiculous. 960 00:44:16,219 --> 00:44:17,921 Yeah, well, you know the secret 961 00:44:17,954 --> 00:44:22,192 to a good mad scientist's lair: no neighbors. 962 00:44:22,225 --> 00:44:24,695 POGUE: Theo has an infectious attitude 963 00:44:24,728 --> 00:44:26,963 toward the most reactive elements... 964 00:44:26,996 --> 00:44:28,331 Nice! 965 00:44:28,364 --> 00:44:30,734 ...which reminds me of a snake handler's affection 966 00:44:30,767 --> 00:44:33,036 for his most venomous pets. 967 00:44:33,069 --> 00:44:34,071 Oh! 968 00:44:34,104 --> 00:44:36,807 Oh, the humanity! 969 00:44:41,211 --> 00:44:43,413 POGUE: And one of his favorite temperamental friends? 970 00:44:43,446 --> 00:44:44,748 Sodium. 971 00:44:44,781 --> 00:44:46,917 Symbol: Na. 972 00:44:46,950 --> 00:44:49,219 11 protons and 11 electrons 973 00:44:49,252 --> 00:44:54,124 arranged in shells as two, eight, and one. 974 00:44:54,157 --> 00:44:56,193 Sodium is an alkali metal. 975 00:44:56,226 --> 00:44:58,795 Like all the elements in this group, 976 00:44:58,828 --> 00:45:02,933 it's desperate to get rid of that extra electron. 977 00:45:02,966 --> 00:45:04,000 If you cut it quickly... 978 00:45:04,033 --> 00:45:05,202 I should see some silvery... 979 00:45:05,235 --> 00:45:07,104 ... you should see a silvery surface inside. 980 00:45:07,137 --> 00:45:08,438 Indeed. 981 00:45:08,471 --> 00:45:09,840 Wow. 982 00:45:09,873 --> 00:45:12,275 POGUE: It slices like cheese, but it's actually a soft metal. 983 00:45:12,308 --> 00:45:14,411 Theo's offered to put on 984 00:45:14,444 --> 00:45:17,180 one of his favorite sodium demonstrations. 985 00:45:17,213 --> 00:45:21,685 What happens when the pure element dumps its outer electron 986 00:45:21,718 --> 00:45:24,888 in a violent altercation with ordinary water? 987 00:45:24,921 --> 00:45:26,790 He insists we wait until nightfall, 988 00:45:26,823 --> 00:45:29,559 when the reaction will be most spectacular. 989 00:45:29,592 --> 00:45:33,063 Kids, do not try this at home! 990 00:45:33,096 --> 00:45:34,898 The whole purpose of this contraption 991 00:45:34,931 --> 00:45:37,067 is just to dump it into the bucket of water? 992 00:45:37,100 --> 00:45:38,568 Yeah, this is a sodium-dumping machine. 993 00:45:38,601 --> 00:45:39,870 (laughs) 994 00:45:39,903 --> 00:45:41,972 All right, let's give this a try. 995 00:45:42,005 --> 00:45:43,507 Here we go! 996 00:45:46,743 --> 00:45:47,410 Nice... 997 00:45:47,443 --> 00:45:47,443 (explosion) 998 00:45:47,443 --> 00:45:48,979 Oh! 999 00:45:51,881 --> 00:45:53,483 POGUE: What we're seeing is what happens 1000 00:45:53,516 --> 00:45:58,221 when sodium's extra electron tears apart water molecules, 1001 00:45:58,254 --> 00:46:03,226 releasing flammable hydrogen gas-- the H in H2O-- 1002 00:46:03,259 --> 00:46:05,462 which explodes when it mixes with air. 1003 00:46:08,231 --> 00:46:11,168 The next day, Theo takes it up a notch. 1004 00:46:11,201 --> 00:46:14,871 As if sodium plus water weren't violent enough, 1005 00:46:14,904 --> 00:46:17,808 now he wants to combine the same deadly sodium 1006 00:46:17,841 --> 00:46:20,510 with another lethal element: 1007 00:46:20,543 --> 00:46:23,814 chlorine, one of the halogens. 1008 00:46:23,847 --> 00:46:25,615 The result, he claims, 1009 00:46:25,648 --> 00:46:32,222 will be a tasty flavoring for a net full of popcorn. 1010 00:46:32,255 --> 00:46:33,890 Isn't chlorine deadly poison? 1011 00:46:33,923 --> 00:46:35,158 Absolutely. 1012 00:46:35,191 --> 00:46:36,593 I mean, chlorine, chlorine... 1013 00:46:36,626 --> 00:46:38,295 they used it as a poison gas in World War I. 1014 00:46:38,328 --> 00:46:40,397 POGUE: It'll be perfectly safe 1015 00:46:40,430 --> 00:46:42,465 when these two deadly ingredients combine. 1016 00:46:42,498 --> 00:46:43,533 I didn't say that. 1017 00:46:43,566 --> 00:46:45,202 I said that after they're combined, 1018 00:46:45,235 --> 00:46:46,503 the result is perfectly safe. 1019 00:46:46,536 --> 00:46:48,605 The actual process of combining them 1020 00:46:48,638 --> 00:46:50,841 is fraught with difficulties. 1021 00:46:50,874 --> 00:46:53,977 Okay, and that's why we're dressed up like miners here. 1022 00:46:56,980 --> 00:47:00,383 POGUE: First, a hunk of sodium in a dry metal bowl. 1023 00:47:00,416 --> 00:47:03,253 Then, a jet of pure chlorine. 1024 00:47:05,088 --> 00:47:07,224 Surprisingly, no explosion. 1025 00:47:07,257 --> 00:47:11,061 Somehow, when these two bad boys of the periodic table 1026 00:47:11,094 --> 00:47:13,864 come together, they calm down. 1027 00:47:15,632 --> 00:47:19,402 At the atomic level, sodium, an alkali metal, 1028 00:47:19,435 --> 00:47:21,805 had an electron it didn't want, 1029 00:47:21,838 --> 00:47:26,309 and chlorine, a halogen, wants desperately to grab an electron. 1030 00:47:26,342 --> 00:47:28,245 Once the handoff was complete, 1031 00:47:28,278 --> 00:47:31,014 both atoms wound up with full shells, 1032 00:47:31,047 --> 00:47:34,117 making them stable and able to join together 1033 00:47:34,150 --> 00:47:36,920 to form a crystal compound we can't live without: 1034 00:47:36,953 --> 00:47:39,055 sodium chloride. 1035 00:47:39,088 --> 00:47:40,457 Table salt. 1036 00:47:40,490 --> 00:47:43,159 Now I don't exactly see, like, a pile of salt anywhere. 1037 00:47:43,192 --> 00:47:44,961 No, the salt, most of it went up in the smoke. 1038 00:47:44,994 --> 00:47:47,497 That is, it went in the popcorn. 1039 00:47:49,966 --> 00:47:51,001 It tastes like salt. 1040 00:47:51,034 --> 00:47:51,835 The good stuff. 1041 00:47:51,868 --> 00:47:51,868 Fresh. 1042 00:47:51,868 --> 00:47:52,869 Fresh salt. 1043 00:47:52,902 --> 00:47:54,638 Only the freshest salt at Theo's farm. 1044 00:47:54,671 --> 00:48:00,610 POGUE: Theo's backyard reactions have given me a crucial insight. 1045 00:48:00,643 --> 00:48:02,846 How elements come together to form compounds 1046 00:48:02,879 --> 00:48:04,881 is all about electrons. 1047 00:48:04,914 --> 00:48:07,751 Which brings me to one of the most notorious 1048 00:48:07,784 --> 00:48:10,086 electron hounds on the table: 1049 00:48:10,119 --> 00:48:10,820 oxygen. 1050 00:48:10,853 --> 00:48:12,923 Symbol: O. 1051 00:48:12,956 --> 00:48:15,392 Eight protons, eight electrons. 1052 00:48:15,425 --> 00:48:18,695 It wants eight electrons to complete its outer shell, 1053 00:48:18,728 --> 00:48:20,764 but it has only six. 1054 00:48:20,797 --> 00:48:23,800 So it's always on the prowl for two more. 1055 00:48:23,833 --> 00:48:25,669 And it's more determined 1056 00:48:25,702 --> 00:48:28,238 than almost any other element on the table. 1057 00:48:28,271 --> 00:48:32,842 To get a first-hand look at oxygen's lust for electrons, 1058 00:48:32,875 --> 00:48:36,313 I've traveled to the Energetic Materials Research 1059 00:48:36,346 --> 00:48:39,349 and Testing Center at New Mexico Tech, 1060 00:48:39,382 --> 00:48:42,252 where the business of violent reactions is booming. 1061 00:48:48,858 --> 00:48:52,762 What he has here in the rear is four pounds of C4. 1062 00:48:52,795 --> 00:48:55,799 Four pounds? 1063 00:48:55,832 --> 00:48:58,168 POGUE: It's a deadly serious business for researchers who study 1064 00:48:58,201 --> 00:49:02,138 improvised explosive devices-- IEDs. 1065 00:49:02,171 --> 00:49:04,541 By adding the 5/16ths nuts, now we have something 1066 00:49:04,574 --> 00:49:05,742 that's going to get propelled out of here 1067 00:49:05,775 --> 00:49:07,177 at a few thousand feet per second. 1068 00:49:07,210 --> 00:49:10,947 POGUE: They have a wide variety of explosives on hand. 1069 00:49:10,980 --> 00:49:16,519 On a typical day, they might blow up a suicide vest, 1070 00:49:16,552 --> 00:49:20,056 a few pipe bombs, 1071 00:49:20,089 --> 00:49:25,195 and a briefcase bomb. 1072 00:49:25,228 --> 00:49:27,163 Tim Collister's job is 1073 00:49:27,196 --> 00:49:29,399 to train law enforcement and fire professionals 1074 00:49:29,432 --> 00:49:32,502 how to deal with these dangerous weapons. 1075 00:49:32,535 --> 00:49:36,406 But today, I'm his only student. 1076 00:49:36,439 --> 00:49:38,308 We're going to set off one of the most powerful 1077 00:49:38,341 --> 00:49:40,110 off-the-shelf explosives there is: 1078 00:49:40,143 --> 00:49:45,849 in the trunk of this car, 300 pounds of ANFO, 1079 00:49:45,882 --> 00:49:49,185 unassuming white pellets that contain enough oxygen, 1080 00:49:49,218 --> 00:49:51,888 as well as nitrogen and hydrogen, 1081 00:49:51,921 --> 00:49:54,858 to turn this car into a scrap heap. 1082 00:49:54,891 --> 00:49:57,193 Basically, it's a fertilizer bomb. 1083 00:49:57,226 --> 00:50:00,230 This is not something I'm going to soon forget. 1084 00:50:00,263 --> 00:50:01,064 No, you're not. 1085 00:50:01,097 --> 00:50:03,934 COLLISTER: Three, two, one. 1086 00:50:14,243 --> 00:50:17,147 POGUE: Hundreds of pounds of solid explosive, 1087 00:50:17,180 --> 00:50:19,382 transformed in a millionth of a second 1088 00:50:19,415 --> 00:50:22,886 into an infernal ball of superheated gas, 1089 00:50:22,919 --> 00:50:27,257 expanding at more than ten times the speed of sound. 1090 00:50:27,290 --> 00:50:31,227 A devastating chemical reaction, yet many times smaller 1091 00:50:31,260 --> 00:50:34,764 than the most notorious ANFO bomb ever detonated. 1092 00:50:34,797 --> 00:50:41,204 In 1995, over 4,000 pounds of ANFO loaded into a rented truck 1093 00:50:41,237 --> 00:50:43,740 destroyed the Federal Building in Oklahoma City, 1094 00:50:43,773 --> 00:50:47,610 killing and injuring hundreds of people. 1095 00:50:47,643 --> 00:50:50,680 It's incredibly destructive stuff. 1096 00:50:50,713 --> 00:50:52,182 How does it work? 1097 00:50:52,215 --> 00:50:53,983 I don't know about you, 1098 00:50:54,016 --> 00:50:56,152 but I am not seeing much car over there. 1099 00:50:56,185 --> 00:50:59,355 That's 'cause there's not much car left, David. 1100 00:50:59,388 --> 00:51:02,459 POGUE: To find out, I turn to the lab's chief research chemist, 1101 00:51:02,492 --> 00:51:03,660 Christa Hockensmith. 1102 00:51:03,693 --> 00:51:06,396 The tires are still there. 1103 00:51:06,429 --> 00:51:09,199 POGUE: She's an expert in the chemistry of explosives. 1104 00:51:09,232 --> 00:51:10,567 Wow. 1105 00:51:10,600 --> 00:51:12,802 HOCKENSMITH: Whoo, doesn't smell so good, does it? 1106 00:51:12,835 --> 00:51:13,903 No. 1107 00:51:13,936 --> 00:51:15,638 You know, we thought maybe the engine 1108 00:51:15,671 --> 00:51:17,841 would become a projectile to come hurtling out. 1109 00:51:17,874 --> 00:51:21,478 The engine did not leave, but the entire car did! 1110 00:51:21,511 --> 00:51:22,545 This whole front half... 1111 00:51:22,578 --> 00:51:24,647 and the car used to be parked over there! 1112 00:51:24,680 --> 00:51:25,682 POGUE: With her help... 1113 00:51:25,715 --> 00:51:27,584 Ah, look at this! 1114 00:51:27,617 --> 00:51:29,085 ...I'm going to conduct 1115 00:51:29,118 --> 00:51:30,820 a forensic investigation of the blast site. 1116 00:51:30,853 --> 00:51:31,855 Cadillac. 1117 00:51:31,888 --> 00:51:33,756 POGUE: But there's not much left. 1118 00:51:33,789 --> 00:51:36,459 What kind of evidence can you derive from this? 1119 00:51:36,492 --> 00:51:37,760 I mean, the car is totally decimated. 1120 00:51:37,793 --> 00:51:41,731 No, we can do good work on finding out 1121 00:51:41,764 --> 00:51:48,271 what caused this explosion with the magic swabs. 1122 00:51:48,304 --> 00:51:51,341 POGUE: We know what was in the bomb... 1123 00:51:51,374 --> 00:51:52,542 I'm getting the hang of this now. 1124 00:51:52,575 --> 00:51:54,410 Yeah, you are, you're getting good. 1125 00:51:54,443 --> 00:51:56,279 POGUE: ...but in an actual criminal investigation, 1126 00:51:56,312 --> 00:51:57,881 this work is vital. 1127 00:51:57,914 --> 00:51:59,449 We're not picking up only filth. 1128 00:51:59,482 --> 00:52:02,218 What we're picking up is what the bomb was made with. 1129 00:52:02,251 --> 00:52:03,753 You think there's going to be traces 1130 00:52:03,786 --> 00:52:04,787 even on this fragment? 1131 00:52:04,820 --> 00:52:06,623 Not if you stick your fingers on it, no. 1132 00:52:06,656 --> 00:52:09,225 But otherwise, yes. 1133 00:52:09,258 --> 00:52:10,793 What you're gonna find is-- 1134 00:52:10,826 --> 00:52:12,328 when we take these back to the lab-- 1135 00:52:12,361 --> 00:52:14,264 that we'll be able to tell 1136 00:52:14,297 --> 00:52:16,466 what elements were present in the bomb. 1137 00:52:16,499 --> 00:52:19,569 POGUE: So much energy released so quickly... 1138 00:52:19,602 --> 00:52:21,337 did oxygen have a role? 1139 00:52:21,370 --> 00:52:22,772 Still runs! 1140 00:52:25,107 --> 00:52:27,710 So, David, what did you think of that car bomb? 1141 00:52:27,743 --> 00:52:29,445 Wicked cool. 1142 00:52:29,478 --> 00:52:30,547 Yes, it was. 1143 00:52:30,580 --> 00:52:31,648 You have the luckiest job in the world. 1144 00:52:31,681 --> 00:52:32,482 You got the swab? 1145 00:52:32,515 --> 00:52:32,515 Here's your swab. 1146 00:52:32,515 --> 00:52:33,917 Okay. 1147 00:52:33,950 --> 00:52:37,020 Christa instructs me to dip the pad into purified water... 1148 00:52:37,053 --> 00:52:38,621 You can shake this up. 1149 00:52:38,654 --> 00:52:39,989 Like that? 1150 00:52:40,022 --> 00:52:41,524 ...to dissolve any chemical traces 1151 00:52:41,557 --> 00:52:43,059 recovered from the debris. 1152 00:52:43,092 --> 00:52:46,262 Covered with paper pulp? 1153 00:52:46,295 --> 00:52:48,364 No, covered with nasty. 1154 00:52:48,397 --> 00:52:49,499 There you are. 1155 00:52:49,532 --> 00:52:51,034 You go like this? 1156 00:52:51,067 --> 00:52:52,435 Shall I suck it up? 1157 00:52:52,468 --> 00:52:54,003 Please. 1158 00:52:54,036 --> 00:52:56,873 That's plenty. 1159 00:52:56,906 --> 00:52:58,041 Okay. 1160 00:52:58,074 --> 00:53:00,643 Stick it right back into the ion chromatograph. 1161 00:53:00,676 --> 00:53:02,712 Okay, you'll just feel a little pinch... 1162 00:53:02,745 --> 00:53:04,581 POGUE: The ion chromatograph 1163 00:53:04,614 --> 00:53:07,584 looks for positively or negatively charged molecules 1164 00:53:07,617 --> 00:53:10,954 called ions in the residue, 1165 00:53:10,987 --> 00:53:13,089 fragments of the original chemical explosive. 1166 00:53:13,122 --> 00:53:15,024 Well, there appears to be a spike right here 1167 00:53:15,057 --> 00:53:16,092 at number three. 1168 00:53:16,125 --> 00:53:17,060 There sure does. 1169 00:53:17,093 --> 00:53:20,029 What use is this analysis? 1170 00:53:20,062 --> 00:53:22,198 Can you tell the State Department 1171 00:53:22,231 --> 00:53:23,399 where the bomb came from? 1172 00:53:23,432 --> 00:53:24,801 I can. 1173 00:53:24,834 --> 00:53:25,902 Really? 1174 00:53:25,935 --> 00:53:26,803 And have you? 1175 00:53:26,836 --> 00:53:28,571 Do they bring you...? 1176 00:53:28,604 --> 00:53:29,606 I can't talk about that. 1177 00:53:29,639 --> 00:53:30,640 You can just say yes or no. 1178 00:53:30,673 --> 00:53:31,774 You can wink. 1179 00:53:31,807 --> 00:53:33,443 No, I can't. 1180 00:53:33,476 --> 00:53:36,012 POGUE: Different elements show up as spikes 1181 00:53:36,045 --> 00:53:38,314 in different locations on the graph. 1182 00:53:38,347 --> 00:53:41,117 Christa tells me this spike indicates that oxygen 1183 00:53:41,150 --> 00:53:45,922 is at work here, contained in molecules called nitrates. 1184 00:53:45,955 --> 00:53:48,625 Nitrates consist of three oxygen atoms 1185 00:53:48,658 --> 00:53:51,427 bound to a central nitrogen atom. 1186 00:53:51,460 --> 00:53:52,895 To set off the bomb, 1187 00:53:52,928 --> 00:53:56,366 an initial spark of heat breaks those bonds. 1188 00:53:56,399 --> 00:53:59,802 Once set free, oxygen rushes away from the nitrogen 1189 00:53:59,835 --> 00:54:02,171 to combine with the elements it prefers-- 1190 00:54:02,204 --> 00:54:05,742 carbon, hydrogen, and even other oxygen atoms-- 1191 00:54:05,775 --> 00:54:08,878 leaving the nitrogen to pair up with each other. 1192 00:54:08,911 --> 00:54:11,247 Every time atoms form a new bond, 1193 00:54:11,280 --> 00:54:13,383 the reaction releases energy. 1194 00:54:13,416 --> 00:54:16,786 And that's what powers the explosion. 1195 00:54:20,656 --> 00:54:24,360 But, in fact, we see similar oxygen reactions every day. 1196 00:54:24,393 --> 00:54:26,429 Like ordinary fire. 1197 00:54:26,462 --> 00:54:28,665 The heat of this flame is generated 1198 00:54:28,698 --> 00:54:33,970 when carbon atoms in the wick bond with oxygen in the air. 1199 00:54:34,003 --> 00:54:39,676 Or rust, a very slow reaction when iron and oxygen combine. 1200 00:54:39,709 --> 00:54:44,514 Oxygen makes engines rev, rockets roar. 1201 00:54:44,547 --> 00:54:46,549 And in exactly the same way, 1202 00:54:46,582 --> 00:54:49,385 oxygen reacts with the food we eat, 1203 00:54:49,418 --> 00:54:53,289 releasing energy like countless tiny fires 1204 00:54:53,322 --> 00:54:57,226 burning in our cells, keeping us alive. 1205 00:54:57,259 --> 00:54:59,729 All of these combustion reactions 1206 00:54:59,762 --> 00:55:01,698 are essentially the same. 1207 00:55:01,731 --> 00:55:04,167 The only difference is speed. 1208 00:55:04,200 --> 00:55:09,639 So how do you speed up a fire to create an explosion? 1209 00:55:09,672 --> 00:55:11,607 You regulate the amount of oxygen 1210 00:55:11,640 --> 00:55:15,378 and how closely it's packed together with other elements. 1211 00:55:15,411 --> 00:55:19,315 As a final demonstration, Christa wants to show me 1212 00:55:19,348 --> 00:55:22,785 how chemists have learned to control the speed of combustion. 1213 00:55:22,818 --> 00:55:25,755 She has arranged the use of a high-speed camera 1214 00:55:25,788 --> 00:55:29,158 to record several different types of explosives. 1215 00:55:29,191 --> 00:55:30,827 We take cover. 1216 00:55:30,860 --> 00:55:31,861 Bunker. 1217 00:55:31,894 --> 00:55:33,263 Bunker. 1218 00:55:38,334 --> 00:55:42,939 POGUE: The first demonstration will be ordinary gunpowder. 1219 00:55:42,972 --> 00:55:44,640 So pure gunpowder is our first test here, right? 1220 00:55:44,673 --> 00:55:47,210 Yes, this is a smokeless powder. 1221 00:55:47,243 --> 00:55:48,478 Whoa! 1222 00:55:48,511 --> 00:55:50,480 Nicely done! 1223 00:55:50,513 --> 00:55:55,184 It was quick, but it wasn't blisteringly quick. 1224 00:55:55,217 --> 00:55:57,353 POGUE: The gunpowder contains its own oxygen, 1225 00:55:57,386 --> 00:55:59,922 but it's in a mixture of powdered chemicals 1226 00:55:59,955 --> 00:56:04,093 held far away from the carbon it needs to bond with. 1227 00:56:04,126 --> 00:56:06,229 But when they finally find their partners, 1228 00:56:06,262 --> 00:56:10,299 the new bonds they form release lots of energy. 1229 00:56:10,332 --> 00:56:13,803 Gunpowder is a relatively slow explosive. 1230 00:56:13,836 --> 00:56:15,872 That's why it's used in guns. 1231 00:56:15,905 --> 00:56:18,608 It creates enough force to fire a projectile, 1232 00:56:18,641 --> 00:56:22,879 but not enough to damage the barrel. 1233 00:56:22,912 --> 00:56:24,547 So you're saying there must be explosives that... 1234 00:56:24,580 --> 00:56:25,915 We're going to get faster and faster. 1235 00:56:25,948 --> 00:56:29,719 POGUE: Next is an emulsion gel explosive. 1236 00:56:29,752 --> 00:56:32,121 Its main ingredient is ammonium nitrate, 1237 00:56:32,154 --> 00:56:34,824 the same stuff that blew up the car. 1238 00:56:34,857 --> 00:56:37,059 A lot more oxygen and a lot of nitrogen 1239 00:56:37,092 --> 00:56:39,695 packed very closely together in a liquid. 1240 00:56:39,728 --> 00:56:41,564 MAN: Three... two... one. 1241 00:56:41,597 --> 00:56:42,698 (explosion) 1242 00:56:42,731 --> 00:56:44,534 POGUE: Oh, jeez! 1243 00:56:44,567 --> 00:56:46,335 Man, I could feel that puppy through here. 1244 00:56:46,368 --> 00:56:49,439 This is a high explosive. 1245 00:56:49,472 --> 00:56:51,107 It generates a shock wave 1246 00:56:51,140 --> 00:56:54,143 that moves faster than the speed of sound. 1247 00:56:54,176 --> 00:56:56,846 In this explosive, oxygen, hydrogen and nitrogen 1248 00:56:56,879 --> 00:56:58,347 are so close together 1249 00:56:58,380 --> 00:57:00,650 they lose no time finding new partners 1250 00:57:00,683 --> 00:57:04,086 and making new bonds that release energy. 1251 00:57:04,119 --> 00:57:09,258 The final demonstration is one pound of C4-- 1252 00:57:09,291 --> 00:57:11,894 a military-grade high explosive 1253 00:57:11,927 --> 00:57:14,197 which burns fast enough to cut steel. 1254 00:57:14,230 --> 00:57:17,934 MAN: Five, four, three, two, one. 1255 00:57:17,967 --> 00:57:18,868 (explosion) 1256 00:57:18,901 --> 00:57:20,169 POGUE: Oh, jeez! 1257 00:57:20,202 --> 00:57:21,971 There's nothing to see. 1258 00:57:22,004 --> 00:57:25,608 It was there, and it was gone! 1259 00:57:25,641 --> 00:57:29,479 C4 assembles oxygen, nitrogen, hydrogen and carbon 1260 00:57:29,512 --> 00:57:32,248 in high concentration-- close together, 1261 00:57:32,281 --> 00:57:34,150 all on a big molecule, 1262 00:57:34,183 --> 00:57:38,221 so the speed of the reaction is blisteringly fast. 1263 00:57:38,254 --> 00:57:41,657 And that gives me an idea. 1264 00:57:41,690 --> 00:57:46,095 Maybe C4 can help me exorcise a personal demon. 1265 00:57:46,128 --> 00:57:47,129 What can I say? 1266 00:57:47,162 --> 00:57:48,531 I have issues. 1267 00:57:48,564 --> 00:57:49,732 Quite frankly, Christa, 1268 00:57:49,765 --> 00:57:51,200 I've been looking forward to this one the most. 1269 00:57:51,233 --> 00:57:53,202 I am with you 100%. 1270 00:57:53,235 --> 00:57:53,970 Clown... 1271 00:57:54,003 --> 00:57:55,171 Let's do it to the clown. 1272 00:57:55,204 --> 00:57:56,873 Let's do it to the clown! 1273 00:57:56,906 --> 00:57:58,508 MAN: Three, two, one. 1274 00:58:00,943 --> 00:58:02,278 (Pogue laughing) 1275 00:58:02,311 --> 00:58:03,446 Okay! 1276 00:58:03,479 --> 00:58:05,314 Well, the world is minus one clown 1277 00:58:05,347 --> 00:58:07,884 and I am out of therapy. 1278 00:58:11,820 --> 00:58:14,056 POGUE: The oxygen that powers all those explosions 1279 00:58:14,089 --> 00:58:17,193 makes up 21% of our atmosphere. 1280 00:58:17,226 --> 00:58:20,763 It's the most abundant element in the earth's crust. 1281 00:58:20,796 --> 00:58:22,632 It's also a big part of us. 1282 00:58:22,665 --> 00:58:24,700 Which makes me wonder. 1283 00:58:24,733 --> 00:58:27,603 What other elements make life possible? 1284 00:58:27,636 --> 00:58:30,339 What, for example, is in me? 1285 00:58:30,372 --> 00:58:32,642 What's in a David? 1286 00:58:32,675 --> 00:58:37,246 Amazingly, I'm mostly made of just six elements: 1287 00:58:37,279 --> 00:58:39,515 nonmetals, mainly from a small neighborhood 1288 00:58:39,548 --> 00:58:41,684 on the periodic table-- 1289 00:58:41,717 --> 00:58:43,819 carbon, hydrogen, nitrogen, 1290 00:58:43,852 --> 00:58:47,256 oxygen, phosphorus, sulfur. 1291 00:58:47,289 --> 00:58:52,094 Or, as some prefer to call them, CHNOPS. 1292 00:58:52,127 --> 00:58:55,998 These are the elements that form the basis of all living things, 1293 00:58:56,031 --> 00:58:58,367 from the most primitive bacteria 1294 00:58:58,400 --> 00:59:00,770 to the largest creatures on earth. 1295 00:59:00,803 --> 00:59:03,139 It seems incredible that so much diversity 1296 00:59:03,172 --> 00:59:06,042 could spring from such a tiny list. 1297 00:59:06,075 --> 00:59:10,546 But what I don't get is, why these six? 1298 00:59:10,579 --> 00:59:13,416 Why CHNOPS? 1299 00:59:13,449 --> 00:59:14,550 Professor? 1300 00:59:14,583 --> 00:59:15,484 Yeah? 1301 00:59:15,517 --> 00:59:16,652 Sorry, I'm late for class. 1302 00:59:16,685 --> 00:59:19,055 POGUE: Chemistry professor Christine Thomas 1303 00:59:19,088 --> 00:59:21,123 at Brandeis University 1304 00:59:21,156 --> 00:59:24,627 has agreed to help me understand what makes me tick. 1305 00:59:24,660 --> 00:59:28,364 I was told that you can help me understand C-H-N-O-P-S, CHNOPS. 1306 00:59:28,397 --> 00:59:29,498 The elements of life. 1307 00:59:29,531 --> 00:59:31,067 CHNOPS? 1308 00:59:31,100 --> 00:59:33,169 POGUE: Better than that, she's going to show me the actual elements 1309 00:59:33,202 --> 00:59:36,439 in the actual quantities that are in me. 1310 00:59:36,472 --> 00:59:38,240 But I don't get how. 1311 00:59:38,273 --> 00:59:41,310 I've prepared for you a CHNOPPING list. 1312 00:59:41,343 --> 00:59:41,343 A CHNOPPING list. 1313 00:59:41,343 --> 00:59:43,179 (laughs) 1314 00:59:43,212 --> 00:59:44,280 You'll have to show me this. 1315 00:59:44,313 --> 00:59:46,882 POGUE: Where do you go to find the elements 1316 00:59:46,915 --> 00:59:49,785 that make up a 185-pound man? 1317 00:59:49,818 --> 00:59:50,853 Isn't it a little weird 1318 00:59:50,886 --> 00:59:53,122 that we're shopping for the elements of life 1319 00:59:53,155 --> 00:59:54,724 at a hardware store? 1320 00:59:54,757 --> 00:59:56,359 Does seem a little strange at first. 1321 00:59:56,392 --> 01:00:00,529 POGUE: But in fact, they're all here in these aisles 1322 01:00:00,562 --> 01:00:03,966 starting with C-- carbon. 1323 01:00:03,999 --> 01:00:06,168 All right, charcoal, right over here. 1324 01:00:06,201 --> 01:00:08,237 POGUE: Charcoal? 1325 01:00:08,270 --> 01:00:11,540 I don't think of the human body being made of charcoal. 1326 01:00:11,573 --> 01:00:14,276 Oh, it's made of carbon, and... you know, just trust me. 1327 01:00:14,309 --> 01:00:16,045 Hydrogen? 1328 01:00:16,078 --> 01:00:17,213 Yup, that's next. 1329 01:00:17,246 --> 01:00:20,082 We're going to get it right here, in water. 1330 01:00:20,115 --> 01:00:22,852 In fact, we're going to get both hydrogen and oxygen 1331 01:00:22,885 --> 01:00:24,086 all in one place. 1332 01:00:24,119 --> 01:00:26,989 So next on the list is nitrogen. 1333 01:00:27,022 --> 01:00:28,190 This is fertilizer. 1334 01:00:28,223 --> 01:00:29,859 It is, and fertilizer, as it turns out, 1335 01:00:29,892 --> 01:00:32,261 has a lot of nitrogen in it, just like you. 1336 01:00:32,294 --> 01:00:34,530 I've been told I'm full of... never mind. 1337 01:00:34,563 --> 01:00:37,033 POGUE: Next is phosphorus. 1338 01:00:37,066 --> 01:00:38,901 I'm not seeing phosphorus. 1339 01:00:38,934 --> 01:00:40,836 There's in fact phosphorus in these matches. 1340 01:00:40,869 --> 01:00:42,138 You're probably going to need 1341 01:00:42,171 --> 01:00:44,574 probably all of the matches that they have here. 1342 01:00:46,508 --> 01:00:47,476 There you go! 1343 01:00:47,509 --> 01:00:50,413 Oh, that ought to do. 1344 01:00:54,216 --> 01:00:55,317 Hi there. 1345 01:00:55,350 --> 01:00:56,786 How are you? 1346 01:00:56,819 --> 01:00:58,487 Just a couple things. 1347 01:00:58,520 --> 01:01:00,857 We're having a couple people over for grill. 1348 01:01:07,129 --> 01:01:09,965 168 bucks?! 1349 01:01:09,998 --> 01:01:13,536 All the vital elements in this magnificent body, 168 bucks? 1350 01:01:13,569 --> 01:01:14,971 Yup, that's it. 1351 01:01:19,041 --> 01:01:22,812 POGUE: So you're telling me that our hardware store haul here 1352 01:01:22,845 --> 01:01:24,413 actually is representative 1353 01:01:24,446 --> 01:01:26,716 of the CHNOPS elements in all life? 1354 01:01:26,749 --> 01:01:28,250 And roughly in the right proportions? 1355 01:01:28,283 --> 01:01:30,853 POGUE: Christine tells me we did pretty well, 1356 01:01:30,886 --> 01:01:32,755 but we didn't quite nail it. 1357 01:01:32,788 --> 01:01:35,725 We're still missing most of the phosphorus we need. 1358 01:01:35,758 --> 01:01:38,260 Luckily, she knows where to get some, 1359 01:01:38,293 --> 01:01:42,131 thanks to a discovery by a 17th-century alchemist 1360 01:01:42,164 --> 01:01:44,667 named Hennig Brandt. 1361 01:01:44,700 --> 01:01:47,069 Brandt was looking for precious gold 1362 01:01:47,102 --> 01:01:49,972 and he thought he might find it in a bodily fluid 1363 01:01:50,005 --> 01:01:52,541 that looks golden indeed. 1364 01:01:52,574 --> 01:01:53,476 All right. 1365 01:01:53,509 --> 01:01:55,144 So we gotta get some... some urine 1366 01:01:55,177 --> 01:01:57,546 and we can, we can get phosphorus from it. 1367 01:01:57,579 --> 01:01:59,815 Actually, you're going to provide a urine sample 1368 01:01:59,848 --> 01:02:00,883 for us to study. 1369 01:02:00,916 --> 01:02:03,953 POGUE: Okay, anything for science. 1370 01:02:13,362 --> 01:02:17,032 Turns out the amount of phosphorus 1371 01:02:17,065 --> 01:02:18,834 in my sample is microscopic. 1372 01:02:18,867 --> 01:02:24,306 We're going to need a lot more, so back to the stable. 1373 01:02:24,339 --> 01:02:25,508 (horse whinnies) 1374 01:02:27,009 --> 01:02:28,811 (sloshing) 1375 01:03:01,643 --> 01:03:05,080 Centuries ago, Hennig Brandt had to collect gallons of urine 1376 01:03:05,113 --> 01:03:06,582 for his experiment. 1377 01:03:09,685 --> 01:03:11,420 (stream flowing) 1378 01:03:27,169 --> 01:03:28,170 Wow. 1379 01:03:28,203 --> 01:03:29,972 I didn't think you had it in you. 1380 01:03:30,005 --> 01:03:31,040 Very funny. 1381 01:03:31,073 --> 01:03:32,474 It was a lot of work, frankly. 1382 01:03:32,507 --> 01:03:36,111 POGUE: The next step requires a concentrated sludge, 1383 01:03:36,144 --> 01:03:38,347 which is urine minus most of the water. 1384 01:03:38,380 --> 01:03:42,051 Brandt's early process caused the phosphorus 1385 01:03:42,084 --> 01:03:43,752 to rise as a vapor, 1386 01:03:43,785 --> 01:03:46,055 which Christine directs safely into water 1387 01:03:46,088 --> 01:03:50,159 because phosphorus is dangerously reactive in the air. 1388 01:03:50,192 --> 01:03:51,393 While that's underway, 1389 01:03:51,426 --> 01:03:53,829 it's time to get the lowdown on the stuff we bought. 1390 01:03:53,862 --> 01:03:55,064 Starting with... 1391 01:03:55,097 --> 01:03:56,632 Carbon. 1392 01:03:56,665 --> 01:04:00,369 Six protons, six electrons in two shells. 1393 01:04:00,402 --> 01:04:04,273 Its pure forms include graphite, diamond, buckyballs, 1394 01:04:04,306 --> 01:04:07,710 nanotubes and graphene. 1395 01:04:07,743 --> 01:04:08,911 You mean charcoal? 1396 01:04:08,944 --> 01:04:10,779 Well, we bought charcoal to represent carbon 1397 01:04:10,812 --> 01:04:12,982 because it's made up of mostly carbon. 1398 01:04:13,015 --> 01:04:15,951 Carbon in its elemental form looks like this graphite here, 1399 01:04:15,984 --> 01:04:17,386 like you'd find on the inside of a pencil. 1400 01:04:17,419 --> 01:04:20,222 What charcoal is mostly is just leftover, say, burnt wood. 1401 01:04:20,255 --> 01:04:24,293 When wood burns, what's eventually left over 1402 01:04:24,326 --> 01:04:28,998 looks an awful lot like this charcoal, or this carbon. 1403 01:04:29,031 --> 01:04:31,967 POGUE: And the stuff in charcoal happens to be the foundation 1404 01:04:32,000 --> 01:04:34,436 of all life on Earth. 1405 01:04:34,469 --> 01:04:36,438 And for good reason. 1406 01:04:36,471 --> 01:04:37,773 Carbon is the backbone of living things 1407 01:04:37,806 --> 01:04:39,541 because since it can bond to itself, 1408 01:04:39,574 --> 01:04:41,543 it can form these long chains of molecules. 1409 01:04:41,576 --> 01:04:45,080 POGUE: Long chains can form because every carbon atom 1410 01:04:45,113 --> 01:04:47,983 needs four electrons to fill its outer shell, 1411 01:04:48,016 --> 01:04:51,520 which means it's eager to bond with up to four others, 1412 01:04:51,553 --> 01:04:53,856 even carbon atoms. 1413 01:04:53,889 --> 01:04:56,659 Virtually all long molecules in the body 1414 01:04:56,692 --> 01:04:59,662 are built around carbon. 1415 01:04:59,695 --> 01:05:01,397 Your body's about 18% carbon, 1416 01:05:01,430 --> 01:05:03,899 which for you would be 33.3 pounds. 1417 01:05:03,932 --> 01:05:05,234 Which is equivalent to 1418 01:05:05,267 --> 01:05:06,802 about two-and-a-half bags of charcoal here. 1419 01:05:06,835 --> 01:05:08,137 All right, so next we have nitrogen. 1420 01:05:08,170 --> 01:05:10,072 We do. 1421 01:05:10,105 --> 01:05:11,674 For this you bought fertilizer. 1422 01:05:11,707 --> 01:05:13,309 Right, so fertilizer is made up 1423 01:05:13,342 --> 01:05:14,977 of a very large percentage of nitrogen 1424 01:05:15,010 --> 01:05:17,846 because plants actually use nitrogen as food. 1425 01:05:17,879 --> 01:05:20,716 So how much actual nitrogen is in a guy like me? 1426 01:05:20,749 --> 01:05:22,918 So your body's about three percent nitrogen, 1427 01:05:22,951 --> 01:05:25,554 so in your case that's 5.6 pounds. 1428 01:05:25,587 --> 01:05:27,423 Okay, hydrogen and oxygen. 1429 01:05:27,456 --> 01:05:30,559 You have these tiles stacked side by side. 1430 01:05:30,592 --> 01:05:32,695 Hydrogen and oxygen. 1431 01:05:32,728 --> 01:05:33,862 H2O in water. 1432 01:05:33,895 --> 01:05:35,164 A twofer! 1433 01:05:35,197 --> 01:05:38,867 Hydrogen and oxygen can actually be separated from water 1434 01:05:38,900 --> 01:05:40,269 using a little bit of electricity. 1435 01:05:40,302 --> 01:05:43,172 POGUE: Electric current breaks up the water molecule. 1436 01:05:43,205 --> 01:05:46,475 The result is these tiny bubbles of hydrogen gas. 1437 01:05:46,508 --> 01:05:49,511 Turns out they're really quite volatile. 1438 01:05:49,544 --> 01:05:50,312 Ooh! 1439 01:05:50,345 --> 01:05:51,480 (laughs) 1440 01:05:51,513 --> 01:05:53,382 POGUE: What the electric current accomplished 1441 01:05:53,415 --> 01:05:56,385 by separating water into hydrogen and oxygen 1442 01:05:56,418 --> 01:05:59,355 a simple flame put back together again. 1443 01:05:59,388 --> 01:06:02,157 THOMAS: Now notice what you see on here, it's a little cloudy, right? 1444 01:06:02,190 --> 01:06:05,928 POGUE: That little foggy spot on the test tube is brand new water 1445 01:06:05,961 --> 01:06:10,399 made just now by burning hydrogen and oxygen. 1446 01:06:10,432 --> 01:06:14,036 Hydrogen is the lightest atom in the universe. 1447 01:06:14,069 --> 01:06:16,505 So even though there are more hydrogen atoms in me 1448 01:06:16,538 --> 01:06:20,809 than any other kind, it adds up to only about 18 pounds. 1449 01:06:20,842 --> 01:06:23,645 Next, oxygen, also in water. 1450 01:06:23,678 --> 01:06:28,117 Of course, I know how much fire likes pure oxygen. 1451 01:06:28,150 --> 01:06:32,821 So why don't you go ahead and light this twig here on fire. 1452 01:06:32,854 --> 01:06:36,592 When you see it starting to glow, go ahead and blow it out. 1453 01:06:39,628 --> 01:06:40,763 Whoa! 1454 01:06:40,796 --> 01:06:43,932 You have created fire! 1455 01:06:43,965 --> 01:06:47,202 Okay, so how much oxygen is in me? 1456 01:06:47,235 --> 01:06:50,105 In a person's body, there's 65% oxygen. 1457 01:06:50,138 --> 01:06:52,841 Actually, in your body would equate to 120 pounds. 1458 01:06:52,874 --> 01:06:54,009 That makes it sound like 1459 01:06:54,042 --> 01:06:56,378 I'm a Macy's Thanksgiving balloon or something. 1460 01:06:56,411 --> 01:06:58,480 POGUE: But as Christine has already demonstrated, 1461 01:06:58,513 --> 01:07:02,618 it's not in me as a gas, it's in all that water. 1462 01:07:02,651 --> 01:07:04,753 And this brings us to P. 1463 01:07:04,786 --> 01:07:06,955 I mean, of course, P as in phosphorus. 1464 01:07:06,988 --> 01:07:11,894 POGUE: Hot phosphorus vapor when cooled in water turns into a solid. 1465 01:07:11,927 --> 01:07:13,395 THOMAS: Yes. 1466 01:07:13,428 --> 01:07:15,964 We've actually condensed it here as a nice chunky, white solid. 1467 01:07:15,997 --> 01:07:17,900 Phosphorus is actually involved 1468 01:07:17,933 --> 01:07:20,002 in something really important called ATP, 1469 01:07:20,035 --> 01:07:23,038 which is the molecule that all cells use for energy. 1470 01:07:23,071 --> 01:07:25,908 POGUE: Altogether, phosphorus makes up about one percent 1471 01:07:25,941 --> 01:07:28,343 of my six-foot-two-inch body. 1472 01:07:28,376 --> 01:07:31,046 Phosphorus was the first element isolated 1473 01:07:31,079 --> 01:07:32,414 from a living creature. 1474 01:07:32,447 --> 01:07:35,250 And it must have surprised Brandt. 1475 01:07:35,283 --> 01:07:37,486 Exposed to air, it glows, 1476 01:07:37,519 --> 01:07:41,323 creating what he described as "cold fire." 1477 01:07:41,356 --> 01:07:46,495 This chemical glow is what we mean today by phosphorescence. 1478 01:07:46,528 --> 01:07:48,363 And when burned in oxygen, 1479 01:07:48,396 --> 01:07:51,033 it generates a spectacular pulsing display 1480 01:07:51,066 --> 01:07:53,702 called a phosphorus sun. 1481 01:07:53,735 --> 01:07:57,005 No wonder it's used to provide energy in our bodies. 1482 01:07:57,038 --> 01:07:59,641 And to think where it came from. 1483 01:07:59,674 --> 01:08:01,076 (horse whinnies) 1484 01:08:01,109 --> 01:08:04,413 There's just one thing left on our CHNOPPING list: sulfur. 1485 01:08:04,446 --> 01:08:05,581 POGUE: I don't get it. 1486 01:08:05,614 --> 01:08:07,316 What does a tire have to do with sulfur? 1487 01:08:07,349 --> 01:08:09,718 So there's a very small fraction of sulfur in this tire, 1488 01:08:09,751 --> 01:08:10,886 and as it turns out, 1489 01:08:10,919 --> 01:08:12,921 there's the same amount of sulfur in this one tire 1490 01:08:12,954 --> 01:08:15,657 as there is in a 185-pound David. 1491 01:08:15,690 --> 01:08:16,792 Which is about how much? 1492 01:08:16,825 --> 01:08:18,293 Which is about half a pound. 1493 01:08:18,326 --> 01:08:22,231 POGUE: Altogether, just those six CHNOPS elements 1494 01:08:22,264 --> 01:08:25,501 make up 97% of the weight of my body. 1495 01:08:25,534 --> 01:08:27,970 But what about the other three percent? 1496 01:08:28,003 --> 01:08:30,672 And so whatever is left over in those different beings 1497 01:08:30,705 --> 01:08:33,208 must be what differentiates one from the next. 1498 01:08:33,241 --> 01:08:35,344 Right, there's what's called the trace elements. 1499 01:08:35,377 --> 01:08:37,813 And the person that would be better to talk to about those 1500 01:08:37,846 --> 01:08:39,348 might be someone that's interested 1501 01:08:39,381 --> 01:08:42,184 in maybe sports medicine or professional athletes. 1502 01:08:42,217 --> 01:08:44,553 Let's see, who could tell us 1503 01:08:44,586 --> 01:08:47,923 about sports, athletes and elements? 1504 01:08:47,956 --> 01:08:50,159 Who could tell us? 1505 01:08:51,393 --> 01:08:53,529 POGUE: Hey, are you Lindsay? 1506 01:08:53,562 --> 01:08:54,396 Yeah, I'm Lindsay. 1507 01:08:54,429 --> 01:08:55,264 David. 1508 01:08:55,297 --> 01:08:56,398 Nice to meet you, David. 1509 01:08:56,431 --> 01:08:57,766 Welcome to the Gatorade Sports Science Institute. 1510 01:08:57,799 --> 01:08:59,334 Gatorade Sports Science Institute. 1511 01:08:59,367 --> 01:09:01,970 I know you guys are involved with elements in the body 1512 01:09:02,003 --> 01:09:03,772 and athlete performance. 1513 01:09:03,805 --> 01:09:07,176 I actually am very concerned with these things too. 1514 01:09:07,209 --> 01:09:09,411 In fact, every morning, I take supplements. 1515 01:09:09,444 --> 01:09:11,580 I use organic elements, 1516 01:09:11,613 --> 01:09:13,582 I make my own. 1517 01:09:13,615 --> 01:09:16,084 Um, calcium, very important. 1518 01:09:16,117 --> 01:09:17,586 Sometimes I... 1519 01:09:19,788 --> 01:09:21,690 Sometimes I'll mix it up, get a little chalk. 1520 01:09:21,723 --> 01:09:23,625 It might look like soap to you, 1521 01:09:23,658 --> 01:09:26,495 but it's a fine source of potassium. 1522 01:09:28,263 --> 01:09:29,164 Iron, 1523 01:09:29,197 --> 01:09:31,567 zinc, 1524 01:09:31,600 --> 01:09:33,702 magnesium... 1525 01:09:33,735 --> 01:09:36,672 I like to think of this as an excellent source of sodium. 1526 01:09:38,340 --> 01:09:39,575 And this is it every morning. 1527 01:09:39,608 --> 01:09:41,610 You know, it doesn't taste fantastic, 1528 01:09:41,643 --> 01:09:44,079 but wow, is it good for me! 1529 01:09:46,181 --> 01:09:48,050 Am I going about this the right way? 1530 01:09:48,083 --> 01:09:50,886 Actually, David, there's a better way to get your elements, 1531 01:09:50,919 --> 01:09:53,055 such as calcium, iron, magnesium, 1532 01:09:53,088 --> 01:09:54,957 in your daily food intake. 1533 01:09:54,990 --> 01:09:58,427 But this is organic free-range! 1534 01:09:58,460 --> 01:10:02,231 POGUE: I'm curious to know how my body uses those trace elements. 1535 01:10:02,264 --> 01:10:03,899 But first, a battery of tests 1536 01:10:03,932 --> 01:10:07,703 to determine what kind of shape I'm in. 1537 01:10:07,736 --> 01:10:09,004 Once I've been poked... 1538 01:10:09,037 --> 01:10:11,173 Go ahead and take all of your clothes off. 1539 01:10:11,206 --> 01:10:11,940 Okay. 1540 01:10:11,973 --> 01:10:12,741 POGUE: ...weighed... 1541 01:10:12,774 --> 01:10:14,510 David, I said all your clothes. 1542 01:10:16,244 --> 01:10:17,312 POGUE: ...measured... 1543 01:10:17,345 --> 01:10:19,281 and scanned-- 1544 01:10:19,314 --> 01:10:21,149 and by the way, in the real world, 1545 01:10:21,182 --> 01:10:22,818 this costs some serious money-- 1546 01:10:22,851 --> 01:10:27,422 she puts me on a treadmill to measure my oxygen use, 1547 01:10:27,455 --> 01:10:30,425 which could be impaired if I have an iron deficiency. 1548 01:10:30,458 --> 01:10:31,393 Okay, and start. 1549 01:10:31,426 --> 01:10:34,396 We'll get to a nice comfy walking pace. 1550 01:10:34,429 --> 01:10:36,898 15 seconds, we're going to increase the speed. 1551 01:10:36,931 --> 01:10:41,537 Okay, David, what's your rating of perceived exertion? 1552 01:10:44,706 --> 01:10:46,608 Keep pushing. 1553 01:10:46,641 --> 01:10:49,344 Okay, David, how do you feel at this stage? 1554 01:10:49,377 --> 01:10:50,545 15? 1555 01:10:50,578 --> 01:10:51,713 Where you at now? 1556 01:10:51,746 --> 01:10:53,949 He's at an 18, okay. 1557 01:10:53,982 --> 01:10:56,218 Ten more seconds, hard as you can. 1558 01:10:56,251 --> 01:10:57,252 You can do it. 1559 01:10:57,285 --> 01:10:58,387 Got any more left? 1560 01:10:58,420 --> 01:11:00,255 Okay, okay, go ahead and stretch, 1561 01:11:00,288 --> 01:11:01,690 go ahead and grab onto the railing. 1562 01:11:03,591 --> 01:11:05,427 That's good, that's good. 1563 01:11:05,460 --> 01:11:07,562 POGUE: Next, a sweat test. 1564 01:11:07,595 --> 01:11:08,764 Okay. 1565 01:11:14,602 --> 01:11:15,504 All the way down, good. 1566 01:11:15,537 --> 01:11:17,472 Lock out at the top. 1567 01:11:17,505 --> 01:11:20,008 This is how OSHA violations happen. 1568 01:11:20,041 --> 01:11:22,711 You know, if you play this video in opposite way, 1569 01:11:22,744 --> 01:11:24,846 it will look like I'm really running. 1570 01:11:24,879 --> 01:11:26,114 Thank you, sir. 1571 01:11:26,147 --> 01:11:26,882 It's been a pleasure. 1572 01:11:26,915 --> 01:11:28,116 Go train somebody else. 1573 01:11:28,149 --> 01:11:29,551 We're just getting warmed up. 1574 01:11:29,584 --> 01:11:31,153 (laughs) 1575 01:11:31,186 --> 01:11:33,188 POGUE: Unfortunately, he wasn't joking. 1576 01:11:33,221 --> 01:11:35,390 Now they're ready to start the actual test. 1577 01:11:35,423 --> 01:11:37,659 These patches will collect my sweat, 1578 01:11:37,692 --> 01:11:39,895 which in turn will tell Lindsay 1579 01:11:39,928 --> 01:11:43,932 how much of the trace elements I'm losing from my body. 1580 01:11:43,965 --> 01:11:45,434 I feel like an old tire. 1581 01:11:45,467 --> 01:11:46,668 Here we go, ready, go! 1582 01:11:46,701 --> 01:11:48,303 Shouldn't you have a mower attachment, at least? 1583 01:11:48,336 --> 01:11:50,372 Come on, drive it, let's go. 1584 01:11:50,405 --> 01:11:51,440 Come on, stay lower. 1585 01:11:51,473 --> 01:11:52,641 Use your butt, use your glutes. 1586 01:11:52,674 --> 01:11:55,777 Finish it, finish it! 1587 01:11:55,810 --> 01:11:57,512 All the way down, all the way up. 1588 01:11:57,545 --> 01:11:58,980 Like that? 1589 01:11:59,013 --> 01:12:00,248 There you go. 1590 01:12:00,281 --> 01:12:01,616 A little higher, a little higher, let's go. 1591 01:12:01,649 --> 01:12:02,884 I'm going to start calling you names in a minute. 1592 01:12:02,917 --> 01:12:04,086 Let's go. 1593 01:12:04,119 --> 01:12:05,153 Oh my God. 1594 01:12:05,186 --> 01:12:06,521 Keep going, keep going... that was two. 1595 01:12:06,554 --> 01:12:07,856 Third-grade girls can get ten. 1596 01:12:07,889 --> 01:12:08,590 (laughs) 1597 01:12:08,623 --> 01:12:09,792 Let's go, keep going. 1598 01:12:11,960 --> 01:12:13,462 Excellent job. 1599 01:12:13,495 --> 01:12:14,463 Yeah, great job. 1600 01:12:14,496 --> 01:12:15,530 I have sweaty pads. 1601 01:12:15,563 --> 01:12:16,398 That's right. 1602 01:12:16,431 --> 01:12:17,699 Come and get 'em! 1603 01:12:17,732 --> 01:12:21,136 POGUE: So the purpose of all this was to measure 1604 01:12:21,169 --> 01:12:22,571 what electrolytes and salts and stuff 1605 01:12:22,604 --> 01:12:24,139 were leaking out of my sweat, right? 1606 01:12:24,172 --> 01:12:26,508 And why exactly do we care? 1607 01:12:26,541 --> 01:12:28,844 Why do you care in the athletes you train here? 1608 01:12:28,877 --> 01:12:32,247 What we want to prevent is athletes cramping, 1609 01:12:32,280 --> 01:12:33,448 affecting their performance, 1610 01:12:33,481 --> 01:12:35,150 not only in practices but also in games. 1611 01:12:35,183 --> 01:12:37,753 So you could be properly hydrated and still get cramps. 1612 01:12:37,786 --> 01:12:38,587 Correct. 1613 01:12:38,620 --> 01:12:39,654 Well, thanks for the education 1614 01:12:39,687 --> 01:12:40,956 and thanks for the workout, Coach. 1615 01:12:40,989 --> 01:12:42,023 You got it, anytime, Dave. 1616 01:12:42,056 --> 01:12:44,493 POGUE: And now for the results. 1617 01:12:44,526 --> 01:12:47,996 My bone density test: normal. 1618 01:12:48,029 --> 01:12:49,064 Plenty of calcium in me. 1619 01:12:49,097 --> 01:12:50,665 BAKER: So you have nice, strong bones. 1620 01:12:50,698 --> 01:12:55,137 So that means that my morning ritual of consuming calcium 1621 01:12:55,170 --> 01:12:56,705 seems to be working. 1622 01:12:56,738 --> 01:12:59,941 It is working, however, I would suggest dairy products 1623 01:12:59,974 --> 01:13:02,310 to get your calcium instead of seashells. 1624 01:13:02,343 --> 01:13:06,181 POGUE: The treadmill: not so good. 1625 01:13:06,214 --> 01:13:08,617 For your age and compared to other males, 1626 01:13:08,650 --> 01:13:11,086 you're in about the 30th percentile. 1627 01:13:11,119 --> 01:13:12,220 That's low. 1628 01:13:12,253 --> 01:13:13,221 It's low. 1629 01:13:13,254 --> 01:13:14,356 It's below average. 1630 01:13:14,389 --> 01:13:16,358 POGUE: This could mean one of two things. 1631 01:13:16,391 --> 01:13:18,660 Either I might have an iron deficiency-- 1632 01:13:18,693 --> 01:13:21,430 so my blood isn't carrying enough oxygen-- 1633 01:13:21,463 --> 01:13:23,565 or I'm really out of shape. 1634 01:13:23,598 --> 01:13:28,837 And my blood test showed I'm not iron deficient, so... 1635 01:13:28,870 --> 01:13:30,205 Well, what about the other elements? 1636 01:13:30,238 --> 01:13:31,006 What do they do? 1637 01:13:31,039 --> 01:13:32,174 Zinc? 1638 01:13:32,207 --> 01:13:35,177 Zinc is important for energy metabolism. 1639 01:13:35,210 --> 01:13:36,311 Potassium? 1640 01:13:36,344 --> 01:13:37,546 Potassium is an important part 1641 01:13:37,579 --> 01:13:39,614 of nervous system function. 1642 01:13:39,647 --> 01:13:41,016 Magnesium? 1643 01:13:41,049 --> 01:13:41,049 Energy metabolism. 1644 01:13:41,049 --> 01:13:42,617 Okay. 1645 01:13:42,650 --> 01:13:45,687 And finally, what about sodium? 1646 01:13:45,720 --> 01:13:48,490 So sodium is important for nervous system function. 1647 01:13:48,523 --> 01:13:50,058 That's why we did that test on you today. 1648 01:13:50,091 --> 01:13:53,061 POGUE: Luckily, my test results were normal. 1649 01:13:53,094 --> 01:13:56,231 I may have been sweating a lot out on that field, 1650 01:13:56,264 --> 01:13:59,301 but I sweat like a champ. 1651 01:13:59,334 --> 01:14:02,938 In total, the human body uses more than 25 elements 1652 01:14:02,971 --> 01:14:06,308 in ways and quantities that are unique to us. 1653 01:14:06,341 --> 01:14:09,144 Not every living thing does it the same way. 1654 01:14:09,177 --> 01:14:10,879 Take oxygen. 1655 01:14:10,912 --> 01:14:13,315 We love the stuff, can't live without it. 1656 01:14:13,348 --> 01:14:15,450 But it wasn't always this way. 1657 01:14:15,483 --> 01:14:19,221 When life began, conditions were very different on earth. 1658 01:14:19,254 --> 01:14:22,390 To begin with, there was no oxygen in the air. 1659 01:14:22,423 --> 01:14:26,595 To learn what put the "O" in our at-MO-sphere, 1660 01:14:26,628 --> 01:14:29,364 I've traveled to Yellowstone National Park. 1661 01:14:29,397 --> 01:14:32,367 David Ward has spent his professional life 1662 01:14:32,400 --> 01:14:35,770 studying the earth's most ancient organisms. 1663 01:14:35,803 --> 01:14:37,572 So, Dave, you're a microbe expert, I hear. 1664 01:14:37,605 --> 01:14:38,740 I am. 1665 01:14:38,773 --> 01:14:40,242 I am a microbial biologist. 1666 01:14:40,275 --> 01:14:41,977 I study microorganisms. 1667 01:14:42,010 --> 01:14:46,114 And, uh, I'm particularly interested in how they evolved. 1668 01:14:46,147 --> 01:14:47,782 Well, when you say the earliest ones, 1669 01:14:47,815 --> 01:14:49,150 how old are we talking about? 1670 01:14:49,183 --> 01:14:51,486 We're talking three, four billion years ago. 1671 01:14:51,519 --> 01:14:56,424 POGUE: Yellowstone sits atop the largest volcanic system 1672 01:14:56,457 --> 01:14:58,860 in North America. 1673 01:14:58,893 --> 01:15:01,930 That unusual geology creates hot, poisonous pools 1674 01:15:01,963 --> 01:15:06,868 that Ward sees as a window into the past. 1675 01:15:06,901 --> 01:15:08,169 You've installed a hot tub here. 1676 01:15:08,202 --> 01:15:10,305 POGUE: The park permits Ward to collect samples 1677 01:15:10,338 --> 01:15:12,574 from these protected environments. 1678 01:15:12,607 --> 01:15:13,608 So this is you. 1679 01:15:13,641 --> 01:15:14,543 This is your office, huh? 1680 01:15:14,576 --> 01:15:15,443 Yeah. 1681 01:15:15,476 --> 01:15:16,478 Now, you are not actually allowed 1682 01:15:16,511 --> 01:15:17,579 to be inside the rocks there. 1683 01:15:17,612 --> 01:15:19,981 You have to have special... a sampling permit. 1684 01:15:20,014 --> 01:15:21,783 You stay here, and I'll go on across. 1685 01:15:21,816 --> 01:15:23,985 Let me know if you need a bottle of water or something! 1686 01:15:24,018 --> 01:15:24,886 (chuckles) 1687 01:15:24,919 --> 01:15:26,521 What is that gizmo you have there? 1688 01:15:26,554 --> 01:15:30,058 This is a thermistor, takes temperature. 1689 01:15:30,091 --> 01:15:31,927 Oh, we call that a thermometer. 1690 01:15:31,960 --> 01:15:34,229 You know, scientists have to have fancy words for things. 1691 01:15:34,262 --> 01:15:36,431 POGUE: Scientists think that in order 1692 01:15:36,464 --> 01:15:38,433 to get the energy they needed to live, 1693 01:15:38,466 --> 01:15:40,735 some of the earliest forms of life 1694 01:15:40,768 --> 01:15:42,871 required extremely hot water 1695 01:15:42,904 --> 01:15:46,375 mixed with elements like hydrogen, sulfur and iron. 1696 01:15:49,577 --> 01:15:51,479 But as the planet cooled, 1697 01:15:51,512 --> 01:15:54,249 another ancient microorganism evolved and changed everything. 1698 01:15:54,282 --> 01:15:57,953 They are called cyanobacteria, 1699 01:15:57,986 --> 01:16:01,423 but we know them as blue-green algae. 1700 01:16:01,456 --> 01:16:04,693 They found a way to get their energy from light and water, 1701 01:16:04,726 --> 01:16:08,763 releasing oxygen as a byproduct, just like modern plants do. 1702 01:16:08,796 --> 01:16:12,000 The evolution of cyanobacteria set the stage 1703 01:16:12,033 --> 01:16:15,036 for all the plant and animal life that followed. 1704 01:16:15,069 --> 01:16:17,472 And in fact, you can see that clearly here. 1705 01:16:17,505 --> 01:16:19,841 You can see this orange to brown transition. 1706 01:16:19,874 --> 01:16:21,309 Yeah. 1707 01:16:21,342 --> 01:16:23,545 And, you know, this is one set of species, 1708 01:16:23,578 --> 01:16:27,248 and then there's another, and then finally this third. 1709 01:16:27,281 --> 01:16:28,817 POGUE: Dave Ward offers to introduce me 1710 01:16:28,850 --> 01:16:31,219 to one of my oldest living relatives 1711 01:16:31,252 --> 01:16:34,322 with the help of an ordinary drinking straw. 1712 01:16:34,355 --> 01:16:36,257 WARD: And we'll take a sample here. 1713 01:16:36,290 --> 01:16:38,627 This is the real high-tech part. 1714 01:16:38,660 --> 01:16:41,229 I use my high-tech soda straw. 1715 01:16:41,262 --> 01:16:42,797 (both laugh) 1716 01:16:42,830 --> 01:16:49,504 Just take aim and push the straw in, 1717 01:16:49,537 --> 01:16:51,906 and just immerse it into the liquid nitrogen. 1718 01:16:51,939 --> 01:16:53,975 Wow, snap-frozen for freshness, huh? 1719 01:16:54,008 --> 01:16:54,809 Yup. 1720 01:16:54,842 --> 01:16:56,177 POGUE: The different colors 1721 01:16:56,210 --> 01:16:58,480 are actually different species of microorganism. 1722 01:16:58,513 --> 01:17:02,817 Back at his lab, Ward prepares the sample. 1723 01:17:02,850 --> 01:17:03,785 There we go. 1724 01:17:03,818 --> 01:17:05,220 POGUE: Here in the layers, 1725 01:17:05,253 --> 01:17:07,756 we can see different species living together 1726 01:17:07,789 --> 01:17:11,593 separated by hundreds of millions of years of evolution. 1727 01:17:11,626 --> 01:17:14,963 The thin, greenish layer on the top is cyanobacteria, 1728 01:17:14,996 --> 01:17:16,998 situated at the best spot 1729 01:17:17,031 --> 01:17:21,236 to find light, water and carbon dioxide for growth. 1730 01:17:21,269 --> 01:17:26,341 And in the history of life, it's the cyanobacteria and us 1731 01:17:26,374 --> 01:17:28,143 that truly came out on top. 1732 01:17:28,176 --> 01:17:30,011 Take a peek here, Dave. 1733 01:17:30,044 --> 01:17:32,647 POGUE: As they spread out of the volcanic pools 1734 01:17:32,680 --> 01:17:34,382 and colonized the planet, 1735 01:17:34,415 --> 01:17:39,320 these tiny organisms pumped out more and more oxygen. 1736 01:17:39,353 --> 01:17:41,890 For a few hundred million years, 1737 01:17:41,923 --> 01:17:45,226 oxygen simply reacted with the metals in the earth's crust, 1738 01:17:45,259 --> 01:17:48,496 and the planet slowly rusted. 1739 01:17:48,529 --> 01:17:50,932 But eventually the oxygen began to build up in the atmosphere. 1740 01:17:50,965 --> 01:17:54,636 And those little bugs are still hard at work today. 1741 01:17:54,669 --> 01:17:57,305 WARD: These little critters that are making half of the oxygen 1742 01:17:57,338 --> 01:18:00,442 that all of the things requiring oxygen breathe today. 1743 01:18:00,475 --> 01:18:04,412 So they're still at work making all of this oxygen. 1744 01:18:04,445 --> 01:18:10,685 POGUE: These microbes changed the face of an entire planet. 1745 01:18:10,718 --> 01:18:12,854 But where did the elements of life, 1746 01:18:12,887 --> 01:18:16,958 and all the other elements, come from in the first place? 1747 01:18:16,991 --> 01:18:21,196 Let's start at the very beginning, with hydrogen. 1748 01:18:21,229 --> 01:18:24,099 One proton and one electron. 1749 01:18:24,132 --> 01:18:28,636 Around 90% of all the atoms in the universe are hydrogen, 1750 01:18:28,669 --> 01:18:32,207 and they were all made by the Big Bang 1751 01:18:32,240 --> 01:18:34,642 more than 13 billion years ago. 1752 01:18:34,675 --> 01:18:37,645 But where did things go from there? 1753 01:18:37,678 --> 01:18:41,649 The answer is in the stars, like our own sun, 1754 01:18:41,682 --> 01:18:43,852 a seething cauldron of hot gas 1755 01:18:43,885 --> 01:18:45,787 constantly turning hydrogen atoms 1756 01:18:45,820 --> 01:18:48,923 into element number two: helium. 1757 01:18:48,956 --> 01:18:50,959 It's a process called fusion. 1758 01:18:50,992 --> 01:18:53,595 And now scientists 1759 01:18:53,628 --> 01:18:55,697 at the National Ignition Facility in California 1760 01:18:55,730 --> 01:18:58,600 are actually trying to recreate that solar process 1761 01:18:58,633 --> 01:19:00,301 here on earth. 1762 01:19:00,334 --> 01:19:04,172 If they can make it practical-- and that's a big "if"-- 1763 01:19:04,205 --> 01:19:07,008 they could unlock a new source of limitless, clean energy. 1764 01:19:07,041 --> 01:19:10,178 ED MOSES: So the world is going to be using more energy. 1765 01:19:10,211 --> 01:19:12,580 POGUE: Ed Moses is a physicist who's leading the effort. 1766 01:19:12,613 --> 01:19:15,183 And his raw material is hydrogen, 1767 01:19:15,216 --> 01:19:18,386 the smallest and the oldest element in the universe. 1768 01:19:18,419 --> 01:19:20,522 MOSES: Around 30 seconds after the Big Bang, 1769 01:19:20,555 --> 01:19:22,757 all that hydrogen appeared. 1770 01:19:22,790 --> 01:19:23,691 From the Big Bang? 1771 01:19:23,724 --> 01:19:24,659 From the Big Bang. 1772 01:19:24,692 --> 01:19:26,327 It sort of has an infinite life. 1773 01:19:26,360 --> 01:19:29,531 So we, when we, you know, drink a glass of water, 1774 01:19:29,564 --> 01:19:31,599 are sampling the Big Bang. 1775 01:19:31,632 --> 01:19:34,068 POGUE: Fusion forces two hydrogen atoms 1776 01:19:34,101 --> 01:19:36,905 to merge into a single helium atom. 1777 01:19:36,938 --> 01:19:38,339 Pound for pound, 1778 01:19:38,372 --> 01:19:41,576 it's the most energetic reaction in the cosmos. 1779 01:19:41,609 --> 01:19:44,212 And that's what his facility would like to reproduce. 1780 01:19:44,245 --> 01:19:46,347 We crash them together, and what happens is 1781 01:19:46,380 --> 01:19:51,953 we turn mass into energy, just like Einstein told us. 1782 01:19:51,986 --> 01:19:54,756 POGUE: To do this, Ed's team focuses 1783 01:19:54,789 --> 01:19:58,760 192 of the world's most powerful laser beams 1784 01:19:58,793 --> 01:20:03,331 onto a bb-sized capsule containing hydrogen atoms. 1785 01:20:03,364 --> 01:20:05,533 This fuses them into helium atoms 1786 01:20:05,566 --> 01:20:10,505 and releases a 100-million- degree pulse of energy. 1787 01:20:10,538 --> 01:20:14,008 The goal is to create a sustained fusion reaction, 1788 01:20:14,041 --> 01:20:18,046 but right now it lasts only a billionth of a second. 1789 01:20:18,079 --> 01:20:20,748 Stars create helium throughout their long lives, 1790 01:20:20,781 --> 01:20:22,116 but in their old age, 1791 01:20:22,149 --> 01:20:25,520 they run low on hydrogen and begin to fuse helium, 1792 01:20:25,553 --> 01:20:28,857 creating larger and larger elements. 1793 01:20:28,890 --> 01:20:31,826 And you'll start walking up the periodic table, 1794 01:20:31,859 --> 01:20:34,362 making more and more elements. 1795 01:20:34,395 --> 01:20:35,763 First you made helium; 1796 01:20:35,796 --> 01:20:39,334 then you'll make lithium and beryllium and boron. 1797 01:20:39,367 --> 01:20:43,271 And you can do this all the way up to iron. 1798 01:20:43,304 --> 01:20:48,810 POGUE: By the time it's fusing iron, a star is in its death throes. 1799 01:20:48,843 --> 01:20:51,946 It begins to collapse, and if it's massive enough, 1800 01:20:51,979 --> 01:20:54,549 that collapse leads to a powerful explosion 1801 01:20:54,582 --> 01:20:58,386 called a supernova. 1802 01:20:58,419 --> 01:21:00,121 In that intense flash, 1803 01:21:00,154 --> 01:21:03,491 the supernova creates elements heavier than iron, 1804 01:21:03,524 --> 01:21:06,094 launching them all into the cosmos, 1805 01:21:06,127 --> 01:21:10,398 creating the raw materials of planets and of life. 1806 01:21:10,431 --> 01:21:13,368 And now we're using those raw materials 1807 01:21:13,401 --> 01:21:15,303 to shape our civilization, 1808 01:21:15,336 --> 01:21:18,573 with elements like silicon-- 1809 01:21:18,606 --> 01:21:21,509 14 protons, 14 electrons, 1810 01:21:21,542 --> 01:21:25,747 the second most abundant element in the earth's rocky crust. 1811 01:21:25,780 --> 01:21:29,284 A member of one of the smallest neighborhoods on the table, 1812 01:21:29,317 --> 01:21:31,719 the semiconductors. 1813 01:21:31,752 --> 01:21:33,488 When most people think of silicon, 1814 01:21:33,521 --> 01:21:36,424 they think of computer chips and the information age. 1815 01:21:36,457 --> 01:21:39,794 But its most familiar form is actually in this. 1816 01:21:41,562 --> 01:21:42,797 For more than 5,000 years, 1817 01:21:42,830 --> 01:21:47,869 silicon glass has brought light and beauty to our lives. 1818 01:21:47,902 --> 01:21:50,104 Today, scientists are re-engineering 1819 01:21:50,137 --> 01:21:53,708 this ancient material atom by atom 1820 01:21:53,741 --> 01:21:55,877 here at Corning in upstate New York. 1821 01:21:55,910 --> 01:21:57,345 PETER BOCKO: You know, David, 1822 01:21:57,378 --> 01:22:01,616 this place looks and sounds like a blacksmith shop, 1823 01:22:01,649 --> 01:22:03,718 but actually it's a scientific laboratory. 1824 01:22:03,751 --> 01:22:05,019 POGUE: They're fiddling around 1825 01:22:05,052 --> 01:22:06,387 with various combinations of elements, 1826 01:22:06,420 --> 01:22:06,420 seeing what kind of glass comes out. 1827 01:22:06,420 --> 01:22:08,256 That's right, yeah. 1828 01:22:08,289 --> 01:22:11,559 POGUE: They tell me it all starts with ordinary sand, 1829 01:22:11,592 --> 01:22:14,996 which is made of a combination of silicon and oxygen. 1830 01:22:15,029 --> 01:22:18,132 But sand is opaque, isn't it? 1831 01:22:18,165 --> 01:22:21,536 It turns out it's much more glasslike than I thought. 1832 01:22:21,569 --> 01:22:26,674 BOCKO: Under magnification, sand looks like little tiny glass jewels 1833 01:22:26,707 --> 01:22:29,010 that are essentially transparent. 1834 01:22:29,043 --> 01:22:30,778 POGUE: So the light's coming from underneath 1835 01:22:30,811 --> 01:22:32,947 these grains of sand and shining right through them? 1836 01:22:32,980 --> 01:22:35,516 Yep, and you know, it shows that it's transparent. 1837 01:22:35,549 --> 01:22:37,418 POGUE: That is so weird. 1838 01:22:37,451 --> 01:22:40,755 POGUE: Melting sand and then allowing it to cool 1839 01:22:40,788 --> 01:22:42,924 begins to turn it into glass. 1840 01:22:42,957 --> 01:22:44,759 Feels like thick, heavy vinyl. 1841 01:22:44,792 --> 01:22:47,595 POGUE: Glass is surprisingly strong. 1842 01:22:47,628 --> 01:22:50,164 It can withstand a lot of crushing force. 1843 01:22:50,197 --> 01:22:52,834 But it's also very brittle. 1844 01:22:52,867 --> 01:22:56,904 Is there any way to get around that weakness? 1845 01:22:56,937 --> 01:23:01,776 BOCKO: What the scientists do is they can tailor the glass 1846 01:23:01,809 --> 01:23:05,446 by adding other things other than the sand 1847 01:23:05,479 --> 01:23:08,716 to engineer the properties they want to into the glass. 1848 01:23:08,749 --> 01:23:11,652 Should I worry that my gloves are on fire? 1849 01:23:11,685 --> 01:23:14,555 POGUE: Changing the 5,000-year-old recipe for glass 1850 01:23:14,588 --> 01:23:17,558 has led to a new form they call Gorilla Glass, 1851 01:23:17,591 --> 01:23:21,229 and you can probably guess why they named it that. 1852 01:23:21,262 --> 01:23:22,597 Something that we call a drop test. 1853 01:23:22,630 --> 01:23:25,166 With the glass, uh, is in a frame, 1854 01:23:25,199 --> 01:23:27,935 like we have a piece of Gorilla Glass in this. 1855 01:23:27,968 --> 01:23:29,103 And the ball is dropped 1856 01:23:29,136 --> 01:23:30,271 from a height of one meter. 1857 01:23:30,304 --> 01:23:32,373 How thick is this piece of glass? 1858 01:23:32,406 --> 01:23:33,841 This is 0.7 millimeters. 1859 01:23:33,874 --> 01:23:34,876 Not even a millimeter? 1860 01:23:34,909 --> 01:23:36,010 Not even a millimeter thick. 1861 01:23:36,043 --> 01:23:36,944 We're going to drop four pounds on that? 1862 01:23:36,977 --> 01:23:37,845 That's right. 1863 01:23:37,878 --> 01:23:39,781 David, this is our hail gun. 1864 01:23:39,814 --> 01:23:43,584 It shoots a ball of ice at 60 to 70 miles an hour. 1865 01:23:43,617 --> 01:23:46,554 Ready, aim, hail! 1866 01:23:47,755 --> 01:23:51,592 So this is a sample of our special glass. 1867 01:23:51,625 --> 01:23:53,161 This is plastic, dude. 1868 01:23:53,194 --> 01:23:54,762 I can make a paper airplane out of this. 1869 01:23:54,795 --> 01:23:56,097 Yeah, yeah. 1870 01:23:59,266 --> 01:24:00,234 It didn't break. 1871 01:24:00,267 --> 01:24:02,236 Oh my gosh, it's going to fold it in half. 1872 01:24:02,269 --> 01:24:03,471 BOCKO: There's a lot of bend to it. 1873 01:24:03,504 --> 01:24:05,073 POGUE: Ready, aim, fire! 1874 01:24:05,106 --> 01:24:09,377 POGUE: The secret behind these weirdly durable forms of glass 1875 01:24:09,410 --> 01:24:12,113 is engineering on the atomic scale. 1876 01:24:12,146 --> 01:24:13,414 Sweet! 1877 01:24:13,447 --> 01:24:14,549 Clearly it worked. 1878 01:24:14,582 --> 01:24:16,451 The 70-mile-an-hour golf-ball-sized hail 1879 01:24:16,484 --> 01:24:18,119 did absolutely nothing to it. 1880 01:24:18,152 --> 01:24:21,122 The glassmakers have learned how to precisely place 1881 01:24:21,155 --> 01:24:23,257 minute amounts of metal atoms-- 1882 01:24:23,290 --> 01:24:26,127 like sodium, potassium, and aluminum-- 1883 01:24:26,160 --> 01:24:28,429 among the silicon atoms. 1884 01:24:28,462 --> 01:24:32,900 The result is hard yet flexible, and scratch resistant. 1885 01:24:32,933 --> 01:24:33,968 No! 1886 01:24:34,001 --> 01:24:35,703 But is it really glass? 1887 01:24:35,736 --> 01:24:37,605 You maintain that this is not, in fact, plastic, 1888 01:24:37,638 --> 01:24:37,638 that this is actually glass. 1889 01:24:37,638 --> 01:24:39,674 Mm-hmm, yup. 1890 01:24:39,707 --> 01:24:42,477 But yet very strong, within reason. 1891 01:24:42,510 --> 01:24:44,912 There is no such thing as an unbreakable glass. 1892 01:24:44,945 --> 01:24:44,945 It is a glass... 1893 01:24:44,945 --> 01:24:46,214 Oh! 1894 01:24:46,247 --> 01:24:46,247 Oh! 1895 01:24:46,247 --> 01:24:48,082 It is a glass... 1896 01:24:48,115 --> 01:24:50,418 So there are limits. 1897 01:24:50,451 --> 01:24:56,390 POGUE: These days we need strong glass for lenses, fiber optics 1898 01:24:56,423 --> 01:24:58,726 and screens of all sizes. 1899 01:24:58,759 --> 01:25:01,028 Hey, I'm on TV! 1900 01:25:01,061 --> 01:25:03,665 But silicon's work is not yet done. 1901 01:25:05,132 --> 01:25:09,137 Because underneath the glass, there's a lot more silicon 1902 01:25:09,170 --> 01:25:12,006 in the guts of all those electronics. 1903 01:25:12,039 --> 01:25:15,743 Silicon is the standard bearer of the semiconductors, 1904 01:25:15,776 --> 01:25:19,013 materials that change from free-flowing conductors 1905 01:25:19,046 --> 01:25:21,415 to nonflowing insulators 1906 01:25:21,448 --> 01:25:24,652 when we simply zap them with an electric current. 1907 01:25:24,685 --> 01:25:27,021 Switches made out of semiconductors 1908 01:25:27,054 --> 01:25:28,823 made computers possible. 1909 01:25:28,856 --> 01:25:31,225 But lately, when it comes to high tech, 1910 01:25:31,258 --> 01:25:33,694 there's a new family on the block: 1911 01:25:33,727 --> 01:25:36,297 the rare earths. 1912 01:25:36,330 --> 01:25:40,535 15 elements located near the bottom of the table. 1913 01:25:40,568 --> 01:25:42,637 And in my job as a technology writer, 1914 01:25:42,670 --> 01:25:44,872 there's one rare earth that interests me 1915 01:25:44,905 --> 01:25:45,873 more than any other: 1916 01:25:45,906 --> 01:25:47,775 neodymium. 1917 01:25:47,808 --> 01:25:52,146 It's the key ingredient in the world's strongest magnets. 1918 01:25:52,179 --> 01:25:54,849 They're critical to computers, cell phones, 1919 01:25:54,882 --> 01:26:00,288 hybrid cars, wind turbines, even tiny earbuds. 1920 01:26:00,321 --> 01:26:03,090 Without neodymium, we'd be sunk. 1921 01:26:03,123 --> 01:26:04,825 So that raises a question: 1922 01:26:04,858 --> 01:26:06,394 if they're in everything, 1923 01:26:06,427 --> 01:26:08,429 how come they're called "rare" earths? 1924 01:26:08,462 --> 01:26:12,133 The best place to find out is at the source. 1925 01:26:12,166 --> 01:26:16,671 John Burba is the chief technology officer at Molycorp. 1926 01:26:16,704 --> 01:26:19,273 He's overseeing a billion-dollar operation 1927 01:26:19,306 --> 01:26:24,712 to bring this 50-year-old mine into the 21st century. 1928 01:26:24,745 --> 01:26:26,914 So how many rare earth mines like this are there 1929 01:26:26,947 --> 01:26:27,982 in the United States? 1930 01:26:28,015 --> 01:26:29,016 One. 1931 01:26:29,049 --> 01:26:30,151 This is it? 1932 01:26:30,184 --> 01:26:31,719 This is it. 1933 01:26:31,752 --> 01:26:34,889 POGUE: One mine in the United States, 1934 01:26:34,922 --> 01:26:37,725 and John tells me it's not even fully operational yet. 1935 01:26:37,758 --> 01:26:39,227 So... 1936 01:26:39,260 --> 01:26:41,596 Where do rare earth minerals come from in the world? 1937 01:26:41,629 --> 01:26:43,998 The majority of it comes from China. 1938 01:26:44,031 --> 01:26:45,333 What kind of majority? 1939 01:26:45,366 --> 01:26:46,701 Like 98%. 1940 01:26:46,734 --> 01:26:48,703 98% of these minerals come from China? 1941 01:26:48,736 --> 01:26:49,904 Yes. 1942 01:26:49,937 --> 01:26:52,039 POGUE: Then he breaks the news 1943 01:26:52,072 --> 01:26:54,442 that the Chinese government has been limiting the export 1944 01:26:54,475 --> 01:26:57,912 of these strategically important elements. 1945 01:26:57,945 --> 01:26:59,814 Seems like the fate of the free world 1946 01:26:59,847 --> 01:27:01,148 could be riding on these rocks. 1947 01:27:01,181 --> 01:27:04,719 I'd better get some of my own while the gettin' is good. 1948 01:27:04,752 --> 01:27:06,921 But look for stuff like this. 1949 01:27:06,954 --> 01:27:09,123 We'll find out how good a geologist you are. 1950 01:27:09,156 --> 01:27:10,191 This reddish stuff? 1951 01:27:10,224 --> 01:27:11,359 Yeah. 1952 01:27:11,392 --> 01:27:12,526 This is a hunk of... what? 1953 01:27:12,559 --> 01:27:14,362 Barite, barium sulfate, 1954 01:27:14,395 --> 01:27:16,264 it's got some monazite in it. 1955 01:27:16,297 --> 01:27:17,832 They are naturally occurring crystals 1956 01:27:17,865 --> 01:27:18,766 that contain the elements. 1957 01:27:18,799 --> 01:27:20,635 So can I get a few more of these? 1958 01:27:20,668 --> 01:27:22,737 Yeah, just look for stuff that's similar. 1959 01:27:22,770 --> 01:27:23,871 You know what, John? 1960 01:27:23,904 --> 01:27:25,873 I like these two a lot. 1961 01:27:25,906 --> 01:27:27,208 I can't decide. 1962 01:27:27,241 --> 01:27:29,243 It's an either/ "ore" situation. 1963 01:27:29,276 --> 01:27:30,511 (laughs) 1964 01:27:30,544 --> 01:27:34,282 So how can I find out which elements are in this hunk? 1965 01:27:34,315 --> 01:27:38,219 POGUE: Molycorp's facility is still under construction. 1966 01:27:38,252 --> 01:27:40,354 So to find out what's in my rocks, 1967 01:27:40,387 --> 01:27:42,223 he suggests I take them to the world's 1968 01:27:42,256 --> 01:27:48,096 premier rare earth research lab in Ames, Iowa. 1969 01:27:50,230 --> 01:27:52,366 We'll be there soon. 1970 01:27:52,399 --> 01:27:54,435 I'm dying to know what I've got my hands on. 1971 01:27:54,468 --> 01:27:57,505 A pinch of praseodymium, perhaps? 1972 01:27:57,538 --> 01:27:59,507 A whole pound of holmium? 1973 01:27:59,540 --> 01:28:02,109 A thimbleful of thulium? 1974 01:28:02,142 --> 01:28:06,047 Or, dare I hope, magnet-making neodymium? 1975 01:28:06,080 --> 01:28:08,683 If anyone can extract all the precious neodymium 1976 01:28:08,716 --> 01:28:11,152 from my rocks, it's these guys. 1977 01:28:11,185 --> 01:28:12,753 David, I've been expecting you. 1978 01:28:12,786 --> 01:28:13,754 Good to see you. 1979 01:28:13,787 --> 01:28:14,722 David Pogue, how are you? 1980 01:28:14,755 --> 01:28:15,756 Yes, sir, yes, sir. 1981 01:28:15,789 --> 01:28:16,924 I see you brought the ore with you. 1982 01:28:16,957 --> 01:28:18,359 I brought this all the way from California. 1983 01:28:18,392 --> 01:28:19,260 All the way, all right! 1984 01:28:19,293 --> 01:28:20,328 I carried it by hand. 1985 01:28:20,361 --> 01:28:21,362 Uh-huh. 1986 01:28:21,395 --> 01:28:22,663 Because, you know, it's rare earth... 1987 01:28:22,696 --> 01:28:23,831 It's rare earth. 1988 01:28:23,864 --> 01:28:25,533 ...ore, and I didn't want anything to happen. 1989 01:28:25,566 --> 01:28:28,035 I didn't check it, I didn't put it in the overhead. 1990 01:28:28,068 --> 01:28:29,603 I think I've got some beautiful samples. 1991 01:28:29,636 --> 01:28:30,604 Oh, yeah. 1992 01:28:30,637 --> 01:28:31,706 There's this mine in California, 1993 01:28:31,739 --> 01:28:32,573 the largest one in the United States. 1994 01:28:32,606 --> 01:28:34,408 Look at the size of this one. 1995 01:28:34,441 --> 01:28:34,441 I think this one's my favorite. 1996 01:28:34,441 --> 01:28:36,344 Oh, yeah. 1997 01:28:36,377 --> 01:28:38,045 I thought if we brought it here to Ames Lab, 1998 01:28:38,078 --> 01:28:39,246 I thought you could, uh, 1999 01:28:39,279 --> 01:28:40,548 do a little chemical analysis on it and tell me... 2000 01:28:40,581 --> 01:28:41,615 We certainly can. 2001 01:28:41,648 --> 01:28:43,317 We'll take your favorite one and... 2002 01:28:43,350 --> 01:28:44,218 Watch out with the hammer. 2003 01:28:44,251 --> 01:28:45,553 What are you... ? 2004 01:28:45,586 --> 01:28:47,321 There we go, that's a good piece right there. 2005 01:28:47,354 --> 01:28:49,590 That's all we're going to need for the chemical analysis, 2006 01:28:49,623 --> 01:28:51,225 so the rest of this we'll just... 2007 01:28:51,258 --> 01:28:52,259 Yeah, but... 2008 01:28:52,292 --> 01:28:53,894 ...throw it right here in the trash. 2009 01:28:53,927 --> 01:28:55,830 But that's, that's rare... ah! 2010 01:28:55,863 --> 01:28:57,098 California! 2011 01:28:57,131 --> 01:29:00,501 POGUE: The truth is, rare earths are not rare. 2012 01:29:00,534 --> 01:29:03,671 They're just notoriously hard to separate. 2013 01:29:03,704 --> 01:29:06,240 The problem is, at an atomic level, 2014 01:29:06,273 --> 01:29:09,276 the rare earth elements all look weirdly alike. 2015 01:29:09,309 --> 01:29:11,912 Moving from element to element 2016 01:29:11,945 --> 01:29:14,014 along a row of the periodic table 2017 01:29:14,047 --> 01:29:18,719 adds a proton to the nucleus and an electron to the outer shell. 2018 01:29:18,752 --> 01:29:20,454 But in the rare earths, 2019 01:29:20,487 --> 01:29:24,191 the new electron disappears into an unfilled inner shell. 2020 01:29:24,224 --> 01:29:26,293 The result? 2021 01:29:26,326 --> 01:29:29,964 15 atoms that all have identical outer electron shells, 2022 01:29:29,997 --> 01:29:33,567 making them virtually indistinguishable chemically. 2023 01:29:33,600 --> 01:29:35,236 But what about my rocks? 2024 01:29:35,269 --> 01:29:37,104 Okay, David, the ore that you brought us, 2025 01:29:37,137 --> 01:29:38,372 the rocks that look like this, 2026 01:29:38,405 --> 01:29:41,075 we analyzed those, and this is what we found. 2027 01:29:41,108 --> 01:29:42,243 We found major components 2028 01:29:42,276 --> 01:29:46,680 of cerium, lanthanum and praseodymium. 2029 01:29:46,713 --> 01:29:48,282 POGUE: But no neodymium. 2030 01:29:48,315 --> 01:29:51,619 Apparently, my rocks are neo free. 2031 01:29:51,652 --> 01:29:53,587 But there was some good news. 2032 01:29:53,620 --> 01:29:58,526 The ore I brought in contained a whopping 20% rare earth oxide. 2033 01:29:58,559 --> 01:30:01,228 Molycorp may soon be able 2034 01:30:01,261 --> 01:30:05,933 to take a big bite out of China's near monopoly. 2035 01:30:05,966 --> 01:30:08,469 Before I head out, though, 2036 01:30:08,502 --> 01:30:10,838 there's one more lab I'm determined to visit. 2037 01:30:10,871 --> 01:30:13,541 So David, would you be interested in seeing 2038 01:30:13,574 --> 01:30:15,309 a rare earth magnet? 2039 01:30:15,342 --> 01:30:18,279 POGUE: Paul is one of the lab's top magnet guys. 2040 01:30:18,312 --> 01:30:20,481 This is a rare earth magnet. 2041 01:30:20,514 --> 01:30:22,850 This is actually neodymium, iron and boron. 2042 01:30:22,883 --> 01:30:25,419 This is about 150 grams 2043 01:30:25,452 --> 01:30:28,756 of the world's highest purity neodymium. 2044 01:30:28,789 --> 01:30:32,092 POGUE: Neodymium magnets are a bit of a misnomer. 2045 01:30:32,125 --> 01:30:35,696 They're really iron magnets with a pinch of neodymium added 2046 01:30:35,729 --> 01:30:38,766 like a powerful spice to make them stronger, 2047 01:30:38,799 --> 01:30:43,571 plus a few boron atoms to help hold everything in place. 2048 01:30:43,604 --> 01:30:44,738 You grow these? 2049 01:30:44,771 --> 01:30:46,607 You don't dig these out of the ore somehow? 2050 01:30:46,640 --> 01:30:48,309 No, no, no, these don't exist in nature. 2051 01:30:48,342 --> 01:30:50,845 These are things that we have to combine and cook 2052 01:30:50,878 --> 01:30:52,746 in the same way that huevos rancheros 2053 01:30:52,779 --> 01:30:54,148 doesn't exist in nature. 2054 01:30:54,181 --> 01:30:55,316 It has to be put together. 2055 01:30:55,349 --> 01:30:58,252 POGUE: Paul's lab is like a dieter's kitchen, 2056 01:30:58,285 --> 01:31:01,922 satisfying a hunger for powerful magnetic crystals 2057 01:31:01,955 --> 01:31:05,960 while reducing the amount of neodymium needed in the recipe. 2058 01:31:05,993 --> 01:31:09,530 And he's just about to whip up a fresh batch. 2059 01:31:09,563 --> 01:31:12,633 The main ingredient is ordinary iron. 2060 01:31:12,666 --> 01:31:13,934 Iron makes magnets... 2061 01:31:13,967 --> 01:31:15,302 CANFIELD: There you go! 2062 01:31:15,335 --> 01:31:17,638 ...but adding neodymium makes magnets on steroids. 2063 01:31:17,671 --> 01:31:19,173 Here's how you make a magnet. 2064 01:31:19,206 --> 01:31:21,642 First, all the solid ingredients 2065 01:31:21,675 --> 01:31:25,412 are sealed into a quartz tube to be melted together. 2066 01:31:25,445 --> 01:31:27,882 David Pogue: Scientist! 2067 01:31:27,915 --> 01:31:30,251 After some time in the furnace, 2068 01:31:30,284 --> 01:31:33,821 tiny magnetic crystals have formed in the melted iron. 2069 01:31:33,854 --> 01:31:35,890 2,000 degree... oh, my gosh! 2070 01:31:35,923 --> 01:31:37,558 It's like threading a needle! 2071 01:31:37,591 --> 01:31:40,928 The next step is to separate the solids from the liquid. 2072 01:31:40,961 --> 01:31:43,664 One, two, three, dump it in, slam the lid. 2073 01:31:43,697 --> 01:31:46,367 They put the centrifuge on the floor for safety 2074 01:31:46,400 --> 01:31:49,336 in case anything goes wrong with the super-hot vial. 2075 01:31:49,369 --> 01:31:50,504 We turn it off. 2076 01:31:50,537 --> 01:31:52,506 That lets you open it up. 2077 01:31:52,539 --> 01:31:55,976 And we can take it out. 2078 01:31:56,009 --> 01:31:58,913 We have single crystals of the neodymium iron boron 2079 01:31:58,946 --> 01:32:00,981 separated from the extra liquid, 2080 01:32:01,014 --> 01:32:04,952 which the centrifuge separated with the ten to 100 G's. 2081 01:32:04,985 --> 01:32:07,488 POGUE: The result of all this cooking and spinning? 2082 01:32:07,521 --> 01:32:12,092 A powerful magnet that uses less neodymium, we hope. 2083 01:32:12,125 --> 01:32:13,627 It sounds like you're saying 2084 01:32:13,660 --> 01:32:15,729 you're trying to use as little of the rare earth as possible. 2085 01:32:15,762 --> 01:32:16,730 Absolutely. 2086 01:32:16,763 --> 01:32:17,998 Why? 2087 01:32:18,031 --> 01:32:19,800 'Cause I thought rare earths aren't really that rare. 2088 01:32:19,833 --> 01:32:22,736 The rare earths are not rare, but they're hard to separate. 2089 01:32:22,769 --> 01:32:24,972 And that's part of the expense. 2090 01:32:25,005 --> 01:32:28,609 POGUE: Even with Paul's help, it looks like rare earths 2091 01:32:28,642 --> 01:32:32,713 are going to remain in short supply, at least for now. 2092 01:32:32,746 --> 01:32:34,782 Partly because scientists continue to find 2093 01:32:34,815 --> 01:32:38,385 surprising new ways to use these strange metals. 2094 01:32:38,418 --> 01:32:41,922 Like marine biologist and conservationist Patrick Rice. 2095 01:32:41,955 --> 01:32:44,258 If he has anything to say about it, 2096 01:32:44,291 --> 01:32:48,262 rare earths may be coming soon to a fish hook near you. 2097 01:32:48,295 --> 01:32:49,930 Ah, is this your little kiddie pool 2098 01:32:49,963 --> 01:32:51,398 where you bring the children to swim? 2099 01:32:51,431 --> 01:32:53,767 This is our little tank here where we have, um, 2100 01:32:53,800 --> 01:32:54,969 a couple little bonnet head sharks 2101 01:32:55,002 --> 01:32:57,571 and a little nurse shark in here. 2102 01:32:57,604 --> 01:33:00,307 POGUE: Rice was searching for the next great shark repellent 2103 01:33:00,340 --> 01:33:02,276 when he made an accidental discovery 2104 01:33:02,309 --> 01:33:06,513 that looks like it'll be good news for both man and fish. 2105 01:33:06,546 --> 01:33:09,016 RICE: We had sharks in a tank like this, 2106 01:33:09,049 --> 01:33:10,684 and a pump broke on one of our tanks, 2107 01:33:10,717 --> 01:33:12,186 and so we were playing with these magnets 2108 01:33:12,219 --> 01:33:13,654 and we put the magnets down by the tank 2109 01:33:13,687 --> 01:33:15,089 to go fix the pump, 2110 01:33:15,122 --> 01:33:18,225 and when we put the magnet by the tank, the sharks took off. 2111 01:33:18,258 --> 01:33:21,095 POGUE: Somehow, the sharks inside the tank 2112 01:33:21,128 --> 01:33:24,064 sensed the presence of magnets outside the tank, 2113 01:33:24,097 --> 01:33:26,667 and when they did, they voted with their fins. 2114 01:33:29,036 --> 01:33:32,172 Patrick offers to demonstrate the weird repulsive effect. 2115 01:33:32,205 --> 01:33:36,110 He hands me a case of super-strong magnets. 2116 01:33:36,143 --> 01:33:39,880 So this is full of actual regular, old refrigerator... 2117 01:33:39,913 --> 01:33:42,116 Oh, yeah, more than refrigerator magnets. 2118 01:33:42,149 --> 01:33:43,884 That's right, that's right. 2119 01:33:43,917 --> 01:33:46,654 And you're saying that this will somehow repel the sharks? 2120 01:33:46,687 --> 01:33:49,990 Okay, here comes a little guy. 2121 01:33:50,023 --> 01:33:51,325 That's a little nurse shark, it might work for him. 2122 01:33:51,358 --> 01:33:52,760 Tell me when he gets over here. 2123 01:33:52,793 --> 01:33:54,361 All right, three, two, one. 2124 01:33:54,394 --> 01:33:57,231 Oh, my gosh, it's like you dropped that thing on his head. 2125 01:33:57,264 --> 01:33:58,432 RICE: Yeah, you saw it, huh? 2126 01:33:58,465 --> 01:34:00,167 Yeah, he's like, dun dun dun, wow! 2127 01:34:00,200 --> 01:34:01,268 He whipped out of there. 2128 01:34:01,301 --> 01:34:02,269 Right, exactly. 2129 01:34:02,302 --> 01:34:04,571 POGUE: The shark can't see the magnet, 2130 01:34:04,604 --> 01:34:06,674 but it obviously feels the effect. 2131 01:34:06,707 --> 01:34:07,708 And it's not happy. 2132 01:34:07,741 --> 01:34:11,612 One, two, three, now. 2133 01:34:11,645 --> 01:34:13,013 Boom, you got him. 2134 01:34:13,046 --> 01:34:13,046 Really? 2135 01:34:13,046 --> 01:34:14,715 Yeah, you got him. 2136 01:34:14,748 --> 01:34:14,748 That's crazy. 2137 01:34:14,748 --> 01:34:16,083 Isn't it amazing? 2138 01:34:16,116 --> 01:34:18,952 POGUE: Patrick thought he could somehow use this effect 2139 01:34:18,985 --> 01:34:22,456 to save sharks from being inadvertently caught 2140 01:34:22,489 --> 01:34:24,158 by commercial fishermen. 2141 01:34:24,191 --> 01:34:27,995 But there was, so to speak, a catch. 2142 01:34:28,028 --> 01:34:30,397 We put the magnet right above the hook on the line. 2143 01:34:30,430 --> 01:34:32,433 And what was happening was the hooks were swinging around 2144 01:34:32,466 --> 01:34:33,734 and getting caught on the magnets. 2145 01:34:33,767 --> 01:34:34,635 That would happen. 2146 01:34:34,668 --> 01:34:35,869 So it wasn't catching any sharks, 2147 01:34:35,902 --> 01:34:37,805 but it wasn't catching anything else either. 2148 01:34:37,838 --> 01:34:40,374 POGUE: But he wasn't willing to give up. 2149 01:34:40,407 --> 01:34:43,243 He decided he needed to find the weakest possible magnet 2150 01:34:43,276 --> 01:34:46,380 that would still affect sharks. 2151 01:34:46,413 --> 01:34:48,716 The first step was to create a baseline for comparison 2152 01:34:48,749 --> 01:34:52,352 by exposing sharks to nonmagnetic materials. 2153 01:34:52,385 --> 01:34:55,522 He offers to recreate his experiment. 2154 01:34:55,555 --> 01:34:57,157 You know, I don't have insurance for this. 2155 01:34:57,190 --> 01:34:59,159 Be careful. It might be slippery. 2156 01:34:59,192 --> 01:35:00,928 You're warning me about the slipperiness? 2157 01:35:00,961 --> 01:35:02,863 Dude, there's three sharks in here! 2158 01:35:02,896 --> 01:35:04,732 RICE: No, but they're nice. 2159 01:35:04,765 --> 01:35:07,301 Okay, I just want to say, for the record, that I'm standing 2160 01:35:07,334 --> 01:35:08,736 in a tank full of sharks. 2161 01:35:08,769 --> 01:35:09,870 That's correct. 2162 01:35:09,903 --> 01:35:12,640 This is like Jaws 7: The Kiddie Pool. 2163 01:35:14,341 --> 01:35:17,277 POGUE: Step one: capture a shark. 2164 01:35:17,310 --> 01:35:19,813 Dude, you just caught a shark with your bare hands! 2165 01:35:19,846 --> 01:35:22,950 POGUE: Then flip the shark upside down, 2166 01:35:22,983 --> 01:35:27,020 which induces a trance state called tonic immobility. 2167 01:35:27,053 --> 01:35:28,388 Once the shark is calm, 2168 01:35:28,421 --> 01:35:30,657 we test its reaction 2169 01:35:30,690 --> 01:35:33,360 to a piece of ordinary, nonmagnetic lead. 2170 01:35:33,393 --> 01:35:36,063 Would you like me to just conk her on the head with this? 2171 01:35:36,096 --> 01:35:37,531 Cover up her eyes. 2172 01:35:37,564 --> 01:35:39,867 So it's not a visual thing. 2173 01:35:39,900 --> 01:35:43,403 POGUE: Using a shield to make sure that the shark can't see the metal, 2174 01:35:43,436 --> 01:35:45,372 I bring it close. 2175 01:35:45,405 --> 01:35:46,974 No reaction. 2176 01:35:47,007 --> 01:35:47,808 None at all. 2177 01:35:47,841 --> 01:35:48,976 POGUE: As expected. 2178 01:35:49,009 --> 01:35:51,779 Next, a nonmagnetic piece of samarium, 2179 01:35:51,812 --> 01:35:53,614 a rare earth element. 2180 01:35:53,647 --> 01:35:56,416 The expectation was that because it's nonmagnetic, 2181 01:35:56,449 --> 01:35:57,985 there would be no reaction. 2182 01:35:58,018 --> 01:35:59,787 Oh, man! 2183 01:35:59,820 --> 01:36:01,355 She didn't like that at all. 2184 01:36:01,388 --> 01:36:02,956 This is like kryptonite for sharks! 2185 01:36:02,989 --> 01:36:03,891 Yes, it is. 2186 01:36:03,924 --> 01:36:04,858 Wow, that's amazing. 2187 01:36:04,891 --> 01:36:06,994 It just woke her up and drove her crazy. 2188 01:36:07,027 --> 01:36:08,195 Yep. 2189 01:36:08,228 --> 01:36:11,465 So the idea is you could make what out of this stuff? 2190 01:36:11,498 --> 01:36:13,066 Well, the idea is that it's not magnetic, 2191 01:36:13,099 --> 01:36:14,935 so we could potentially incorporate it 2192 01:36:14,968 --> 01:36:16,069 into a fishing hook. 2193 01:36:16,102 --> 01:36:19,306 And then you got something that repels sharks 2194 01:36:19,339 --> 01:36:22,309 but doesn't have the magnetic properties, 2195 01:36:22,342 --> 01:36:25,479 so it won't tangle the gear and stuff like that. 2196 01:36:25,512 --> 01:36:27,748 POGUE: The discovery that nonmagnetic rare earths 2197 01:36:27,781 --> 01:36:31,718 have a repellent effect on sharks was a complete fluke. 2198 01:36:31,751 --> 01:36:34,788 And it works with other rare earth metals as well. 2199 01:36:34,821 --> 01:36:36,690 But why? 2200 01:36:36,723 --> 01:36:40,928 What do sharks have against these particular elements? 2201 01:36:40,961 --> 01:36:42,529 We believe it's creating a little electric shock. 2202 01:36:42,562 --> 01:36:43,797 A little electric shock? 2203 01:36:43,830 --> 01:36:44,898 Yeah, yeah. 2204 01:36:44,931 --> 01:36:45,866 A shark shock. 2205 01:36:45,899 --> 01:36:47,201 A shark shocker. 2206 01:36:47,234 --> 01:36:48,402 POGUE: Patrick demonstrates using a beaker of seawater, 2207 01:36:48,435 --> 01:36:53,507 a piece of samarium, a voltmeter and an actual shark fin. 2208 01:36:53,540 --> 01:36:55,342 (singing Jaws theme): Bum bum, bum bum, bum bum, bum bum... 2209 01:36:55,375 --> 01:36:57,311 POGUE: When he submerges the samarium 2210 01:36:57,344 --> 01:36:59,179 and the shark fin in the seawater, 2211 01:36:59,212 --> 01:37:01,949 an electric current flows. 2212 01:37:01,982 --> 01:37:03,250 Whoa! 2213 01:37:03,283 --> 01:37:04,184 Oh, my God. 2214 01:37:04,217 --> 01:37:05,485 That's almost a D-size battery. 2215 01:37:05,518 --> 01:37:07,721 Did we just make, in effect, a battery? 2216 01:37:07,754 --> 01:37:08,789 Correct. 2217 01:37:08,822 --> 01:37:12,059 POGUE: As a group, the rare earths 2218 01:37:12,092 --> 01:37:15,362 give up their outer electrons very easily. 2219 01:37:15,395 --> 01:37:16,597 In the salt water, 2220 01:37:16,630 --> 01:37:18,999 samarium atoms break free of the metal disk 2221 01:37:19,032 --> 01:37:22,169 and give up one or more of their outer electrons. 2222 01:37:22,202 --> 01:37:25,005 The atoms become positively charged 2223 01:37:25,038 --> 01:37:27,207 and are attracted to the shark fin, 2224 01:37:27,240 --> 01:37:29,276 which, like many biological materials, 2225 01:37:29,309 --> 01:37:32,179 has a slight negative charge. 2226 01:37:32,212 --> 01:37:34,047 The movement of the charged atoms 2227 01:37:34,080 --> 01:37:35,415 creates an electric current. 2228 01:37:35,448 --> 01:37:37,417 Wow, that's some real juice flowing in there. 2229 01:37:37,450 --> 01:37:39,152 Just like in a battery. 2230 01:37:39,185 --> 01:37:40,787 It's a complete closed circuit, 2231 01:37:40,820 --> 01:37:42,055 and the voltmeter's measuring that. 2232 01:37:42,088 --> 01:37:42,088 That's pretty amazing. 2233 01:37:42,088 --> 01:37:43,590 Yeah. 2234 01:37:43,623 --> 01:37:47,494 POGUE: But is the effect actually strong enough 2235 01:37:47,527 --> 01:37:49,563 to put a shark off its meal? 2236 01:37:49,596 --> 01:37:50,964 So we've just done our little test... 2237 01:37:50,997 --> 01:37:52,633 POGUE: There's one final experiment we can run to find out. 2238 01:37:52,666 --> 01:37:54,301 What we're going to do now... 2239 01:37:54,334 --> 01:37:55,602 Whoa! 2240 01:37:55,635 --> 01:37:56,503 Thank you. 2241 01:37:56,536 --> 01:37:57,504 You're welcome. 2242 01:37:57,537 --> 01:37:58,939 That was just for the blooper reel. 2243 01:37:58,972 --> 01:38:00,340 We like to get some material... 2244 01:38:00,373 --> 01:38:02,309 POGUE: As I was saying, 2245 01:38:02,342 --> 01:38:06,413 there's one final experiment we can run to find out. 2246 01:38:06,446 --> 01:38:08,115 What we're going to do here is 2247 01:38:08,148 --> 01:38:10,517 a little experiment we've never done before. 2248 01:38:10,550 --> 01:38:13,020 You haven't done this before? 2249 01:38:13,053 --> 01:38:14,354 We haven't done this before. 2250 01:38:14,387 --> 01:38:16,423 You waited until there was a national TV camera rolling? 2251 01:38:16,456 --> 01:38:18,292 (whistling) 2252 01:38:18,325 --> 01:38:20,527 POGUE: There's a nine-foot lemon shark in this lagoon, 2253 01:38:20,560 --> 01:38:22,729 and it's lunchtime. 2254 01:38:22,762 --> 01:38:24,965 Now for the test. 2255 01:38:24,998 --> 01:38:28,435 We're going to suspend two identical pieces of tuna. 2256 01:38:28,468 --> 01:38:30,604 One will hang below a piece of lead-- 2257 01:38:30,637 --> 01:38:32,005 that's our control-- 2258 01:38:32,038 --> 01:38:35,075 the other under a piece of samarium. 2259 01:38:35,108 --> 01:38:36,076 You go ahead and put it out there. 2260 01:38:36,109 --> 01:38:36,677 Really? 2261 01:38:36,710 --> 01:38:37,411 Yup. 2262 01:38:37,444 --> 01:38:38,378 Lower her down. 2263 01:38:38,411 --> 01:38:39,613 POGUE: If the test is successful, 2264 01:38:39,646 --> 01:38:42,482 the shark should avoid the samarium-tainted meal, 2265 01:38:42,515 --> 01:38:45,452 but not the food near the lead. 2266 01:38:45,485 --> 01:38:46,887 RICE: Here she comes. 2267 01:38:46,920 --> 01:38:48,522 POGUE: Oh, she didn't like it at all. 2268 01:38:48,555 --> 01:38:50,590 She was aiming right at it and she was like, ugh! 2269 01:38:50,623 --> 01:38:52,159 RICE: That was an excellent response. 2270 01:38:52,192 --> 01:38:55,229 Notice the other fish-- it doesn't have any effect on them. 2271 01:38:56,930 --> 01:38:59,066 Okay, wait a minute, now she's going for the lead. 2272 01:38:59,099 --> 01:39:01,635 RICE: So there's the control. 2273 01:39:01,668 --> 01:39:03,170 POGUE: And she loves the lead one! 2274 01:39:03,203 --> 01:39:06,873 RICE: No problem on the control, so that's awesome. 2275 01:39:06,906 --> 01:39:09,343 POGUE: Since making this remarkable discovery, 2276 01:39:09,376 --> 01:39:11,678 Patrick has experimented with designs 2277 01:39:11,711 --> 01:39:13,347 for shark-repelling fishing hooks, 2278 01:39:13,380 --> 01:39:16,416 and he's seen some promising results. 2279 01:39:16,449 --> 01:39:18,518 The last experiment we did, we put out 46,000 hooks 2280 01:39:18,551 --> 01:39:20,320 and we reduced shark by-catch by 27%. 2281 01:39:20,353 --> 01:39:22,823 POGUE: Get your fresh chum here! 2282 01:39:22,856 --> 01:39:25,058 POGUE: Shark zapping is just the latest entry 2283 01:39:25,091 --> 01:39:28,395 in the growing list of curious rare earth abilities. 2284 01:39:28,428 --> 01:39:32,833 But perhaps the real shocker is that these 15 elements 2285 01:39:32,866 --> 01:39:35,202 were so long misunderstood, 2286 01:39:35,235 --> 01:39:39,806 their identities masked by their identical outer electron shells. 2287 01:39:39,839 --> 01:39:43,844 But those aren't the only atoms hiding from view. 2288 01:39:43,877 --> 01:39:46,279 Scientists now know that most elements 2289 01:39:46,312 --> 01:39:48,382 come in more than one version. 2290 01:39:48,415 --> 01:39:51,718 The different versions are called isotopes. 2291 01:39:51,751 --> 01:39:55,322 Consider carbon, the backbone of life. 2292 01:39:55,355 --> 01:39:58,692 It has three natural isotopes, or versions. 2293 01:39:58,725 --> 01:40:01,762 Each has six protons and six electrons-- 2294 01:40:01,795 --> 01:40:03,930 that's what makes them all carbon. 2295 01:40:03,963 --> 01:40:05,732 The difference between them is 2296 01:40:05,765 --> 01:40:07,968 the number of neutrons in the nucleus. 2297 01:40:08,001 --> 01:40:10,771 Neutrons are electrically neutral particles 2298 01:40:10,804 --> 01:40:13,707 that act as glue to hold atoms together. 2299 01:40:13,740 --> 01:40:18,278 What we think of as normal carbon is called carbon-12, 2300 01:40:18,311 --> 01:40:21,748 six protons plus six neutrons. 2301 01:40:21,781 --> 01:40:25,886 But about one percent of carbon atoms have an extra neutron, 2302 01:40:25,919 --> 01:40:27,587 giving them seven. 2303 01:40:27,620 --> 01:40:30,390 They're called carbon-13. 2304 01:40:30,423 --> 01:40:33,960 And about one in a million have eight neutrons-- 2305 01:40:33,993 --> 01:40:36,163 that's carbon-14. 2306 01:40:36,196 --> 01:40:38,432 And that rare version of carbon 2307 01:40:38,465 --> 01:40:42,436 has proven to be a crucial tool for unlocking the past. 2308 01:40:45,038 --> 01:40:48,875 Several times a year, scientist Scott Stine travels 2309 01:40:48,908 --> 01:40:52,679 to the shores of Mono Lake near Yosemite National Park. 2310 01:40:52,712 --> 01:40:55,215 So this, then, is Mono Lake. 2311 01:40:55,248 --> 01:40:56,450 Mono Lake, yeah. 2312 01:40:56,483 --> 01:40:59,219 Right here at the foot of the Sierra Nevada. 2313 01:40:59,252 --> 01:41:02,989 POGUE: He's studying the long history of droughts in California, 2314 01:41:03,022 --> 01:41:05,292 trying to determine how frequently they occur 2315 01:41:05,325 --> 01:41:07,594 and how long they last. 2316 01:41:07,627 --> 01:41:11,198 Over the millennia, the water level has risen and fallen 2317 01:41:11,231 --> 01:41:14,768 as the area has cycled between wet periods and dry times. 2318 01:41:14,801 --> 01:41:17,704 So that sandy area should be the level? 2319 01:41:17,737 --> 01:41:19,806 STINE: During times when the climate was dry, 2320 01:41:19,839 --> 01:41:22,375 Mono Lake dropped down, exposed the shore lands 2321 01:41:22,408 --> 01:41:24,878 and allowed trees and shrubs to grow. 2322 01:41:24,911 --> 01:41:28,381 POGUE: When the dry periods ended and the water level rose, 2323 01:41:28,414 --> 01:41:32,519 the trees drowned, marking the end of the droughts. 2324 01:41:32,552 --> 01:41:35,255 Since then, the remains of those trees 2325 01:41:35,288 --> 01:41:39,226 have been well-preserved by the arid climate. 2326 01:41:39,259 --> 01:41:41,995 These droughts were long persistent. 2327 01:41:42,028 --> 01:41:44,197 POGUE: To determine how long ago these droughts occurred, 2328 01:41:44,230 --> 01:41:48,435 Scott is using carbon-14 to date the trees. 2329 01:41:48,468 --> 01:41:51,538 Unlike the other natural isotopes of carbon, 2330 01:41:51,571 --> 01:41:54,808 carbon-14 is unstable. 2331 01:41:54,841 --> 01:41:58,044 Over time, its atoms begin to deteriorate. 2332 01:41:58,077 --> 01:42:00,847 One of its neutrons turns into a proton 2333 01:42:00,880 --> 01:42:03,316 and spits out an electron. 2334 01:42:03,349 --> 01:42:06,219 Now with seven protons instead of six, 2335 01:42:06,252 --> 01:42:09,055 it's turned into nitrogen. 2336 01:42:09,088 --> 01:42:11,925 That process is called radioactive decay, 2337 01:42:11,958 --> 01:42:14,861 and scientists know exactly how long it will take 2338 01:42:14,894 --> 01:42:20,066 for half of any amount of carbon-14 to decay away. 2339 01:42:20,099 --> 01:42:24,104 Scientists call that time its half-life. 2340 01:42:24,137 --> 01:42:27,107 Living things constantly replenish 2341 01:42:27,140 --> 01:42:28,742 the carbon in their bodies-- 2342 01:42:28,775 --> 01:42:32,112 animals from food, 2343 01:42:32,145 --> 01:42:34,181 plants from the atmosphere. 2344 01:42:34,214 --> 01:42:37,450 But after death, that process stops. 2345 01:42:37,483 --> 01:42:40,420 The amount of carbon-12 stays the same, 2346 01:42:40,453 --> 01:42:45,592 but the carbon-14 decays away at a constant rate, 2347 01:42:45,625 --> 01:42:49,362 making carbon-14 a ticking atomic clock. 2348 01:42:49,395 --> 01:42:52,365 To know how long ago this ancient tree died, 2349 01:42:52,398 --> 01:42:56,703 we just need to count the carbon atoms in a small sample. 2350 01:42:56,736 --> 01:42:58,138 Piece of cake! 2351 01:42:58,171 --> 01:42:59,472 If you're this guy. 2352 01:42:59,505 --> 01:43:02,209 Now, these are fragments of the tree stumps at Mono Lake, 2353 01:43:02,242 --> 01:43:05,545 and I understand that you are the master of carbon dating. 2354 01:43:05,578 --> 01:43:09,683 POGUE: Physicist Tom Brown works in the carbon-dating program 2355 01:43:09,716 --> 01:43:12,352 at Lawrence Livermore National Laboratory. 2356 01:43:12,385 --> 01:43:13,687 In fact, if I'm not mistaken, 2357 01:43:13,720 --> 01:43:15,922 carbon dating actually preexisted 2358 01:43:15,955 --> 01:43:17,324 before Internet dating. 2359 01:43:17,357 --> 01:43:18,858 Very much. 2360 01:43:18,891 --> 01:43:24,798 POGUE: Carbon-14 can be used to date samples up to 40,000 years old. 2361 01:43:24,831 --> 01:43:27,400 It's been used to find the ages of many Egyptian mummies 2362 01:43:27,433 --> 01:43:31,004 and other ancient artifacts. 2363 01:43:31,037 --> 01:43:34,241 So how does wood fare with carbon dating? 2364 01:43:34,274 --> 01:43:36,243 Intact wood is very good material to date. 2365 01:43:36,276 --> 01:43:39,946 It retains the carbon from when that material died 2366 01:43:39,979 --> 01:43:42,148 and we're able to extract and purify it 2367 01:43:42,181 --> 01:43:44,918 and get a really good material for dating. 2368 01:43:44,951 --> 01:43:47,454 POGUE: Tom needs only a small amount of wood. 2369 01:43:47,487 --> 01:43:50,190 Even this tiny sample is overkill. 2370 01:43:50,223 --> 01:43:54,928 A lab technician cleans it and reduces it to a fine powder. 2371 01:43:54,961 --> 01:43:58,965 Oh, man, this huge thing? 2372 01:43:58,998 --> 01:44:01,568 This is your Carbon-Dater-Matic 3000? 2373 01:44:01,601 --> 01:44:05,171 POGUE: The actual counting of the atoms takes place here, 2374 01:44:05,204 --> 01:44:07,707 in the carbon-dating accelerator. 2375 01:44:07,740 --> 01:44:10,877 I see you bought the camping version. 2376 01:44:10,910 --> 01:44:12,846 BROWN: We have our one milligram of carbon from the woodchip sample 2377 01:44:12,879 --> 01:44:15,215 basically in that hole. 2378 01:44:15,248 --> 01:44:16,483 In that tiny little hole? 2379 01:44:16,516 --> 01:44:18,051 That's where the one milligram of carbon is 2380 01:44:18,084 --> 01:44:19,085 from that sample. 2381 01:44:19,118 --> 01:44:20,353 Not a lot of wood chips. 2382 01:44:20,386 --> 01:44:24,691 We put about 64 of these holders in one of these wheels. 2383 01:44:24,724 --> 01:44:26,059 POGUE: The accelerator applies 2384 01:44:26,092 --> 01:44:28,495 a powerful electric charge to the atoms-- 2385 01:44:28,528 --> 01:44:30,030 basically lightning-- 2386 01:44:30,063 --> 01:44:32,932 giving them the speed and energy they need 2387 01:44:32,965 --> 01:44:35,669 to hit a detector with enough force to be counted. 2388 01:44:35,702 --> 01:44:37,771 BROWN: The ratio of the carbon-14 ions 2389 01:44:37,804 --> 01:44:41,474 to the amount of carbon-12 in the sample 2390 01:44:41,507 --> 01:44:43,810 tells us how old the sample is. 2391 01:44:43,843 --> 01:44:47,013 The fewer the carbon-14s, the older it is? 2392 01:44:47,046 --> 01:44:47,881 Yes. 2393 01:44:47,914 --> 01:44:49,983 POGUE: With his accelerator, 2394 01:44:50,016 --> 01:44:54,020 Tom calculates that our tree died about 150 years ago. 2395 01:44:54,053 --> 01:44:57,357 That must have been when California's last drought ended, 2396 01:44:57,390 --> 01:44:59,192 a key piece of information 2397 01:44:59,225 --> 01:45:02,362 for understanding the region's climate cycles. 2398 01:45:02,395 --> 01:45:06,333 Carbon-14 has helped open up deep insights into the past, 2399 01:45:06,366 --> 01:45:09,636 but it's just one of hundreds of radioactive isotopes-- 2400 01:45:09,669 --> 01:45:12,038 that is, elements that decay. 2401 01:45:12,071 --> 01:45:14,274 In fact, at the bottom of the periodic table, 2402 01:45:14,307 --> 01:45:17,510 beginning with number 84, polonium, 2403 01:45:17,543 --> 01:45:21,348 all of the elements and their isotopes are radioactive, 2404 01:45:21,381 --> 01:45:24,684 including the element that stands for both the promise 2405 01:45:24,717 --> 01:45:26,820 and the peril of radioactivity: 2406 01:45:26,853 --> 01:45:28,755 uranium. 2407 01:45:28,788 --> 01:45:35,362 92 protons, 92 electrons and 146 neutrons. 2408 01:45:35,395 --> 01:45:37,464 Before the nuclear age, 2409 01:45:37,497 --> 01:45:41,234 uranium was thought to be the end of the periodic table. 2410 01:45:41,267 --> 01:45:43,203 But in the last 70 years, 2411 01:45:43,236 --> 01:45:45,438 scientists have left nature behind 2412 01:45:45,471 --> 01:45:49,542 and created 26 new elements. 2413 01:45:49,575 --> 01:45:51,978 The age of man-made atoms 2414 01:45:52,011 --> 01:45:54,381 began in the first half of the 20th century, 2415 01:45:54,414 --> 01:45:57,083 when researchers began bombarding elements 2416 01:45:57,116 --> 01:45:59,185 with neutrons. 2417 01:45:59,218 --> 01:46:01,454 Sometimes the neutron is simply absorbed, 2418 01:46:01,487 --> 01:46:03,923 creating a new isotope. 2419 01:46:03,956 --> 01:46:07,427 But sometimes the nucleus can't take the punishment. 2420 01:46:07,460 --> 01:46:11,464 It becomes unstable and splits into two smaller atoms 2421 01:46:11,497 --> 01:46:14,200 in a powerful reaction called fission 2422 01:46:14,233 --> 01:46:17,337 that releases large amounts of energy. 2423 01:46:17,370 --> 01:46:20,240 To learn more, I've come to the Nuclear Museum 2424 01:46:20,273 --> 01:46:22,242 in Albuquerque, New Mexico... 2425 01:46:22,275 --> 01:46:24,310 MATT DENNIS: Yeah, this is a mad science project. 2426 01:46:24,343 --> 01:46:26,579 ...where atomic scientist Matt Dennis 2427 01:46:26,612 --> 01:46:29,649 has offered to demonstrate how a nuclear reactor works. 2428 01:46:29,682 --> 01:46:31,618 D'oh! 2429 01:46:31,651 --> 01:46:33,453 You guys make a lot of jokes about "Gone Fission?" 2430 01:46:33,486 --> 01:46:35,121 I actually have an atomic shirt 2431 01:46:35,154 --> 01:46:36,856 that says something to that effect, so yes. 2432 01:46:36,889 --> 01:46:38,391 I knew that! I knew that! 2433 01:46:38,424 --> 01:46:39,793 Okay, now, to the naked eye, 2434 01:46:39,826 --> 01:46:42,095 this looks exactly like a nuclear reactor. 2435 01:46:42,128 --> 01:46:44,864 (Klaxon horn blows) 2436 01:46:44,897 --> 01:46:49,068 DENNIS: The similarities are the mousetraps are uranium atoms 2437 01:46:49,101 --> 01:46:52,038 and the white ping-pong balls are neutrons, 2438 01:46:52,071 --> 01:46:54,674 which you use one to start a chain reaction. 2439 01:46:54,707 --> 01:46:59,078 POGUE: In a reactor, one neutron splits a uranium atom, 2440 01:46:59,111 --> 01:47:02,949 which releases energy and two or three more neutrons, 2441 01:47:02,982 --> 01:47:05,218 which in turn split more atoms, 2442 01:47:05,251 --> 01:47:07,687 releasing more neutrons and so on, 2443 01:47:07,720 --> 01:47:10,156 causing a chain reaction. 2444 01:47:10,189 --> 01:47:12,459 So you get more and more neutrons, 2445 01:47:12,492 --> 01:47:14,394 and thus the chain reaction keeps going. 2446 01:47:14,427 --> 01:47:16,062 All right, ladies and jelly-spoons 2447 01:47:16,095 --> 01:47:18,465 here goes the orange ping-pong ball. 2448 01:47:18,498 --> 01:47:22,135 This evening's role, you'll be portraying the neutron. 2449 01:47:22,168 --> 01:47:23,736 All right, I just drop it in here? 2450 01:47:23,769 --> 01:47:25,071 Any old place? 2451 01:47:25,104 --> 01:47:27,140 Just drop it in right there, we'll start the chain reaction. 2452 01:47:27,173 --> 01:47:29,376 Incoming neutron! 2453 01:47:33,412 --> 01:47:35,381 (laughs) 2454 01:47:35,414 --> 01:47:37,884 I'm sorry, Matt, the camera wasn't rolling. 2455 01:47:37,917 --> 01:47:39,252 Can you set that up again? 2456 01:47:39,285 --> 01:47:43,790 POGUE: From a single neutron, an escalating response. 2457 01:47:43,823 --> 01:47:47,126 Our mousetrap reactor doesn't have many atoms, 2458 01:47:47,159 --> 01:47:49,629 so the reaction dies quickly. 2459 01:47:49,662 --> 01:47:51,831 But pack enough fissionable uranium atoms 2460 01:47:51,864 --> 01:47:53,500 closely enough together 2461 01:47:53,533 --> 01:47:57,303 and the whole thing can get out of hand pretty fast. 2462 01:47:57,336 --> 01:48:00,207 And sometimes that's the point. 2463 01:48:02,041 --> 01:48:04,978 This museum has the world's largest public collection 2464 01:48:05,011 --> 01:48:09,682 of artifacts that chronicle the dark side of nuclear energy. 2465 01:48:09,715 --> 01:48:12,118 JAMES WALTHER: And so that's a Trident Z-3 up there. 2466 01:48:12,151 --> 01:48:13,753 POGUE: That's huge. 2467 01:48:13,786 --> 01:48:15,355 You guys are just surrounded by bombs. 2468 01:48:15,388 --> 01:48:17,190 I feel like a kid in a death store. 2469 01:48:17,223 --> 01:48:21,828 POGUE: In 1945, the U.S. developed two atomic weapons. 2470 01:48:21,861 --> 01:48:23,997 Both were used against Japan. 2471 01:48:24,030 --> 01:48:28,535 The first was fueled by an isotope called uranium-235. 2472 01:48:28,568 --> 01:48:30,470 That bomb was called Little Boy. 2473 01:48:30,503 --> 01:48:32,505 This is the Little Boy bomb. 2474 01:48:32,538 --> 01:48:33,473 This is the... 2475 01:48:33,506 --> 01:48:34,541 This is it? 2476 01:48:34,574 --> 01:48:35,842 I guess I shouldn't bump it then, huh? 2477 01:48:35,875 --> 01:48:37,544 Well, it's a current... concurrent copy. 2478 01:48:37,577 --> 01:48:38,845 This is just like it. 2479 01:48:38,878 --> 01:48:41,514 Inside this big case was a gun barrel 2480 01:48:41,547 --> 01:48:43,449 and high explosives on the ends 2481 01:48:43,482 --> 01:48:47,153 to push the two pieces of enriched uranium together 2482 01:48:47,186 --> 01:48:48,354 at supersonic speed. 2483 01:48:48,387 --> 01:48:51,658 POGUE: The military made only one uranium bomb, 2484 01:48:51,691 --> 01:48:56,896 because separating rare U-235 from the more common U-238, 2485 01:48:56,929 --> 01:48:59,098 which doesn't work in fission reactions, 2486 01:48:59,131 --> 01:49:00,633 is a very difficult process. 2487 01:49:00,666 --> 01:49:05,572 So for the second bomb, called Fat Man, 2488 01:49:05,605 --> 01:49:08,474 they used an entirely different element: 2489 01:49:08,507 --> 01:49:10,143 plutonium-- 2490 01:49:10,176 --> 01:49:14,748 94 protons, 94 electrons, and 150 neutrons. 2491 01:49:17,416 --> 01:49:21,154 Plutonium was the first man-made element. 2492 01:49:21,187 --> 01:49:25,858 It was identified in 1940 by chemist Glenn Seaborg, 2493 01:49:25,891 --> 01:49:29,696 when he bombarded uranium atoms with protons and neutrons 2494 01:49:29,729 --> 01:49:33,566 until some of them stuck. 2495 01:49:33,599 --> 01:49:35,969 Over his long career, Seaborg went on 2496 01:49:36,002 --> 01:49:41,674 to isolate or create nine more man-made elements, 2497 01:49:41,707 --> 01:49:45,111 including Americium, which is in minute quantities 2498 01:49:45,144 --> 01:49:49,649 in the smoke alarms in our homes. 2499 01:49:49,682 --> 01:49:51,751 He pushed the end of the periodic table 2500 01:49:51,784 --> 01:49:54,821 all the way to element 106, 2501 01:49:54,854 --> 01:49:58,591 which is called Seaborgium in his honor. 2502 01:49:58,624 --> 01:50:00,460 I started out, uh, here at the laboratory 2503 01:50:00,493 --> 01:50:02,462 using these counters quite frequently... 2504 01:50:02,495 --> 01:50:05,164 POGUE: Ken Moody is a chemist at Lawrence Livermore Lab. 2505 01:50:05,197 --> 01:50:08,468 But he developed a love of big fat juicy atoms 2506 01:50:08,501 --> 01:50:13,239 as a graduate student in Seaborg's lab in the 1970s. 2507 01:50:13,272 --> 01:50:16,743 Afterwards, his first job was analyzing radioactive debris 2508 01:50:16,776 --> 01:50:20,213 produced by underground nuclear weapon tests. 2509 01:50:20,246 --> 01:50:22,215 And it was our job to go pick samples 2510 01:50:22,248 --> 01:50:23,750 and tell the physicists how well this device had worked. 2511 01:50:23,783 --> 01:50:25,051 POGUE: I think I'm smart enough to know 2512 01:50:25,084 --> 01:50:27,086 that those fragments would probably be radioactive. 2513 01:50:27,119 --> 01:50:27,887 Yes. 2514 01:50:27,920 --> 01:50:29,188 Would they not be dangerous? 2515 01:50:29,221 --> 01:50:33,059 Uh, well, we didn't carry 'em around in our pockets. 2516 01:50:33,092 --> 01:50:34,727 POGUE: Since the end of the cold war, 2517 01:50:34,760 --> 01:50:38,464 Ken's goal has been to expand the periodic table. 2518 01:50:38,497 --> 01:50:40,366 He's teamed up with a Russian lab, 2519 01:50:40,399 --> 01:50:42,335 and together they've succeeded 2520 01:50:42,368 --> 01:50:46,639 in creating six new elements in this cyclotron. 2521 01:50:46,672 --> 01:50:48,141 But there's a hitch. 2522 01:50:48,174 --> 01:50:50,476 They've only made a few atoms of each, 2523 01:50:50,509 --> 01:50:52,111 and they're all so unstable, 2524 01:50:52,144 --> 01:50:56,049 they decay away almost as soon as they come into existence. 2525 01:50:56,082 --> 01:50:58,284 POGUE: With all due respect, 2526 01:50:58,317 --> 01:51:00,920 none of the six elements that you've discovered 2527 01:51:00,953 --> 01:51:02,655 are actually in the world right now. 2528 01:51:02,688 --> 01:51:03,790 That's correct. 2529 01:51:03,823 --> 01:51:05,258 So do they count? 2530 01:51:05,291 --> 01:51:07,527 Doesn't sound like much, but for a chemist, 2531 01:51:07,560 --> 01:51:09,195 a ten-second activity 2532 01:51:09,228 --> 01:51:11,330 actually allows you to do something with it, 2533 01:51:11,363 --> 01:51:13,766 but it isn't enough that you can put it in a bottle 2534 01:51:13,799 --> 01:51:17,170 and put it on the mantelpiece and admire it the next day. 2535 01:51:17,203 --> 01:51:20,840 POGUE: Still, Ken has high hopes for the future. 2536 01:51:20,873 --> 01:51:22,308 He believes that somewhere 2537 01:51:22,341 --> 01:51:24,911 beyond today's largest man-made elements, 2538 01:51:24,944 --> 01:51:27,113 scientists will find an island of stability 2539 01:51:27,146 --> 01:51:29,549 on the periodic table 2540 01:51:29,582 --> 01:51:33,152 where some super-large atoms will be both stable and useful, 2541 01:51:33,185 --> 01:51:37,323 perhaps satisfying the needs of our future civilization. 2542 01:51:37,356 --> 01:51:39,258 It's amazing to think 2543 01:51:39,291 --> 01:51:41,794 that something as complex as the physical universe 2544 01:51:41,827 --> 01:51:44,864 can be put on a single chart. 2545 01:51:44,897 --> 01:51:47,233 And from about 90 basic elements, 2546 01:51:47,266 --> 01:51:50,236 man and nature have teamed up 2547 01:51:50,269 --> 01:51:54,540 to create the incredible variety of stuff in our lives. 2548 01:51:54,573 --> 01:51:56,876 And the story is far from over. 2549 01:51:56,909 --> 01:51:59,545 As scientists continue to hunt the secrets of the elements, 2550 01:51:59,578 --> 01:52:03,015 what new understanding and technologies will follow 2551 01:52:03,048 --> 01:52:06,252 can only be imagined.184014

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